Sage Journals: Discover world-class research

Abstract

The standardisation of eight partial least squares calibration models for the prediction of diesel oil properties was studied. The models were developed using spectra acquired on a laboratory accousto-optic tunable filter (AOTF) near infrared (NIR) spectrophotometer (with a quartz cuvette) and transferred to another AOTF-NIR spectrophotometer (with a fibre-optic probe) and to an Fourier transform NIR spectrometer, both designed for on-line application. Thirteen standardisation methods, using different approaches, were studied: standardisation by the pretreatment of spectra, (piecewise) direct standardisation and (piecewise) reverse standardisation. The reverse approach proved to be the best strategy to transfer the models.

Keywords

near infrared spectroscopy chemometrics standardisation diesel oil

Get full access to this article

View all access options for this article.

References

McClure

W.F.

, Anal. Chem. 66, 43A (1994).

Workman

J.J.

, Appl. Spectrosc. Rev. 31, 251 (1996).

Burns

D.A.

and Margoshes

, Handbook of NIR Technology. Marcel Dekker, New York, USA (1992).

Lavine

B.K.

Sum

S.T.

Brown

S.D.

and Despagne

, Anal. Chem. 68, 21R (1996).

Geladi

and Dabakk

, J. Near Infrared Spectrosc. 3, 119 (1995).

Miller

J.N.

, Analyst 118, 455 (1993).

Guchardi

Filho

P.A.C.

Poppi

R.J.

and Pasquini

, J. Near Infrared Spectrosc. 6, 333 (1998).

and Chung

, Appl. Spectrosc. 53(5), 557 (1999).

Espinosa

Lambert

and Valleur

, Hydrocarbon Processing, February issue (1995).

10.

Parisi

A.F.

Nogueiras

and Prieto

, Anal. Chim. Acta 238, 95 (1990).

11.

Kelly

J.J.

Barlow

C.H.

Jingujii

T.M.

and Callis

J.B.

, Anal. Chem. 61, 313 (1989).

12.

Callis

J.B.

Illman

D.L.

and Kowalski

B.R.

, Anal. Chem. 59(9), 624A (1987).

13.

de Noord

O.E.

, Chemom. Intell. Lab. Syst. 25, 85 (1994).

14.

Bouveresse

and Massart

D.L.

, Vib. Spectrosc. 11, 604 (1996).

15.

Dean

and Isaksson

, NIR news 4(2), 8 (1993).

16.

Dean

and Isaksson

, NIR news 4(4), 14 (1993).

17.

de Noord

O.E.

, Chemom. Intell. Lab. Syst. 23, 65 (1994).

18.

Haaland

D.M.

Adhihetty

I.S.

McGuire

J.A.

Wangmaneerat

and Niemczyk

T.M.

, Anal. Chem. 63, 2329 (1991).

19.

Adams

M.J.

, Chemometrics in Analytical Spectroscopy. RSC, London, UK (1995).

20.

Osborne

B.G.

, Analyst 113, 263 (1998).

21.

Barnes

R.J.

Dhanoa

M.S.

and Lister

S.J.

, Appl. Spectrosc. 43(5), 772 (1989).

22.

Wang

Lysaght

M.J.

and Kowalski

B.R.

, Anal. Chem. 63, 2750 (1991).

23.

Wang

Dean

and Kowalski

B.R.

, Anal. Chem. 67, 2379 (1995).

24.

Shenk

J.S.

and Westherhaus

M.O.

, NIR news 4(1), 13 (1993).

25.

Wang

Dean

and Kowalski

B.R.

, Anal. Chem. 64, 562 (1992).

26.

Lima

F.S.G.

, Master Thesis, Instituto Militar de Engenharia, Brazil (2000).

27.

Lin

and Brown

C.W.

, Anal. Chim. Acta 349, 263 (1997).

28.

Beebe

K.R.

, Chemometrics: A Practical Guide. John Wiley & Sons, Chichester, UK (1997).

29.

Martens

and Næs

, Multivariate Calibration. John Wiley & Sons, Chichester, UK (1991).

Evaluation of Standardisation Methods of near Infrared Calibration Models

Abstract

Keywords

Get full access to this article

References