Abstract
A summary of the instrumentation and principles involved in photoelectron spectroscopy is presented. Brief descriptions of the available commercial instruments are given. Results both in the low energy area (molecular photoelectron spectroscopy) and the high energy area (ESCA) are reviewed, with emphasis on recent data and/or controversial new areas of study.
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References
1.
Berry
R. S.
, Ann. Rev. Phys. Chem. 20 , 357 (1969 ).
2.
Turner
D. W.
Baker
A. D.
Baker
C.
, and
Brundle
C. R.
, Molecular Photoelectron Spectroscopy (Wiley , New York , 1970 ).
3.
Siegbahn
K.
, “Electron Spectroscopy for Chemical Analysis” Nova Acta Regiae Societatis Scientiorum, Upsaliensis Ser. IV. Vol. 20 (1967 ) (available in U. S. as AFML Rep. TR-68-189).
4.
Turner
D. W.
, in Physical Methods in Advanced Inorganic Chemistry , edited by
Hill
H. A. O.
and
Day
P.
(Interscience , New York , 1968 ), p. 74 .
5.
Betteridge
D.
and
Baker
A. D.
, Anal. Chem. 42 , 43 (1970 ).
6.
Price
W. C.
, Endeavour 26 , 78 (1967 ).
7.
Brundle
C. R.
and
Robin
M. B.
, in Determination of Organic Structures by Physical Methods , edited by
Nachod
F.
and
Zuckerman
G.
(Academic , New York , 1971 ), Vol. III .
8.
Siegbahn
K.
, ESCA Applied to Free Molecules (North-Holland , Amsterdam , 1970 ).
9.
Frost
D. C.
McDowell
C. A.
, and
Vroom
D. A.
, Proc. Roy. Soc. (London) A296 , 516 (1967 ).
10.
Turner
D. W.
, Proc. Roy. Soc. (London) A307 , 15 (1968 ).
11.
Lempka
J. H.
, unpublished work;
Turner
D. W.
unpublished work;
Price
W. C.
, unpublished.
12.
Brundle
C. R.
Robin
M. B.
, and
Jones
G. R.
, J. Chem. Phys. 52 , 3383 (1970 ).
13.
Mitchell
P.
and
Wilson
M.
, Chem. Phys. Lett. 3 , 389 (1969 ).
14.
Samson
J. A. R.
, Chem. Phys. Lett. 4 , 257 (1969 ).
15.
Sampson
J. A. R.
Techniques of Vacuum Ultraviolet Spectroscopy (Wiley , New York , 1967 ).
16.
Samson
J. A. R.
, Rev. Sci. Instrum. 40 , 1174 (1969 ).
17.
Turner
D. W.
, Nature 213 , 795 (1967 ).
18.
Al-Joboury
M. I.
and
Turner
D. W.
, J. Chem. Soc. 5154 (1963 ); 4434 (1965 ).
19.
Samson
J. A. R.
and
Cairns
R. B.
, Phys. Rev. 173 , 80 (1969 ).
20.
Rose
T.
Frey
R.
, and
Brehm
B.
, Chem. Comm. 1418 (1969 ); (b)
Brehm
B.
Menzinger
M.
, and
Zorn
C.
, Can. J. Chem. , to be published; (c)
Brehm
B.
, personal communication .
21.
Lempka
J. H.
Passmore
T. R.
, and
Price
W. C.
, Proc. Roy. Soc. (London) A304 , 53 (1968 ).
22.
Brundle
C. R.
Robin
M. B.
, and
Basch
H.
, J. Amer. Chem. Soc. 92 , 3863 (1970 ).
23.
Hughes
A. L.
and
Rojansky
V.
, Phys. Rev. 34 , 284 (1929 ),
Hughes
A. L.
and
McMillan
H.
, Phys. Rev. 34 , 293 (1929 ).
24.
Eland
J. D. H.
and
Danby
C. J.
, J. Sci. Instrum. 1 , 406 (1968 ).
25.
Simpson
J. A.
, Rev. Sci. Instrum. 35 , 1968 (1964 ).
26.
Hafner
H.
Simpson
J. A.
, and
Kuyatt
C. E.
, Rev. Sci. Instrum. 39 , 33 , (1968 ).
27.
Melhorn
W.
, Z. Physik 160 , 247 (1960 ); 187 , 21 (1965 ).
28.
Berkowitz
J.
, personal communication .
29.
Edquist
O.
Lindholm
E.
Selin
L. E.
, and
Asbrink
L.
, Phys. Scripta , to be published.
30.
Rendina
J.
and
Grojean
R. E.
, Appl. Spectrosc. 25 , 24 (1971 ), following article.
31.
Fahlman
A.
Albridge
R. G.
Nordberg
R.
, and
LaCosse
W. M.
, Rev. Sci. Instrum. 41 , 596 (1970 ).
32.
Fadley
C. S.
Hagström
S. B. M.
Hollander
J. M.
Klein
M. P.
, and
Shirley
D. A.
, Science 157 , 1571 (1967 ).
33.
Varian Instruments Inc., McPherson Instrument Corp., Hewlett—Packard Co.
34.
Perkin-Elmer (England) Corp., A.E.I. Ltd., and Vacuum Generators, Ltd.
35.
Japan Applied Spectroscopy Co.
36.
Fadley
C. S.
Geoffroy
G. L.
Hagström
S. B. M.
, and
Hollander
J. M.
, Nucl. Instrum. Methods 68 , 177 (1969 ).
37.
Koopmans
T.
, Physica 1 , 104 (1933 ).
38.
Basch
H.
Robin
M. B.
Kuebler
N. A.
Baker
C.
, and
Turner
D. W.
, J. Chem. Phys. 51 , 52 (1969 ).
39.
Lake
R. F.
and
Thompson
H.
, Proc. Roy. Soc. (London) A315 , 323 (1970 ).
40.
Brundle
C. R.
and
Turner
D. W.
, Proc. Roy. Soc. (London) A307 , 27 , (1968 ).
41.
Baker
A. D.
, unpublished work.
42.
Baker
A. D.
May
D. P.
, and
Turner
D. W.
, J. Chem. Soc. B 22 , (1968 ).
43.
Brundle
C. R.
Robin
M. B.
, and
Basch
H.
, J. Chem. Phys. 53 , 2196 (1970 ).
44.
Lempka
H. J.
Streets
D. G.
Potts
A. W.
, and
Price
W. C.
, Phil. Trans. Roy. Soc. (London) A268 , 59 (1970 ).
45.
Pullen
B. P.
Carlson
J. A.
Moddeman
W. E.
Schweitzer
G. K.
Bull
W. E.
, and
Grimm
F. A.
, J. Chem. Phys. 53 , 768 (1970 ).
46.
Bassett
P. J.
and
Lloyd
D. R.
, Chem. Phys. Lett. 3 , 22 (1969 ).
47.
Frost
D. C.
Herring
F. G.
McDowell
C. A.
Mustafa
M. R.
, and
Sandhu
J. S.
, Chem. Phys. Lett. 2 , 663 (1968 ).
48.
Green
J. C.
Green
M. L. H.
Joachim
P. J.
Orchard
A. F.
, and
Turner
D. W.
, Phil. Trans. Roy. Soc. (London) A268 , 111 , (1970 ).
49.
Coulson
C. A.
and
Strauss
H. L.
, Proc. Roy. Soc. (London) A269 , 443 , (1962 ).
50.
Brundle
C. R.
Robin
M. B.
, and
Basch
H.
, unpublished data.
51.
Bischof
P.
Hashmall
J. A.
Heilbronner
E.
, and
Hornung
V.
, Helv. Chem. Acta 52 , 1745 (1969 ).
52.
Bischof
P.
Hasmall
J. A.
Heilbronner
E.
, and
Hornung
V.
, Tetrahedron Lett. 4025 , (1969 ).
53.
Baker
A. D.
, J. Chem. Ed. , to be published.
54.
Hoffman
R.
Heilbronner
E.
, and
Bleiter
R.
, J. Amer. Chem. Soc. 92 , 706 (1970 ).
55.
Momigny
J.
and
Lorguet
J. C.
, Chem. Phys. Lett. 1 , 505 (1968 ).
56.
Momigny
J.
Goffart
C.
and
D'Or
L.
, Int. J. Mass Spectrosc. Ion Phys. 1 , 53 (1968 ).
57.
Natalis
P.
Collin
J. E.
, and
Momigny
J.
, Int. J. Mass Spectrosc. Ion Phys. 1 , 327 (1968 ).
58.
Natalis
P.
and
Collin
J. E.
, Chem. Phys. Lett. 2 , 79 (1968 ).
59.
Brundle
C. R.
, Chem. Phys. Lett. 5 , 410 (1970 ).
60.
Baker
A. D.
Brundle
C. R.
, and
Turner
D. W.
, Int. J. Mass Spectrosc. Ion Phys. 1 , 443 (1968 ).
61.
Samson
J. A. R.
, Chem. Phys. Lett. 4 , 257 (1969 ).
62.
Peatman
W. B.
Borne
T. B.
, and
Schlag
E. W.
, Chem. Phys. Lett. 2 , 492 (1969 ).
63.
Smith
A. L.
, Discussions Faraday Soc. , to be published.
64.
Ashbrink
L.
Lindholm
E.
, and
Edquist
O.
, Chem. Phys. Lett. 5 , 609 (1970 ) and references cited therein.
65.
Brundle
C. R.
Neumann
D.
Price
W. C.
Evans
D.
Potts
A. W.
, and
Streets
D. G.
, J. Chem. Phys. 53 , 705 (1970 ).
66.
Dixon
R. N.
and
Hull
S. E.
, Chem. Phys. Lett. 3 , 367 (1969 ).
67.
Green
J. C.
King
D. I.
, and
Eland
J. H. D.
, Chem. Commun. 7 , 1121 (1970 ).
68.
Lloyd
D. R.
and
Schlag
E. W.
, Inorg. Chem. 8 , 2544 (1969 ).
69.
Eland
J. D. H.
, Int. J. Mass Spectr. Ion Phys. 4 , 37 (1970 ).
70.
Evans
S.
Green
J. C.
Green
M. L. H.
Orchard
A. F.
, and
Turner
D. W.
, Discussions Faraday Soc. 47 , 112 (1969 ).
71.
Baker
A. D.
Betteridge
D.
Kemp
N. R.
, and
Kirby
R. E.
, J. Mass. Spectr. Ion Phys. 4 , 90 (1970 ).
72.
Hercules
D. M.
, Anal. Chem. 42 , 20 (1970 ).
73.
Helmer
J.
and
Snyder
L. C.
, personal communication .
74.
Barber
M.
and
Clark
D. T.
, Chem. Commun. 23 (1970 ).
75.
Carlson
T. A.
, personal communication .
76.
Thomas
T. D.
, J. Amer. Chem. Soc. 92 , 4184 (1970 ).
77.
Kramer
L. N.
and
Klein
M. P.
, J. Chem. Phys. 51 , 3618 (1969 ).
78.
Helmer
J.
and
Robin
M. B.
, personal communication .
79.
Rosencwaig
A.
and
Wertheim
G.
, personal communication .
80.
Robin
M. B.
and
Day
P.
, Advan. Inorg. Radiochem. 10 , 247 (1967 ).
81.
Helmer
J.
, personal communication .
82.
Helmer
J.
Rosencwaig
A.
, and
Wertheim
G.
, personal communication .
83.
Fadley
C. S.
Shirley
D. A.
Freeman
A. J.
Bagus
P. S.
, and
Mallow
J. V.
, Phys. Rev. Lett. 23 , 1397 (1969 ).
84.
May
D. P.
and
Turner
D. W.
, J. Chem. Phys. 45 , 471 (1966 ).
85.
Price
W. C.
, in Molecular Spectroscopy , edited by
Hepple
P.
(Institute of Petroleum , London , 1968 ).
86.
Brundle
C. R.
and
Turner
D. W.
, Int. J. Mass Spectrosc. Ion Phys. 2 , 195 (1969 ).
87.
Neumann
D.
and
Snyder
L. C.
, personal communication .
88.
Brehm
B.
and
Von Puttkamer
E.
, Advan. Mass Spectrometry 4 , 591 (1968 ).
89.
Frost
D. C.
McDowell
C. A.
, and
Vroom
D. A.
, Can. J. Chem. 45 , 1343 (1967 ).
90.
Dibeler
V. H.
Krauss
M.
Reese
R. M.
, and
Harlee
F. N.
, J. Chem. Phys. 42 , 3791 (1965 ).
91.
Baer
T.
Peatman
W. B.
, and
Schlag
E. W.
, Chem. Phys. Lett. 4 , 243 (1969 ).
92.
Price
W. C.
, personal communication .
93.
Taylor
N. J.
, J. Vac. Sci. Technol. 6 , 241 (1970 ).
94.
Harris
L. A.
, Surface Sci. 15 , 77 (1969 ).
95.
Haas
T. W.
and
Grant
J. T.
, Phys. Lett. 30A , 272 (1969 ).
96.
For example, see
Smith
N. V.
, Phys. Rev. Lett. 23 , 1452 (1969 ).
97.
Eastman
D. E.
, personal communication .
98.
Eastman
D. E.
and
Cashion
J. K.
, Phys. Rev. Lett. 24 , 310 (1970 ).
99.
Palmberg
P. W.
Bohn
G. K.
, and
Tracy
J. C.
, Appl. Phys. Lett. 15 , 254 (1969 ).
100.
Hagstrum
H. D.
and
Becker
G. E.
, Phys. Rev. Lett. 22 , 1054 (1969 ).
101.
Bordass
W. T.
and
Linnet
J. W.
, Nature 222 , 660 (1969 ).
102.
Delgass
W. N.
Hughes
T. R.
, and
Fadley
C. S.
, Catalys. Rev. 4 , 179 (1970 ).