Abstract
The metal complexation of the hydroxyanthraquinones, chrysotalunin, chrysophanol and their derivatives, with Al3+, Ni2+ and Zn2+ was studied by electrospray ionization mass spectrometry (ESI-MS). The results showed that chrysophanol and its derivatives form metal complexes with Al3+, Ni2+ and Zn2+ ions, but chrysotalunin does not. Among the metal ions, Al3+ was found to form the complexes most easily.
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References
1.
Thomson
R.H.
, Naturally occurring quinines III, Recent Advances (3rd Edn ). Chapman and Hall , New York, USA , pp. 347 –526 (1987 ).
2.
Bosch
R.
Friederich
U.
Lutz
W.K.
Brocker
E.
Bachmann
M.
Schlatter
Ch.
, Mutation Research 188 , 161 (1987 ).
3.
Liberman
D.F.
Schaefer
F.L.
Fink
R.C.
Ramgopal
M.
Ghosh
A.C.
Mulcahy
R.
, Applied and Environmental Microbiology 476 (1980 ).
4.
Sendelbach
L.E.
, Toxicology 57 , 227 (1989 ).
5.
Inoue
M.
Nishimura
H.
Li
H.-H.
Mizutani
J.
, J. Chem. Ecol. 18 , 1833 (1992 ).
6.
Engstrom
G.W.
McDorman
D.J.
Maroney
M.J.
, J. Agric. Food Chem. 28 , 1139 . (1980 ).
7.
Suzuki
T.
Fujitake
N.
Oji
Y.
, Soil Sci. Plant Nutr. 45 , 297 (1999 ).
8.
Fujitake
N.
Azuma
J.
Hamasaki
T.
, Soil Sci. Plant Nutr. 38 , 579 (1992 ).
9.
Salinas
F.
de la Pena
A. Munoz
Murillo
J.A.
, Analyst 109 , 1135 (1984 ).
10.
Kumada
K.
, in Chemistry of Soil Organic Matter . Japan Scientific Society Press , Tokyo, Japan , pp. 1 –241 (1987 ).
11.
Monities
B.
Marine-Font
A.
Douilland
R.
, Ann. Physiol. Veg. 11 , 313 (1969 ).
12.
Inderjit
B.
Nishimura
H.
, Anal. Appl. Biol. 135 , 425 (1999 ).
13.
Vukomanovic
D.V.
Stone
J.A.
van Loon
G.W.
Nakatsu
K.
Zoutman
D.E.
, Spectrochim. Acta, B 53 , 893 (1998 ).
14.
Reviewer's suggestion.
15.
Li
H.
Siu
K.W.M.
Guevremont
R.
Le Blanc
J.C.Y.
, J. Am. Soc. Mass Spectrom. 8 , 781 (1997 ).
16.
Chu
I.K.
Guo
X.
Lau
T.-C.
Siu
K.W.M.
, Anal. Chem. 71 , 2364 (1999 ).
17.
Sible
E.M.
Brimmer
S.P.
Leary
J.A.
, J. Am. Soc. Mass Spectrom. 8 , 32 (1997 ).
18.
Konig
S.
Leary
J.A.
, J. Am. Soc. Mass Spectrom. 9 , 1125 (1998 ).
19.
Asam
M.R.
Glish
G.L.
, J. Am. Soc. Mass Spectrom. 8 , 987 (1997 ).
20.
Hsu
F.-F.
Bohrer
A.
Turk
J.
, J. Am. Soc. Mass Spectrom. 9 , 516 (1998 ).
21.
Veenstra
T.D.
Johnson
K.L.
Tomlinson
A.J.
Craig
T.A.
Kumar
R.
Naylor
S.
, J. Am. Soc. Mass Spectrom. 9 , 8 (1998 ).
22.
Deng
H.
van Berkel
G.J.
, J. Mass Spectrom. 33 , 1080 (1998 ).
23.
Satterfield
M.
Brodbelt
J.S.
, Anal. Chem. 72 , 5898 (2000 ).
24.
Alvarez
E.J.
Vartanian
V.H.
Brodbelt
J.S.
, Anal. Chem. 69 , 1147 (1997 ).
25.
Pearson
R.G.
, J. Am. Chem. Soc. 85 , 3533 (1963 ).
