This paper presents the development of a new strategy for the calibration of air-fuel ratio measurements in engines by laser-induced fluorescence (LIF). After a brief introduction to the LIF technique, the paper highlights the structured approach undertaken to ensure that accurate quantitative measurements were produced. In particular, the new approach to coping with the fluorescence dependency on pressure and temperature, the issues related to the choice of a fluorescence tracer, the careful determination of the optimum tracer concentration and the complete calibration methodology are described, together with the resolution of some of the obstacles encountered. The paper concludes with some examples of calibrated measurements accompanied by a comparison of the results with combustion and emission performances. These results show a very good correlation.
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