Abstract
The ‘solution’ analogues of four single-gas adsorption isotherms [i.e. the Langmuir-Freundlich (LF), the generalized Langmuir (GL), the Toth (T) and the LF-GL equations] were examined. The derived expressions were applied to the description of the experimental adsorption data relating to the sorption of a binary liquid solution containing components of unlimited miscibility on to microporous solids. Optimization of the equation parameters, as well as a comparison of the results obtained with those determined earlier for sorption in systems where the components were of limited miscibility, was undertaken.
References
1.
Blackburn
A.
Kipling
J.J.
Tester
D.A.
(1957 ) J. Chem. Soc. 2374 .
2.
Cysewski
P.
Garbacz
J.K.
Biniak
S.
Świątkowski
A.
(1990 ) Pol. J. Chem. 64 , 267 .
3.
Dąbrowski
A.
(1985 ) Description of Mono and Multilayer Adsorption from Solutions of Non-electrolytes onto Real Surfaces of Solids , University Press , Lublin .
4.
Dąbrowski
A.
Jaroniec
M.
(1979 ) Acta Chim. Acad. Sci. Hung. 99 , 255 .
5.
Dubinin
M.M.
(1972 ) Adsorption–Desorption Phenomena , Academic Press , New York .
6.
Findesein
W.
Szymanowski
J.
Wierzbicki
A.
(1980 ) Theory and Calculation Methods of Optimization , PWN , Warsaw .
7.
Garbacz
J.K.
Cysewski
P.
Biniak
S.
(1987 ) Adsorp. Sci. Technol. 4 , 105 .
8.
Garbacz
J.K.
Cysewski
P.
Biniak
S.
(1989 ) Pol. J. Chem. 63 , 205 .
9.
Garbacz
J.K.
Ziółkowska
D.
Świątkowski
A.
(1992 ) Proc. Conf. Carbon '92 , Essen, Germany .
10.
Garbacz
J.K.
Ziółkowska
D.
Świątkowski
A.
(1993 ) Proc. 3rd Int. Symp. Sep. Technol. , Antwerp, Belgium .
11.
Garbacz
J.K.
Cysewski
P.
Biniak
S.
Świątkowski
A.
(1986 ) Adsorp. Sci. Technol. 3 , 253 .
12.
Kipling
J.J.
Peakal
D.B.
(1956 ) J. Chem. Soc. 4828 .
13.
Manes
M.
Hofer
J.L.
(1969 ) J. Phys. Chem. 73 , 584 .
14.
Ościk
J.
Dąbrowski
A.
Jaroniec
M.
Rudziński
W.
(1976a ) J. Colloid Interface Sci . 56 , 91 .
15.
Ościk
J.
Dąbrowski
A.
Sokołowski
S.
Jaroniec
M.
(1976b ) J. Catal. Hokkaido Univ. 23 , 91 .
16.
Sircar
S.
Myers
A.L.
(1973 ) AIChE J . 19 , 159 .
17.
Wöhleber
D.A.
Manes
M.
(1971a ) J. Phys. Chem. 75 , 61 .
18.
Wöhleber
D.A.
Manes
M.
(1971b ) J. Phys. Chem. 75 , 3720 .
19.
Ziółkowska
D.
(1999 ) Adsorp. Sci. Technol. 17 , 479 .
20.
Ziółkowska
D.
Garbacz
J.K.
(1997 ) Adsorp. Sci. Technol. 3 , 155 .