Laser-induced breakdown spectroscopy (LIBS) is presented for detection of several Group I and II elements (e.g., Na, Ca, Li, and K), as well as Mn and CaOH, in bulk aqueous solution at pressures exceeding 2.76 × 107 Pa (276 bar). Preliminary investigations reveal only minor pressure effects on the emission intensity and line width for all elements examined. These effects are found to depend on detector timing and laser pulse energy. The results of these investigations have implications for potential applications of LIBS for in situ multi-elemental detection in deep-ocean environments.
Von DammK. L., “Controls on the Chemistry and Temporal Variability of Seafloor Hydrothermal Fluids”, in Seafloor Hydrothermal Systems: Physical, Chemical, Biological, and Geological Interactions, HumphrisS. E.ZierenbergR. A.MullineauxL. S. and ThomsonR. E, Eds. (Geophysical Monograph Series, American Geophysical Union, Washington, D.C., 1995), Chap. 91, p. 222.
2.
DalyK. L.ByrneR. H.DicksonA. G.GallagerS. M.PerryM. J. and TiveyM. K, Marine Tech. Soc. J.38(2), 121 (2004).
BrechF. and CrossL, Appl. Spectrosc.16, 59 (1962).
6.
CremersD. A., Appl. Spectrosc.41, 572 (1987).
7.
DaviesC. M.TelleH. H.MontgomeryD. J. and CorbettR. E, Spectrochim. Acta, Part B50, 1059 (1995).
8.
MarquardtB. J.GoodeS. R. and AngelS. M, Anal. Chem.68, 977 (1996).
9.
MarquardtB. J.StratisD. N.CremersD. A. and AngelS. M, Appl. Spectrosc.52, 1148 (1998).
10.
SamekO.BeddowsD. C. S.KaiserJ.KukhlevskyS. V.LiškaM.TelleH. H. and YoungJ, Opt. Eng.39, 2248 (2000).
11.
TelleH. H.BeddowsD. C. S.MorrisG. W. and SamekO, Spectrochim. Acta, Part B56, 947 (2001).
12.
PalancoS.BaenaJ. M. and LasernaJ. J, Spectrochim. Acta, Part B57, 591 (2002).
13.
WiensR. C.SharmaS. K.ThompsonJ.MisraA. and LuceyP. G, Spectrochim. Acta, Part A61, 2324 (2005).
14.
BlacicJ. D.PettitD. R.CremersD. A. and RoesslerN, “Laser-Induced Breakdown Spectroscopy for Remote Elemental Analysis of Planetary Surfaces”, Proceedings of the International Symposium on Spectral Sensing Research, 302 (1992).
15.
DaviesC. M.TelleH. H. and WilliamsA. W, Fresenius' J. Anal. Chem.355, 895 (1996).
16.
HouX. D. and JonesB. T, Microchem. J.66, 115 (2000).
17.
KnightA. K.ScherbarthN. L.CremersD. A. and FerrisM. J, Appl. Spectrosc.54, 331 (2000).
18.
GruberJ.HeitzJ.StrasserH.BäuerleD. and RamasederN, Spectrochim. Acta, Part B56, 685 (2001).
19.
WhitehouseA. I.YoungJ.BotheroydI. M.LawsonS.EvansC. P. and WrightJ, Spectrochim. Acta, Part B56, 821 (2001).
20.
ArpZ. A.CremersD. A.HarrisR. D.OschwaldD. M.ParkerG. R.Jr., and WayneD. M., Spectrochim. Acta, Part B59, 987 (2004).
21.
López-MorenoC.PalancoS. and LasernaJ. J, Spectrochim. Acta, Part B60, 1034 (2005).
22.
KochS.CourtR.GarenW.NeuW. and ReuterR, Spectrochim. Acta, Part B60, 1230 (2005).
23.
PaksyL.NémetB.LengyelA.KozmaL. and CzekkelJ, Spectrochim. Acta, Part B51, 279 (1996).
24.
TranM.SunQ.SmithB. and WinefordnerJ. D, Anal. Chim. Acta419, 153 (2000).
25.
WainnerR. T.HarmonR. S.MiziolekA. W.McNesbyK. L. and FrenchP. D, Spectrochim. Acta, Part B56, 777 (2001).
26.
BarbiniR.ColaoF.LazicV.FantoniR.PalucciA. and AngeloneM, Spectrochim. Acta, Part B57, 1203 (2002).
27.
BulajicD.CristoforettiG.CorsiM.HidalgoM.LegnaioliS.PalleschiV.SalvettiA.TognoniE.GreenS.BatesD.SteigerA.FonsecaJ.MartinsJ.McKayJ.TozerB.WellsD.WellsR. and HarithM. A, Spectrochim. Acta, Part B57, 1181 (2002).
28.
NodaM.DeguchiY.IwasakiS. and YoshikawaN, Spectrochim. Acta, Part B57, 701 (2002).
29.
LeeW. B.WuJ.LeeY. I. and SneddonJ, Appl. Spectrosc.39, 27 (2004).
30.
MunsonC. A.De LuciaF. C.Jr.PiehlerT.McNesbyK. L. and MiziolekA. W, Spectrochim. Acta, Part B60, 1217 (2005).
31.
SalléB.CremersD. A.MauriceS. and WiensR. C, Spectrochim. Acta, Part B60, 479 (2005).
32.
CremersD. A.RadziemskiL. J. and LoreeT. R, Appl. Spectrosc.38, 721 (1984).
33.
NygaR. and NeuW, Opt. Lett.18, 747 (1993).
34.
KnoppR.ScherbaumF. J. and KimJ. I, Fresenius' J. Anal. Chem.355, 16 (1996).
35.
PichahchyA. E.CremersD. A. and FerrisM. J, Spectrochim. Acta, Part B52, 25 (1997).
36.
KennedyP. K.HammerD. X. and RockwellB. A, Prog. Quant. Electron21(3), 155 (1997).
37.
BeddowsD. C. S.SamekO.LiskaM. and TelleH. H, Spectrochim. Acta, Part B57, 1461 (2002).
38.
PearmanW. F.ScaffidiJ. and AngelS. M, “Trace Metal Analysis in Bulk Aqueous solution using nanosecond dual pulse laser induced breakdown spectroscopy”, in Trends in Optics and Photonics Book Series, Book 81 (Laser Induced Plasma Spectroscopy and Applications) (Optical Society of America, Washington, D.C., 2002), p. 218.
39.
PearmanW.ScaffidiJ. and AngelS. M, Appl. Opt.42, 6085 (2003).
40.
KochS.GarenW.MüllerM. and NeuW, Appl. Phys. A79, 1071 (2004).
41.
St-OngeL.KwongE.SabsabiM. and VadasE. B, J. Pharm. Biomed. Anal.36, 277 (2004).
42.
De GiacomoA.Dell'AglioM.ColaoF. and FantoniR, Spectrochim. Acta, Part B59, 1431 (2004).
43.
De GiacomoA.Dell'AglioM. and De PascaleO, Appl. Phys. A79, 1035 (2004).
44.
De GiacomoA.Dell'AglioM.ColaoF.FantoniR. and LazicV, Appl. Surf. Sci.247, 157 (2005).
45.
CasavolaA.De GiacomoA.Dell'AglioM.TaccognaF.ColonnaG.De PascaleO. and LongoS, Spectrochim. Acta, Part B60, 975 (2005).
46.
LazicV.ColaoF.FantoniR. and SpizzicchinoV, Spectrochim. Acta, Part B60, 1002 (2005).
47.
LazicV.ColaoF.FantoniR. and SpizzicchinoV, Spectrochim. Acta, Part B60, 1014 (2005).
48.
NakamuraS.ItoY. and SoneK, Anal. Chem.68, 2981 (1996).
49.
RadziemskiL. J.LoreeT. R.CremersD. A. and HoffmanN. M, Anal. Chem.55, 1246 (1983).
50.
MaoX.ZengX.WenS. B. and RussoR. E, Spectrochim. Acta, Part B60, 960 (2005).
51.
DetalleV.HéonR.SabsabiM. and St-OngeL, Spectrochim. Acta, Part B56, 1011 (2001).
