Abstract
Linear free energy relationships (LFER) from collision-activated dissociations (CADs) have been uncovered from electrospray mass spectra of dinucleating macrocyclic ligands involving Cu and Ag transition metal ions. In particular, the electrospray mass spectral method for the determination of stability constants has been explored. The LFERs are interpreted in terms of two collision models, both of which underlie a broader class of investigations.
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