A general kinetic theory, which takes explicit account of the phenomena occurring at reconstructible surfaces while adsorption or desorption proceed, is proposed. The theory contains a few free parameters which specify the adsorption and desorption rate constants, and the reconstruction and irreversibility degrees of the process.
References
1.
AcharyaR. and SwamyP.N. (1994) J. Phys. Chem. A27, 7247.
2.
AvnirD.FarinP. and PfeiferP. (1983) J. Chem. Phys.79, 3566.
3.
AvnirD. and JaroniecM. (1989) Langmuir5, 1431.
4.
ByczukK.SpalekJ.JoyceG.S. and SarkarS. (1995) Acta Phys. Pol. B26, 2167.
5.
CerofoliniG.F. (1971) Surf. Sci.24, 391.
6.
CerofoliniG.F. (1972) J. Low Temp. Phys.6, 473.
7.
CerofoliniG.F. (1974) Thin Solid Films23, 129.
8.
CerofoliniG.F. (1975) Surf. Sci.51, 333.
9.
CerofoliniG.F. (1976a) J. Low Temp. Phys.23, 687.
10.
CerofoliniG.F. (1976b) Surf. Sci.61, 678.
11.
CerofoliniG.F. (1978) Chem. Phys.33, 423.
12.
CerofoliniG.F. (1982) J. Colloid Interface Sci.86, 204.
13.
CerofoliniG.F. (1983) in Colloid Science, Vol. 4, EverettD.H., Ed, Specialist Periodical Reports, Royal Society of Chemistry, London, Chap. 2, pp. 59–83.
14.
CerofoliniG.F. (1995) in Adsorption on New and Modified Inorganic Sorbents, DabrowskiA.TertykhV., Eds, Elsevier, Amsterdam, The Netherlands, Chap. 2, pp. 435–464.
CerofoliniG.F. (2006) J. Phys. A: Math. Gen.39, 3195.
18.
CerofoliniG.F. and CerofoliniM. (1980) J. Colloid Interface Sci.78, 65.
19.
CerofoliniG.F. and ReN. (1993) Riv. Nuovo Cimento16, 1.
20.
CerofoliniG.F. and RudzińskiW. (1997) in Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces, RudzińskiW.SteeleW.A.ZgrablichG., Eds, Elsevier, Amsterdam, The Netherlands, pp. 1–103.
21.
ColyvanM. (2001) Synthese127, 265.
22.
FraenkelA.A. (1955) Integers and Theory of Numbers, Yeshiva University, New York State: Republished in 2004 by Dover Press, Mineola, NY, U.S.A.
23.
HaldaneF.D.M. (1991) Phys. Rev. Lett.67, 937.
24.
HillT.L. (1960) An Introduction to Statistical Thermodynamics, Addison-Wesley, Reading, MA, U.S.A.
25.
JaielloJ. and SchwarzJ.A. (1991) J. Colloid Interface Sci.146, 415.
26.
JaroniecM. (1975) Surf. Sci.50, 553.
27.
JaroniecM. and BräuerP. (1986) Surf. Sci. Rep.6, 65.
28.
JaroniecM. and MadeyR. (1988) Physical Adsorption on Heterogeneous Solids, Elsevier, Amsterdam, The Netherlands.
29.
JaroniecM.SokolowskiS. and CerefoliniG.F. (1976) Thin Solid Films31, 321.
30.
LandsbergP.T. (1962) J. Appl. Phys.33, 2251.
31.
LandsbergP.T. (1978) Thermodynamics and Statistical Mechanics, Oxford University Press, Oxford, U.K., p. vi.
32.
LangmuirI. (1918) J. Am. Chem. Soc.40, 1361.
33.
MaddyP. (1988a) J. Symbolic Logic53, 481.
34.
MaddyP. (1988b) J. Symbolic Logic53, 736.
35.
MayagoitiaV.RojasF.RiccardoJ.L.PereyraV.D. and ZgrablichG. (1990) Phys. Rev. B41, 7150.
36.
MonodJ.WymanJ. and ChangeuxJ.P. (1965) J. Mol. Biol.12, 88.
37.
NewkomeG.R.MoorefieldC.N. and VögtlF. (2001) Dendrimers and Dendrons. Concepts, Syntheses, Applications, Wiley–VCH, Weinheim, Germany.
38.
PfeifferP. and AvnirD. (1983) J. Chem. Phys.79, 3558; Erratum (1984): J. Chem. Phys.80, 4573.
39.
PfeifferP. and LiuK.-Y. (1997) in Equilibria and Dynamics of Gas Adsorption on Heterogeneous Solid Surfaces, RudzińskiW.SteeleW.A.ZgrablichG., Eds, Elsevier, Amsterdam, The Netherlands, pp. 625–677.
40.
PfeifferP.ObertM. and ColeM.W. (1989) Proc. R. Soc. London, Ser. A423, 169.
41.
PincockC. (2010) in Internet Encyclopedia of Philosophy, FieserJ.DowdenB., Eds, item published on February 26, 2010, and downloaded from http://www.iep.utm.edu/ on January 1, 2011.
42.
RiccardoJ.L.Ramirez-PastorA.J. and RomáF. (2004) Phys. Rev. Lett.93, 186101/1–4.
43.
RudzińskiW. and EverettD.H. (1992) Adsorption of Gases on Heterogeneous Surfaces, Academic Press, London, U.K.
44.
RudzińskiW.JagielloJ. and GrilletY. (1982) J. Colloid Interface Sci.87, 478.
45.
RudzińskiW.LeeS.-L.YanSanders C.-C. and PanczykT. (2001) J. Phys. Chem. B105, 10847.
46.
SteeleW.A. (1974) The Interaction of Gases with Solid Surfaces, Pergamon Press, Oxford, U.K.
47.
WignerE.P. (1960) Commun. Pure Appl. Math.13, 1.
48.
ZgrablichG.MayagoitiaV.RojasF.BulnesF.GonzalezA.P.NazzarroM.PereyraV.Ramirez-PastorA.J.RiccardoJ.L. and SapagK. (1996a) Langmuir12, 129.
49.
ZgrablichG.ZuppaC.CiaceraM.RiccardoJ.L. and SteeleW.A. (1996b) Surf. Sci.356, 257.