The gas-phase absorption spectra of 2-methylpent-2-ene-4-one, 2-methylpent-l-en-3-one, trans-pent-3-en-2-one, pent-l-en-3-one, 2-methylpent-2-enal, 4-methylpent-2-enal, methacrolein, acrolein, acetylacetone, and 4-methylpentan-3-onal have been determined at 525°C and at a total pressure of 28.5 atm. The effect of temperature on the absorption has been investigated and, for comparison, the absorption spectra have also been determined in cyclohexane solution at room temperature.
EgertonA. and PidgeonL. M., Proc. Roy. Soc. (London) Ser.A142, 26 (1933).
2.
WithrowL. and RassweilerG. M., Ind. Eng. Chem.25, 9231359 (1933); 26, 1256 (1934); 27, 872 (1935).
3.
UbbelohdeA. R., Proc. Roy. Soc. (London) Ser.A152, 354 (1935).
4.
EgertonA. and YoungG. H. S., Trans. Faraday Soc.44, 750 (1948).
5.
ThomasJ. R. and CrandallH. W., Ind. Eng. Chem.43, 2761 (1951); BaruschM. R.CrandallH. W.PayneJ. Q., and ThomasJ. R., Ind. Eng. Chem.43, 2764 (1951); BaruschM. R.NeuJ. T.PayneJ. Q., and ThomasJ. R., Ind. Eng. Chem.43, 766 (1951).
6.
BurtR.SkuseF., and ThomasA., Combustion Flame9, 159 (1965).
7.
FishA.HaskellW. W., and ReadI. A. (to be published).
8.
AffleckW. S. and ThomasA. (to be published).
9.
GaydonA. G. and HurleI. R., The Shock Tube in Chemical Physics (Chapman and Hall Ltd., London, 1964), p. 136.
10.
BaumanR. P., Absorption Spectroscopy (John Wiley & Sons, Inc., New York, 1962), p. 153.
11.
SlavinW., Anal. Chem.35, 561 (1963).
12.
MaddinR. P., Phys. Thin Films1, 135 (1963).
13.
CalvertJ. G. and PittsJ. N., Photochemistry (John Wiley & Sons, Inc., New York, 1966), p. 253.
14.
WoodwardR. B., J. Amer. Chem. Soc.63, 1123 (1941).
15.
ConantJ. B. and ThompsonA. F., J. Amer. Chem. Soc.54, 4039 (1932).
16.
GrossmanP., Z. Physik. Chem.109, 305 (1924).
17.
AllenG. and DwekR. A., J. Chem. Soc.1966, 161 (1966).
