Mesoporous silica has been prepared using tetraethyl orthosilicate (TEOS) as the silica source and cetyltrimethylammonium bromide (CTAB) as the template, with Cl− and SO24− as the respective inorganic counterions. The as-made mesoporous silica samples were calcined at different temperatures, following which the adsorption isotherms of laccase onto the calcined mesoporous silica surface were obtained. The relationships between the adsorption isotherm type and the morphology, pore diameter, surface electrical potentials (ζ) as well as the values of the isoelectric point (IEP) of the mesoporous silica were discussed.
References
1.
CurrieJ.A. (1961) Br. J. Appl. Phys.12, 275.
2.
EirichF.R. (1977) J. Colloid Interface Sci.58, 423.
3.
EverettD.H. (1972) Pure Appl. Chem.31, 577.
4.
HakulinenN.KiiskinenL.KruusK.SaloheimoM.PaananenA.KoivulaA. and RouvinenJ. (2002) Nat. Struct. Biol.9, 601.
5.
IlerR.K. (1979) The Chemistry of Silicon, John Wiley & Sons, New York, pp. 634, 671, 667–707.
6.
KresgeC.LeonowiczM.RothW.VartuliJ. and BeckJ. (1992) Nature (London)359, 710.
7.
KrukM. and JaroniecM. (1997) Langmuir13, 6267.
8.
KrukM.AntochshukV. and SayariM.J.A. (1999) J. Phys. Chem. B103, 10–670.
9.
LiJ. (1993) Biochemistry, Peking University Press, Beijing, P. R. China, pp. 87, 115.
10.
LinH.ChengS. and MouC. (1998) Chem. Mater. 10, 581.
11.
LiuS. and QianS. (2003) Acta Microbiol. Sinica43, 73.
12.
Schmidt-WinkelP.LukensW.ZhaoD.YangP.ChmelkaB. and StuckyG. (1999) J. Am. Chem. Soc.121, 254.
13.
WangZ.YangY.QuX.ZhangJ.ChenY. and NieL. (2005) Environ. Chem. Lett.3, 33.
14.
XuR.R.PangW.Q.YuJ.HuoQ. and ChenJ. (2004) Chemistry – Zeolites and Porous Materials, Science Press, Beijing, P. R. China, p. 152.
15.
YangY.YingH.ShaoJ.HuangZ. and LiuX. (2007b) J. Am. Ceram. Soc.90, 3460.
16.
YangY.ZhangJ.LiuX.ChenY. and JiaX. (2007a) J. Am. Ceram. Soc.90, 2050.
17.
YangY.ZhangJ.YangW.WuJ. and ChenR. (2003) Appl. Surf. Sci.206, 20.
18.
ZhangL.D. (2001) Nanomaterials, Chemistry Industry Press, Beijing, P. R. China, p. 11.
19.
ZhangM.XiaoY. and GongW. (2003) J. Biol. (Chinese)20, 6.