Alkylammonium chlorides whose adsorption/micelle energetic ratio (AMER) is close to unity are those adsorbed most effectively on the surface of a solid carrier (adsorbent). A change in the solution pH leads to a change in the hydrocarbon chain length of the alkylammonium chlorides with AMER values close to unity and hence to a positive change on the length of the hydrocarbon chain adsorbed on the carrier surface.
References
1.
AbramsonA.A.GayevoyG.M. (1979) Surfactants, Khimia, Leningrad (in Russian).
2.
AlexandrovichH.M.MozheykoF.F.KorshukE.F.MarkinA.D. (1983) The Physical Chemistry of Selective Flotation of Potassium Salts, Nauka i Tekhnika, Minsk (in Russian).
3.
EmersonM.F.HoltzerA.J. (1965) J. Phys. Chem.69, 3718.
4.
KoganovskyA.M.KlimenkoN.A. (1978) Physicochemical Fundamentals of Surfactant Extraction from Aqueous Solutions and Sewage, Kiev (in Russian).