Abstract
This paper presents a method for rapid and accurate determination of individual components in modified thermosetting acrylic-coating resins. This technique is based on infrared-absorbance measurements at 1733 cm−1, 816 cm−1, and 700 cm−1 for the acrylate, melamine-formaldehyde, and styrene components, respectively. The accuracy and precision obtained on typical system of known composition have been found to be better than ±2% absolute for any one component. Furthermore, the analysis can be performed in minutes after the initial calibration work has been completed.
Get full access to this article
View all access options for this article.
References
1.
Miller
C. D.
Shreve
O. D.
, Anal. Chem. 28 , 200 (1956 ).
2.
Sterling
G. D.
Cobler
J. G.
Erley
D. S.
Blanchard
F. A.
, Anal. Chem. 31 , 1612 (1959 ).
3.
Binder
J. L.
, Anal. Chem. 26 , 1877 (1954 ).
4.
Dinsmore
H. L.
Smith
D. C.
, Anal. Chem. 20 , 11 (1948 ).
5.
Fraser
J. G.
Pross
A. W.
, Offic. Dig. 29 , 75 (1957 ).
6.
Hampton
R. R.
, Anal. Chem. 21 , 923 (1949 ).
7.
Pokroviskii
E. I.
, Vysokomolekul. Soedin. 1 , 738 (1959 ).
8.
Svoboda
G. R.
, Anal. Chem. 34 , 1655 (1962 ).
9.
Wexler
A. S.
, Anal. Chem. 36 , 1829 (1964 ).
10.
Ito
K.
Yamashita
Y.
, Polymer Letters 3 , 625 (1965 ).
11.
Crippen
R. C.
Borella
C. E.
, Anal. Chem. 21 , 927 (1949 ).
12.
Meekan
E. J.
, J. Polymer Sci. 4 , 639 (1949 ).
13.
Tobolsky
A. V.
Eisenberg
A.
O'Driscoll
K. F.
, Anal. Chem. 31 , 203 (1959 )
14.
Takayama
Y.
Araki
S.
, J. Chem Soc. Japan, Ind. Chem. Sect. 61 , 431 (1958 ).
15.
Arnold
A.
Madorsky
I.
Wood
L. A.
, Anal. Chem. 23 , 1656 (1951 ).
16.
Boelhouwer
C.
Tjoan
T. S.
Waterman
H. I.
, Anal. Chim. Acta 11 , 74 (1954 ).
17.
Swann
M. H.
, Anal. Chem. 25 , 1735 (1953 ).
18.
Hilton
C. L.
Newell
J. E.
Tolsma
J.
, Anal. Chem. 31 , 915 (1959 ).
19.Am. Soc. Testing Materials, Philadelphia, “Standards” Part 4, p. 330 , (1952 ).
20.
Knappe
E.
Peteri
D.
, Z. Anal. Chem. 194 , 417 (1963 ).
21.
Swann
M. H.
, Anal. Chem. 25 , 1735 (1953 ).
22.
Miller
C. D.
Shreve
O. D.
, Anal. Chem. 28 , 200 (1956 ).
23.
Shelberg
E. F.
, Anal. Chem. 23 , 1492 (1951 ).
24.
Miller
D. L.
Samsel
E. P.
Cobler
J. G.
, Anal. Chem. 33 , 677 (1961 ).
25.
Esposito
G. G.
Swann
M. H.
, Gas Chromatog. Aug. 281 , (1965 ).
26.
Strussburger
J.
, Anal. Chem. 32 , 454 (1960 ).
27.
Gatrell
R. L.
Mao
T. J.
, Anal. Chem. 37 , 1294 (1965 ).
28.
Chinai
S. N.
Campbell
R. H.
, Anal. Chem. 33 , 577 (1961 ).
29.
Pokrovskii
E. I.
, Vysokomolekul. Soedin. 6 , 642 (1964 ).
30.
Trent
F. M.
Key
C. L.
, Paper presented at 4th National Society Appl. Spectry. Meeting , Cleveland, Ohio .
31.Am. Soc. Testing Materials, Philadelphia, “Standards” Part 20, p. 550 (1964 ).
32.
Miller
C. D.
Shreve
O. D.
, Anal. Chem. 28 , 200 (1956 ).
