The nuclear magnetic resonance and infrared spectra of five N-vinyl compounds and the corresponding N-ethyl compounds have been observed in order to obtain detailed information about the N-vinyl group. Resultant data indicate that one might prove the presence of N-vinyl by two characteristic infrared maxima in the region of 1390 to 1300 cm−1. The NMR spectra of the N-vinyl protons conform to the expected ABX pattern. The chemical shifts do not permit differentiation from other vinyl types.
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References
1.
LandisW. R. and PerrineT. D. (to be published).
2.
AnilinBadische and Soda-FabrikAG, Ludwigshafen am Rhein, West Germany.
3.
Borden Chemical Company, Philadelphia, Pennsylvania.
4.
Aldrich Chemical Company, Inc., Milwaukee, Wisconsin.
5.
BanwellC. N. and SheppardN., Mol. Phys.3, 351 (1960).
6.
BanwellC. N., Mol. Phys.3, 511 (N) (1960).
7.
BrügelW.AnkelTh., and KruckebergF., Z. Elektrochem.64, 1121 (1960).
8.
BishopE. O. and RichardsR. E., Mol. Phys.3, 114 (1960).
9.
EmsleyJ. W.FeeneyJ., and SutcliffeL. H., High Resolution Nuclear Magnetic Resonance Spectroscopy (Perga-mon Press, Inc., Oxford, 1965), Vol. I, p. 280.
10.
NakanishiK., Infrared Absorption Spectroscopy (Holden-Day, Inc., San Francisco, 1962), p. 24.
11.
PottsW. J. and NyquistR. A., Spectrochim. Acta15, 679 (1959).