The fragmentation pattern of C70+• in its collision with He has been studied in order to derive an explanation for recent observations on tremendous differences in relative intensities and extent of fragmentation upon variation of the centre-of-mass collision energy.
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References
1.
The Int. J. Mass Spectrom. Ion Processes has devoted a whole issue—138 (1994) “Fullerenes, Carbon and Metal—Carbon Cluster Ions“—to this topic.
2.
McElvanyS.W.RossM.M., J. Am. Soc. Mass Spectrom.3, 268 (1992).
3.
SchwarzH.WeiskeT.BöhmeD.K.HrusákJ., in Buckminsterfullerenes, Ed. by BillupsW.E.CiufoliniM.A.. VCH Publishers, New York, pp. 257–283 (1993), and references therein.
4.
CaldwellK.A.GiblinD.E.GrossM.L., J. Am. Chem. Soc.114, 3743 (1992).
5.
KleiserR.SprangH.FurrerS.CampbellE.E.B., Z. Phys. D28, 89 (1993), and references cited therein.
The maximum energy available to be transferred to the internal degrees of freedom of an ion that collides with an atom is given by the centre-of-mass collision energy, Ecm: Ecm = ma (ma + mion)-1 Eion, with m being the mass of the atom (ma) and the ion (mion) and Eion representing the translational energy of the ion.
12.
TakayamaM.ShinoharaH., Fullerene Sci. and Technol.2, 165 (1994).
13.
LeziusM.ScheierP.FoltinM.DünserB.RauthT.AkimovV.M.KrätschmerW.MärkTD., Int. J. Mass Spectrom. Ion Processes129, 49 (1993).
14.
StachJ.MöderM.HerzschuhR., Z. Chem.30, 157 (1990).
15.
DrewelloT.HerzschuhR.StachJ., Z. Phys. D28, 339 (1993).
16.
CoxD.M.BehalS.DiskoM.GorunS.M.GreaneyM.HsuC.S.KollinE.B.MillarJ.RobbinsJ.RobbinsW.SherwoodR.D.TindallP., J. Am. Chem. Soc.113, 2940 (1991).
17.
LifshitzC.LaskinJ.PeresT., Org. Mass Spectrom.28, 1001 (1993).
18.
YuD.H.AndersenL.H.BrinkC.HvelplundP., Z. Phys. D29, 53 (1994).
19.
DrewelloT.AsmusK.-D.StachJ.HerzschuhR.KaoM.FooteC.S., J. Phys. Chem.95, 10554 (1991).
20.
RossM.M.CallahanJ.H., J. Phys. Chem.95, 5720 (1991).
21.
BruinsA.P.JenningsK.R., Int. J. Mass Spectrom. Ion Phys.26, 395 (1978).
22.
EllerK.DrewelloT., Org. Mass Spectrom.28, 1462 (1993).
23.
At present there are very few sector-field mass spectrometers for which these considerations are not valid. For a set-up that can overcome these problems, see Reference 4.
24.
UggerudE.DerrickP.J., J. Phys. Chem.95, 1430 (1991).
25.
AlexanderA.J.ThibaultP.BoydR.K., J. Am. Chem. Soc.112, 2484 (1990).
26.
For similar experiments on 8 keV-C60+• colliding with He an energy shift of some 100 eV was found, see Reference 20.
27.
LufferD.R.SchramK.H., Rapid Commun. Mass Spectrom.4, 552 (1990).
28.
DoyleR.J.RossM.M., J. Phys. Chem.95, 4954 (1991).
29.
BrinkC.AndersenL.H.HvelplundP.YuD.H., Z. Phys. D29, 45 (1994).