Abstract
We describe a brass light pipe (LP) mounted in a cylindrical optical accessory for attenuated total reflection (ATR) that can be used to readily obtain the infrared spectra of liquids and monolayers. As examples, we show the LP spectra of isooctane, decane, dimethyl malonate, dodecanol, dodecanethiol, and acetic acid and compare them to those obtained by transmission as well as by ATR. In addition, we utilize a dodecanethiol monolayer spectrum to illustrate the sensitivity of the LP scheme.
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References
1.
Cort
B.
Andrew
J. F.
and
Hansen
G. J
, Appl. Spectrosc. 41 , 493 (1987 ).
2.
Hansen
W. N.
and
Hansen
G. J
, Appl. Spectrosc. 41 , 553 (1987 ).
3.
Hansen
W. N.
Andrew
J. F.
and
Hansen
G. J
, Appl. Spectrosc. 41 , 562 (1987 ).
4.
Yu
B.-Z.
Hansen
W. N.
and
Ward
J
, Appl. Spectrosc. 43 , 113 (1989 ).
5.
Chapados
C.
Bjoraker
G. L.
and
Birnbaum
G
, J. Quant. Spectrosc. Radiat. Trans. 43 , 319 (1990 ).
6.
Chapados
C.
and
Birnbaum
G
, unpublished results .
7.
Dirinck
I.
Meyer
E.
Van Bocxlaer
J.
Lambert
W.
and
De Leenheer
A
, J. Chromatogr., A 819 , 155 (1998 ).
8.
Le Quere
J. L.
and
Semon
E
, Analusis 26 , M40 (1998 ).
9.
McGarvey
D. J.
Stuff
J. R.
Williams
B. R.
and
Durst
H. D
, Spectrosc. Lett. 33 , 795 (2000 ).
10.
Harrick
N. J.
, Internal Reflection Spectroscopy (Interscience Publishers , New York , 1967 ).
11.
Griffiths
P. R.
, Optical Spectroscopy: Sampling Techniques Manual (Harrick Scientific Corporation , Ossining, NY , 1987 ).
12.
Max
J.-J.
and
Chapados
C
, Appl. Spectrosc. 53 , 1045 (1999 ).
13.
Max
J.-J.
Trudel
M.
and
Chapados
C
, Appl. Spectrosc. 52 , 234 (1998 ).
