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Abstract

In the process of collecting a library of spectra of aromatic compounds for investigation of synthetic liquid fuels, various correlations have been observed. (1) Phenylnaphthalene-type spectra have been noted in related compounds, (2) spectra and structures of fluorene derivatives have been studied; (3) graphs of intensity as a function of wavelength for the first band in the spectra of several alkyl- and alicyclic-benzenes and phenols have revealed interesting properties; (4) spectral effect of three classes of alicyclic rings on the first band in spectra of polynuclear condensed aromatics have been discussed, and (5) ring-strain, produced by substituents in an aromatic nucleus because of steric hindrance, has been found to cause drastic changes in the spectra.

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References

American Petroleum Institute Research Project 44. Carnegie Institute of Technology . Catalog of Ultraviolet Spectral Data.

Askew

F. A.

, J. Chem. Soc. 1935, 509.

Bradsher

C. K.

Rapoport

, and Anderson

, J. Am. Chan. Soc. 66, 215 (1946).

Burns

P. M.

, and Iball

, Nature 173, 635 (1954).

Clar

, Aromatische Kohlenwasserstoffe, Springer-Verlag, Berlin, 1941.

Fórster

Th.

, Z. Naturforsch. 2a, 149 (1947).

Friedel

R. A.

and Orchin

, Ultraviolet Spectra of Aromatic Compounds, John Wiley & Sons, New York, 1951.

Friedel

R. A.

Reggel

, and Orchin

, J. Am. Chem. Soc. 70, 199 (1948).

Fromherz

Thaler

, and Wolf

, Z. Elektrochem. 49, 387 (1943).

10.

Harnick

Herbstein

F. H.

and Schmidt

, Nature 168, 158 (1951).

11.

Hirschberg

and Jones

R. N.

, Can. Jour. Res. B27, 437 (1949).

12.

Jacobs

W. A.

Craig

L. C.

, and Lavin

G. I.

, J. Biol. Chem. 141, 51 (1941).

13.

Jones

R. N.

, J. Am. Chem. Soc. 63, 313 (1941).

14.

Jones

R. N.

, Ibid., 67, 2021 (1945).

15.

Jones

R. N.

, Ibid., 67, 2127 (1945).

16.

Mills

W. H.

and Nixon

I. G.

, J. Chem. Soc. 1930, 2510.

17.

Newman

M. S.

and Whitehouse

H. S.

, J. Am. Chem. Soc. 71, 3664 (1949).

18.

Pauling

, Nature of the Chemical Bond, Cornell University Press, Ithaca, 1945, p. 143.

19.

Platt

J. R.

, J. Chem. Phys. 19, 263 (1951).

20.

Ramart-Lucas

and Hoch

, Bull. soc. chim. [5], 2, 1376 (1935).

21.

Sklar

A. L.

, J. Chem. Phys. 10, 135 (1942).

Correlations in Ultraviolet Spectrophotometry

Abstract

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References