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Abstract

Titanium-doped mobile crystalline material-41s (MCM-41s) and Fe- and Ti-doped MCM-41s were synthesized by direct thermal synthesis at moderate Ti and small Fe doping amounts, and their structural and porous properties were examined by X-ray diffraction, nitrogen adsorption, and ultraviolet-visible absorption techniques. It was found that a moderate Ti addition condition is required to introduce Ti species into the framework of silica walls without losing the regular mesoporous structure. Further Fe incorporation into Ti-doped MCM-41 modifies the mixed phase–doped structure and shifts the absorption edge to the visible light range. By appropriately choosing synthesis conditions, it is possible to incorporate both Ti and Fe in MCM-41 without sacrificing the ordered mesoporosity and the high specific surface area while greatly improving the light absorption properties.

References

Anpo

(2004) Bull. Chem. Soc. Jpn. 77, 1427.

Anpo

and Che

(1999) Adv. Catal. 44, 119.

Awate

S.V.

Jacob

N.E.

Deshpande

S.S.

Gaydhankar

T.R.

and Belhekar

A.A.

(2005) J. Mol. Catal. A: Chem. 226, 149.

Bagshaw

S.A.

Di-Renzo

and Fajula

(1996) Chem. Commun. 2209.

Belheker

A.A.

Awate

S.V.

and Anand

(2002) Catal. Commun. 3, 453.

Blasco

Corma

Navarro

M.T.

and Pariente

J.P.

(1995) J. Catal. 156, 65.

Contier

and Tuel

(1995) J. Catal. 157, 124.

Corma

Navarro

M.T.

and Perez-Pariente

(1994) J. Chem. Soc. Chem. Commun. 147.

Dagan

and Tomkiewicz

(1993) J. Phys. Chem. 97, 12651.

10.

Da Silva

J.P.

Machado

Ferreira I.

Lourenco

J.P.

and Ferreira

Vieira L.F.

(2006) Microporous Mesoporous Mater. 89, 143.

11.

Y.J.

Kim

J.H.

Park

J.H.

Park

S.S.

Hong

S.S.

Suh

C.S.

and Lee

G.D.

(2005) Catal. Today 101, 299.

12.

Fox

M.A.

Doan

K.E.

and Dulay

M.T.

(1994) Res. Chem. Intermed. 20, 711.

13.

Green

K.J.

and Rudham

(1993) J. Chem. Soc., Faraday Trans. 89, 1867.

14.

Hoffmann

M.R.

Martin

S.T.

Choi

W.Y.

and Bahnemann

D.W.

(1995) Chem. Rev. 95, 69.

15.

Koyano

K.A.

and Tatsumi

(1997) Microporous Mater. 10, 259.

16.

Kresge

C.T.

Leonowicz

M.E.

Roth

W.J.

Vartuli

J.C.

and Beck

J.S.

(1992) Nature 359, 710.

17.

Krishna

R.M.

Prakash

A.M.

and Kevan

(2000) J. Phys. Chem. B 104, 1796.

18.

Litter

M.I.

and Navio

J.A.

(1996) J. Photochem. Photobiol. A 98, 171.

19.

Liu

X.-S.

K-.K.

and Thomas

J.K.

(1993) J. Chem. Soc., Faraday Trans. 89, 1861.

20.

Martin

S.T.

Herrmann

Choi

W.Y.

and Hoffmann

M.R.

(1994) J. Chem. Soc., Faraday Trans. 90, 3315.

21.

Perathoner

Lanzafame

Passalacqua

Centi

Schlogl

and Su

D.-S.

(2006) Microporous Mesoporous Mater. 90, 347.

22.

Popova

Szegedi

Cherkezova-Zheleva

Mitov

Kostova

and Tsoncheva

(2009) J. Hazard. Mater. 168, 226.

23.

Rouquerol

and Sing

K.S.W.

(1998). Adsorption by Powders and Porous Solid—Principle, Methodology and Applications, Academic Press, London.

24.

Sclafani

Palmisano

and Schiavello

(1990) J. Phys. Chem. 94, 829.

25.

Serpone

Lawless

Khairutdinov

and Pelizzetti

(1995). J. Phys. Chem. 99, 16655.

26.

Sung-Suh

H.M.

Luan

Z.-H.

and Kevan

(1997). J. Phys. Chem. B 101, 10455.

27.

Szegedi

Popova

and Lazar

(2011) React. Kinet., Mech. Catal. 104, 291.

28.

Tanev

P.T.

Chibwe

and Pinnavaia

T.J.

(1994) Nature 368, 321.

29.

Torimoto

Ito

Kuwabata

and Yoneyama

(1996) Environ. Sci. Technol. 30, 1275.

30.

Uphade

B.S.

Yamada

Akita

Nakamura

and Haruta

(2001) Appl. Catal. A215, 137.

31.

Wang

C.-Y.

Bahnemann

D.W.

Dohrmann

J.K.

(2000) Chem. Commun. 1539.

32.

Wang

J.-A.

Limas-Ballesteros

Lopez

Moreno

Gomez

Novaro

and Bokhimi

(2001) J. Phys. Chem. B 105, 9692.

33.

Wang

X.-X.

Lian

W.-H.

X.-Z.

Basset

J.M.

and Lefebvre

(2006) J. Catal. 238, 13.

34.

Zhang

Cheng

Wang

Sun

Han

and Kong

(2012) Microporous Mesoporous Mater. 162, 51.

35.

Y.-M.

and Langford

C.H.

(1995) J. Phys. Chem. 99, 11501.

36.

Zhang

Z.-B.

Wang

C.-C.

Zakaria

and Ying

J.Y.

(1998) J. Phys. Chem. B 102, 10871.

Synthesis and Characterization of Mobile Crystalline Material-41 Doped with Titanium and Iron

Abstract

References