Column kinetics for metal removal could be described more adequately by a modified dose–response model than by the Thomas model or Bohart–Adams model conventionally used. The new empirical model can be used either in a linearized form or a non-linearized form. Use of the model minimizes the error resulting from use of the Thomas model, especially at lower or higher time periods of the breakthrough curve.
References
1.
BenefieldL.D.JudkinsJ.F.WeandB.L. (1982) Process Chemistry for Water and Wastewater Treatment, Prentice-Hall, Inc., Englewood Cliffs, NJ, USA, pp. 381–402.
2.
BohartG.S.AdamsE.Q. (1920) J. Am. Chem. Soc.42, 523.
3.
ChatterjeeS.PriceB. (1977) Regression Analysis by Example, John Wiley & Sons, Inc., New York, pp. 177–180.
KapoorA.ViraraghavanT. (1998) Water Res. 32, 1968.
8.
KeinathT.M.WeberW.J.Jr. (1968) J. Water Pollut. Control Fed.40, 741.
9.
KratochvilD.VoleskyB.DemopoulisG. (1997) Water Res. 31, 2327.
10.
MyersR.H. (1986) Classic and Modern Regression with Applications, PWS Publishers, Boston, MA, USA, pp. 197–200.
11.
NeterJ.WassermanW. (1974) Applied Linear Statistical Models: Regression Analysis of Variance, and Experimental Design, Richard D. Irwin, Inc., Homewood, IL, USA, pp. 329–335.
12.
ReynoldsT.D.RichardsP.A. (1996) Unit Operation and Processes in Environmental Engineering, 2nd Edn, PWS Publishers, Boston, MA, USA.
13.
SalsburgD.S. (1986) Statistics for Toxicologists, Marcel Dekker, Inc., New York.
14.
SpintiM.ZhuangH.TrujilloE.M. (1995) Water Environ. Res.67, 943.