The use of a continuum source in conjunction with a piezoelectrically scanned Fabry-Perot interferometer is described for the observation of absorption line-widths of the calcium 422.67 nm line in hydrogen diffusion flames. The variation of the observed absorption half-width with calcium concentration has been examined. Values for the effective and collisional half-widths for the Ca absorption line are given, and the corresponding a-parameters and collisional cross sections are calculated.
de GalanL.WagenaarH. C., Proc. 3rd. CISAFA, Paris, Sept. 1971.
15.
BehmenburgW., J. Quant. Spectrosc. Rad. Trans.4, 177 (1964).
16.
KirkbrightG. F.TroccoliO. E.VetterS., Spectrochim. Acta in press.
17.
HollanderTj.BroidaH. P., J. Quant. Spectrosc. Rad. Trans.7, 965 (1967).
18.
HollanderTj.JansenB. J.PlaatJ. J.AlkemadeC. T. J., J. Quant. Spectrosc. Rad. Trans.10, 1301 (1970).
19.
KirkbrightG. F.TroccoliO. E., Spectrochim. Acta in press.
20.
TolanskyS., An Introduction to Interferometry (Longman, Green and Co., London, 1955).
21.
FranconM., Optical Interferometry (Academic Press, New York, 1966).
22.
SyobodaV., Anal. Chem.40, 1384 (1968).
23.
AlkemadeC. T. J.ZeegersP. J. T., “Excitation and De excitation processes in flames,” in Spectrochemical Methods of Analysis, WinefordnerJ. D., Ed. (J. Wiley-Interscience, New York, 1970).
24.
ChabbalR., J. Rech. Centre Nat. Rech. Sci.24, 138 (1953).