Attempts to gain access to an indirect mass spectrometric characterization of dimeric [60]fullerene derivatives such as C119, C120 and C120O have been made. By exploring the ability of different hosts to form host–guest complexes with [60]fullerene derivatives it was intended to obtain products which could be analyzed by fast-atom bombardment (FAB) mass spectrometry. γ-Cyclodextrin (CD) and several calixarenes have been tried as potential hosts, but only CD was capable of forming the desired complexes in some cases. Besides the well-known complex [2CD + C60], prepared for testing purposes, we report, for the first time, the formation and FAB mass spectra of [2CD + C60O] and [2CD + C60O2].
GromovA.BallenwegS.KrätschmerW.LebedkinS., in Fullerenes and Fullerene Nanostructures, Ed by KuzmanyH.FinkJ.MehringM.RothS., World Scientific, Singapore, p. 460 (1996).
BallenwegS.GrossJ.LebedkinS.KrätschmerW.GleiterR.ReschM., Poster Presentation P08, 28th AGMS-Tagung.Tübingen, Germany, June 1995.
23.
GrossJ.BallenwegS.GromovA.KrätschmerW., Oral Presentation V41, 29th AGMS-Tagung.Bremen, Germany, May 1996.
24.
BraunT., Fullerene Science and Technology5, 1291 (1997).
25.
MeiliJ.SeiblJ., Org. Mass Spectrom.19, 581 (1984).
26.
The symbol M will be used for monoisotopic masses and M, for isotopic average molecular weights which apply to isotopically unresolved signals.
27.
MillerJ.M.ChenL.-Z., Rapid Commun. Mass Spectrom.6, 184 (1992).
28.
BeckR.D.WelsP.HirschA.LamparthI., J. Phys. Chem.98, 9683 (1994).
29.
DengJ.-P.MouC.-Y.HanC.-C., in Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials, Ed by RuoffR.S.KadishK.M., Am. Electrochem. Soc., Pennington, p. 1409 (1995).
30.
McElvanyS.W.JohnsonE.A.HollimanC.L., in Recent Advances in the Chemistry and Physics of Fullerenes and Related Materials, Ed by RuoffR. S.KadishK. M., Am. Electrochem. Soc., Pennington, p. 1425 (1995).
31.
Van CleempoelA.GijbelsR.ClaeysM.Van den HeuvelH., Rapid. Commun. Mass Spectrom.10, 1579 (1996).
32.
FriedmanL.LongF.A., J. Am. Chem. Soc.75, 2832 (1952).
33.
BowenR.D.HarrisonA.G., Org. Mass Spectrom.16, 180 (1981).
34.
SchlotterF., PhD thesis.University of Heidelberg, 1997.
35.
SchätzR.WeberC.SchillingG.OeserT.Huber-PatzU.IrngartingerH.von der LiethC. W.PiepkornR., Liebigs Ann.1401 (1995).
