The infrared spectra of thirteen aliphatic aldehydes of varying structure have been recorded and analyzed in the range of 700–400 cm−1 The structural configuration adjacent to the carbonyl group was found to affect the observed spectra in a specific manner It thus appears possible to differentiate α-branched and non-α-branched aliphatic aldehydes from their infrared spectra in this region.
Get full access to this article
View all access options for this article.
References
1.
HartwellE. J.RichardsR. E., and ThompsonH. W., J. CHEM. SOC.1948, 1436
2.
BloutE. R.FieldsM., and KarplusR., J. AM. CHEM. SOC.70, 194 (1948)
3.
BellamyL. L., The Infrared Spectra of Complex Molecules, John Wiley and Sons, Inc., New York, 1958, 2nd ed.
4.
EvansJ. C. and BernsteinH. J., CAN. J. CHEM.34, 1083 (1956)
5.
WordenE. F.Jr., SPECTROCHIM. ACTA18, 11211962)
6.
DoddR. E.RobertsH. L., and WoodwardL. A. T.CHEM. SOC.1957, 2783
7.
BrandJ. C. D. and WatsonJ. K. G., TRANS. FARA- DAY SOC.56, 1582 (1960)
8.
KingG. W. and MouleD., SPECTROCHIM. ACTA17, 286 (1961)
9.
LambertP. and LecomteJ., COMPT. REND.208, 740 (1939)
10.
NovakH. and WhalleyE., SPECTROCHIM. ACTA16, 521 (1960)
11.
BentleyF. F.WolfarthE. F.SrpN. E., and PowellW. R., IBID.13, 1 (1958)