A spectroradiometer–luminometer has been constructed, calibrated, and applied to the measurement of fluorescence- and chemiluminescence-emission intensity as a function of wavelength and to kinetic decay studies. It is also applicable to investigations of phosphorescence, electroluminescence, bioluminescence, and the spectroradiometry of external light sources. A computer program has been set up to take care of wavelength-response corrections and to convert emission intensities into photochemical, radiometric, or luminous units, including total integrated intensities for quantum-yield studies.
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References
1.
HirtR. C.SchmittR. G.SearleN. D.SullivanA. P., J. Opt. Soc. Am.50, 706 (1960); and HirtR. C.SchmittR. G.DuttonW. L., Solar Energy3, No. 2, 19 (1959).
2.
KingF. T.HirtR. C., Anal. Chem.24, 1545 (1952).
3.
Emitted energy was measured at the photomultiplier.
4.
RauhutM. M.SheehanD.ClarkeR. A.RobertsB. G.SemselA. M., J. Org. Chem.30, 3587 (1965).
5.
RauhutM. M.RobertsB. G.SemselA. M., J. Am. Chem. Soc.88, 3604 (1966).
6.
RauhutM. M.SemselA. M.RobertsB. G., J. Org. Chem.31, 2431 (1965).