Abstract
The absorption spectra of some organic azides have been studied in the visible and uv region using different solvents. Interpretation of the obtained results is attempted. The different transitions obtained are assigned to either intramolecular charge–transfer transitions or to locally excited ones. The energies of the charge–transfer states are computed. No evidence was found for an n → π* transition.
Get full access to this article
View all access options for this article.
References
1.
Mangini
A.
and
Cosoni
Dalmonte D.
, Chem. Zentr. 1 , 1978 (1943 ).
2.
Mandala
E.
and
Garonna
G.
, Gazz. Chim. Ital. 71 , 182 (1941 ).
3.
Bennemay
M.
and
Verdier
E. T.
, J. Chim. Phys. 41 , 113 (1944 ).
4.
Sheinker
Yu. N.
and
Syrkin
Yu. K.
, Chem. Abstr. 45 , 3246g (1950 ).
5.
Spauschus
H. O.
and
Scott
J. M.
, J. Amer. Chem. Soc. 73 , 208 (1951 ).
6.
Spauschus
H. O.
and
Scott
J. M.
, J. Amer. Chem. Soc. 73 , 210 (1951 ).
7.
Grammaticakis
P.
, Compt. Rend. 244 , 1517 (1957 ).
8.
Smith
P.
Hall
J.
, and
Kan
R. O.
, J. Amer. Chem. Soc. 84 , 485 (1962 ).
9.
Ladik
J.
and
Messmer
A.
, Acta Chim. Acad. Sci. Hung. 34 , (1962 ).
10.
Vogel
A. I.
, Practical Organic Chemistry (Longmans , London 1956 ), 3rd ed.
11.
Noelting
E.
and
Michel
O.
, Ber . 26 , 86 (1893 ).
12.
Yonezawa
T.
Kato
H.
and
Konishi
H.
, Bull. Chem. Soc. Japan , 40 , 1071 (1967 ).
13.
Franklin
J. L.
Dibeler
V. H.
Reese
R. M.
, and
Krauss
M.
, J. Amer. Chem. Soc. 80 , 298 (1958 ).
14.
Nagakura
S.
and
Tanaka
J.
, J. Chem. Phys. 22 , 236 (1954 ).
15.
Nagakura
S.
, J. Chem. Phys. 23 , 1441 (1955 ).
16.
Murrell
J. N.
, Theory of Electronic Spectra of Organic Molecules (Methuen , London , 1963 ).