Abstract
Multi-quanta vibrational transitions are discussed in terms of the local mode model in order to develop a better understanding of the features observed in the short-wave near infrared (700–1100 nm) spectra of organic liquids. It is demonstrated that the spectra of simple alkanes and alcohols exhibit local mode features, and that these features are characteristic of molecular structure and will, therefore, be useful for quantitative and qualitative analysis.
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References
1.
Schrieve
G.D.
Melish
G.G.
and
Ullman
A.H.
, Appl. Spectrosc. 45 , 711 (1991 ).
2.
Schrieve
G.D.
and
Ullman
A.H.
, Appl. Spectrosc. 45 , 713 (1991 ).
3.
Rosenthal
R.D.
, US Patents 4,404,602 (1983 ), and 4,466,076 (1984 ).
4.
Phelan
M.K.
Barlow
C.H.
Kelly
J.J.
Jinguji
T.M.
and
Callis
J.B.
, Anal. Chem. 61 , 1419 (1989 ).
5.
Kelly
J.J.
Barlow
C.H.
Jinguji
T.M.
Callis
J.B.
, Anal. Chem. 61 , 313 (1989 ).
6.
Mayes
D.M.
and
Callis
J.B.
, Appl. Spectrosc. 43 , 27 (1989 ).
7.
Herzberg
G.
, Infrared and Raman Spectra of Polyatomic Molecules. , Van Nostrand , New York (1945 ).
8.
Wilson
E.B.
Decius
J.C.
and
Cross
P.C.
, Molecular Vibrations. , Dover Publications , New York (1955 ).
9.
Ellis
J.W.
, Trans. Faraday Soc. 25 , 888 (1928 ).
10.
Bray
R.G.
and
Berry
M.J.
, J. Chem. Phys. 71 , 4909 (1979 ).
11.
Heller
D.F.
and
Mukamel
S.
, J. Chem. Phys. 70 , 463 (1979 ).
12.
Spears
K.G.
and
Rice
S.A.
, J. Chem. Phys. 55 , 5561 (1971 ).
13.
Henry
B.R.
and
Siebrand
W.
, J. Chem. Phys. 49 , 5369 (1968 ).
14.
Hayward
R.J.
Henry
B.R.
and
Siebrand
W.
, J. Mol. Spectrosc. 46 , 207 (1973 ).
15.
Hayward
R.J.
and
Henry
B.R.
, J. Mol. Spectrosc. 50 , 58 (1974 ).
16.
Hayward
R.J.
and
Henry
B.R.
, J. Mol. Spectrosc. 57 , 221 (1975 ).
17.
Henry
B.R.
, Acc. Chem. Res. 10 , 207 (1977 ).
18.
Burberry
M.S.
and
Albrecht
A.C.
, J. Chem. Phys. 71 , 4631 (1979 ).
19.
Child
M.S.
, Acc. Chem. Res. 18 , 45 (1985 ).
20.
Duncan
J.L.
, Spectrochim. Acta 47A , 1 (1991 ).
21.
Mills
I.M.
and
Robiettte
A.G.
, Mol. Phys. 85 , 743 (1985 ).
22.
Henry
B.R.
, in Vibrational Spectra and Structure , Ed. by
Durig
J.R.
Elsevier , New York (1981 ).
23.
Siebrand
W.
and
Williams
D.F.
, J. Chem. Phys. 49 , 1860 (1968 ).
24.
Fang
H.L.
Meister
D.M.
and
Swofford
R.L.
, J. Chem. Phys. 88 , 410 (1984 ).
25.
Bellamy
L.J.
and
Mayo
D.W.
, J. Chem. Phys. 80 , 1217 (1976 ).
26.
Bellamy
L.J.
, Appl. Spectrosc. 33 , 439 (1979 ).
27.
Fang
H.L.
and
Swofford
R.L.
, Appl. Optics 21 , 55 (1982 ).
28.
Fang
H.L.
and
Compton
D.A.C.
, J. Phys. Chem. 92 , 7185 (1988 ).
29.
Fermi
E.
, Z. Physik. 71 , 250 (1931 ).
30.
Darling
B.T.
and
Dennisen
D.M.
, Phys. Rev. 57 , 128 (1940 ).
31.
Olinger
J.M.
, PhD Dissertation , University of California , Riverside (1989 ).
32.
Henry
B.R.
Hung
I.
MacPhail
R.A.
and
Strauss
H.L.
, J. Am. Chem. Soc. 102 , 515 (1980 ).
33.
Fang
H.L.
and
Swofford
R.L.
, J. Chem. Phys. 73 , 2607 (1980 ).