Spectral data are presented showing that the β form of glucose can be changed to the α form while in the solid phase, but this is not reversible. The existence of β-D-gIucose hydrate is postulated. Anomer transformation occurs only with the hydrated sugar Rigorous drying of infrared-quality KBr was found unnecessary for use with the sugars
Get full access to this article
View all access options for this article.
References
1.
BarkerS. A.BourneE. J.StaceyM., and WhiffenD. H., J. CHEM. SOC.1954, 171
2.
BarkerS. A.BourneE. J.StephensR., and WhiffenD. H., IBID.1954, 3468
3.
BarkerS. A.BourneE. J.NeelyW. B., and WhiffenD. H., CHEM. AND IND. (LONDON)1954, 1418
4.
BarkerS. A.BourneE. J.WeigelH., and WhiffenD. H., IBID.1956, 318
5.
FarmerV. C., IBID.1959, 1306
6.
HigginsH. G.StewartC. M., and HarringtonK. J., J. POLYMER SCI.51, 59 (1961)
7.
NorrisK. P. and GreenstreetJ. E. S., NATURE181, 265 (1958)
8.
KuhnL. P., ANAL. CHEM.22, 276 (1950)
9.
O'ConnorR. T.DuPreE. F., and McCallE. R., IBID.29, 998 (1957)
10.
TipsonR. S. and IsbellH. S., J. RESEARCH NATL BUR. STANDARDS66A, 31 (1962)
11.
WhistlerR. L. and HouseL. R., ANAL. CHEM.25, 1463 (1953)