We report the infrared spectra in the range 1000 to 700 cm−1 of 19 mono- and 35 disubstituted acenaphthenes in solution. The spectra allow the identification of the position of substitution in the mono- and common disubstituted acenaphthenes studied. Comment is made on a band which appears close to 835 cm−1 in all the acenaphthenes studied where a 4-substituent is absent.
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