The stabilization of formate and acetate surface species on Pd(111) has been studied by temperature-programmed desorption and infrared reflection absorption spectroscopy (IRRAS). In addition to the previously reported stabilization of carboxylate species by the pre-adsorption of oxygen, an even bigger stabilizing effect was observed upon the adsorption of carbon monoxide onto formate- and acetate-covered surfaces. The presence of carbon monoxide delays the decomposition of carboxylate species by blocking surrounding sites. Proper use of co-adsorbed species could help to improve selectivity or activity in heterogeneous catalytic reactions.
References
1.
AasN. and BowkerM. (1993) J. Chem. Soc., Faraday Trans. 89, 1249.
2.
AasN.LiY.X. and BowkerM. (1991) J. Phys. Condens. Matter3S281.
3.
BowkerM.MorganC. and CouvesJ. (2004) Surf. Sci.555, 145.
4.
CalazaF.StacchiolaD.NeurockM. and TysoeW.T. (2005) Surf. Sci.598, 263.
5.
CalazaF.StacchiolaD.NeurockM. and TysoeW.T. (2010a) J. Am. Chem. Soc.132, 2202.
6.
CalazaF.StacchiolaD.NeurockM. and TysoeW.T. (2010b) Catal. Lett.138, 135.
7.
ConradH.ErtlG. and KuppersJ. (1978) Surf. Sci.76, 323.
8.
ConradH.ErtlG.KuppersJ. and LattaE.E. (1977) Surf. Sci.65, 245.
9.
DavisJ.L. and BarteauM.A. (1989) Langmuir5, 1299.
10.
DavisJ.L. and BarteauM.A. (1991) Surf. Sci.256, 50.
11.
GaoF.WangY.L.CalazaF.StacchiolaD. and TysoeW.T. (2008) J. Mol. Catal. A281, 14.
12.
GarciaA.R.da SilvaJ.L. and IlharcoL.M. (1998) Surf. Sci.415, 183.
13.
Global Data (2011) “Acetic Acid: World Supply Outweighs Demand” (31 January).
14.
HaleyR.D.TikhovM.S. and LambertR.M. (2001) Catal. Lett.76, 125.
15.
HansenE. and NeurockM. (2001) J. Phys. Chem. B105, 9218.
16.
JamesJ.SaldinD.K.ZhengT.TysoeW.T. and ShollD.S. (2005) Catal. Today105, 74.
17.
JeroroE. and VohsJ.M. (2009) Catal. Lett.130, 271.
18.
KaltchevM.ThompsonA.W. and TysoeW.T. (1997) Surf. Sci.391, 145.
19.
KrauseP.F.KatonJ.E.RogersJ.M. and PhillipsD.B. (1977) Appl. Spectrosc. 31, 110.
20.
LiZ.J.GaoF. and TysoeW.T. (2008) Surf. Sci.602, 416.
21.
StacchiolaD. and TysoeW.T. (2002) Surf. Sci.513L431.
22.
StacchiolaD.BurkholderL. and TysoeW.T. (2002a) J. Am. Chem. Soc.124, 8984.
23.
StacchiolaD.BurkholderL. and TysoeW.T. (2002b) Surf. Sci.511, 215.
24.
StacchiolaD.CalazaF.BurkholderL. and TysoeW.T. (2004) J. Am. Chem. Soc.126, 15384.
25.
StacchiolaD.KaltchevM.WuG. and TysoeW.T. (2000) Surf. Sci.470L32.
26.
StacchiolaD.ThompsonA.W.KaltchevM. and TysoeW.T. (2002c) J. Vac. Sci. Technol. A20, 2101.
27.
StacchiolaD.WuG.KaltchevM. and TysoeW.T. (2001) J. Chem. Phys.115, 3315.
28.
StacchiolaD.CalazaF.BurkholderL.SchwabacherA.W.NeurockM. and TysoeW.T. (2005) Angew. Chem., Int. Ed. Engl.44, 4572.
29.
TeschnerD.BorsodiJ.WootschA.RevayZ.HaveckerM.Knop-GerickeA.JacksonS.D. and SchloglR. (2008) Science320, 86.
30.
WeltnerW. (1955) J. Am. Chem. Soc.77, 3941.
31.
WuG.StacchiolaD.CollinsM. and TysoeW.T. (2000) Surf. Rev. Lett.7, 271.
32.
ZhengT.StacchiolaD.SaldinD.K.JamesJ.ShollD.S. and TysoeW.T. (2005) Surf. Sci.574, 166.
