Abstract
The excitation emission matrix spectral subtraction (EEMSS) fluorescence technique was used to estimate adulteration of petrol by kerosene. A calibration graph obtained from the spectral volume with the use of EEMSS fluorescence is found to be efficacious in the whole range 0 to 90% v/v of kerosene. The method is simple, reliable, and superior in terms of both sensitivity (1% v/v) and accuracy compared to any other method. The method gives a good recovery for synthesized adulterated sample.
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References
1.
Rho
J. H.
Stuart
J. L.
, Anal. Chem. 50 , 620 (1978 ).
2.
Senga
Y.
Minamin
S.
, Appl. Spectrosc. 45 , 1721 (1991 ).
3.
Gray
N. R.
McMillen
S. J.
Requejo
A. G.
Kerr
J. M.
Denoux
G.
McDonald
T. J.
, SPE 25990 , 465 (1993 ).
4.
Beltran
J. L.
Ferrer
R.
Guiteras
J.
, Anal. Chim. Acta 373 , 311 (1998 ).
5.
JiJi
R. D.
Cooper
G. A.
Booksh
K. S.
, Anal. Chim. Acta 397 , 61 (1999 ).
6.
Dudelzak
A. E.
Babichenko
S. M.
Poryvkina
L. V.
Saar
K. J.
, Appl. Opt. 30 , 453 (1991 ).
7.
Shanahan
G. J.
Boley
N. P.
Traynor
A. D.
, Appl. Spectrosc. 45 , 1070 (1991 ).
8.
Patra
D.
Sireesha
K. L.
Mishra
A. K.
, J. Scient. Ind. Res. 59 , 300 (2000 ).
9.
Patra
D.
Mishra
A. K.
, “Total Fluorescence Quantum Yield of Petroleum Products” , unpublished work .
10.
Patra
D.
Mishra
A. K.
, Analyst 125 , 1383 (2000 ).
11.
Patra
D.
Mishra
A. K.
, Talanta 53 , 783 (2001 ).
12.
Kao
S.
Asanov
A. N.
Oldham
P. B.
, Instrum. Sci. Technol. 26 , 375 (1998 ).
13.
Gupta
A. A.
Swami
K. K.
Misra
A. K.
Bhatnagar
A. K.
Mukhopadhaya
P. K.
, Hydrocarbon Technol . 15 , 137 (1992 ).
14.
Bhatnagar
V. P.
, J. Acoust. Soc. India 9 , 19 (1981 ).
15.
Bahari
M. Shahru
Criddle
W. J.
Thomas
J. D. R.
, Analyst 115 , 417 (1990 ).
16.
Bahari
M. Shahru
Criddle
W. J.
Thomas
J. D. R.
, Anal. Proc. 28 , 14 (1991 ).
17.
Bahari
M. Shahru
Criddle
W. J.
Thomas
J. D. R.
, Anal. Proc. 29 , 30 (1992 ).
18.
Srivastava
A.
Shukla
R. K.
Srivastava
A.
Bali
L. M.
, in Proceedings of the International Conference on Fiber Optics and Photonics (Tata McGraw Hill , New Delhi , 1997 ), Vol. II , p. 989 .
19.
Roy
S.
, Sensors and Actuators B 55 , 212 (1999 ).
20.
Wang
X.
Mullins
O. C.
, Appl. Spectrosc. 48 , 977 (1994 ).
21.
Ralston
C. Y.
Yu
X.
Mullins
O. C.
, Appl. Spectrosc. 50 , 1563 (1996 ).
22.
Downari
T. D.
Mullins
O. C.
, Appl. Spectrosc. 49 , 754 (1995 ).
23.
Lakowicz
J. R.
, Principles of Fluorescence Spectroscopy (Plenum Press , New York , 1986 ), 3rd ed. , p. 305 .
24.
Smith
G. C.
Sinski
J. F.
, Appl. Spectrosc. 53 , 1459 (1999 ).
