Abstract
With no element has there ever been such a spectacular leap to fame as with germanium. Twenty-five years ago it was a rare and obscure element, attracting very little attention and with no obvious uses or future. Yet, in a few years it was being intensively studied by physicist, metallurgist, electronic engineer, and chemist. It was being widely sought for, it was being produced with a purity greater than that of any other element, and it had laid the foundation for a still expanding semiconductor industry. Its congener, silicon, although one of the commonest of elements had, in its elemental form, attracted little attention, yet now it also is being closely studied and is being prepared with a purity comparable to that of germanium. Before 1948 the production of germanium was negligibly small but it now exceeds a quarter of a million pounds per annum. The production of silicon for semiconductor devices has reached similar heights.
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References
1.
A. "Properties of Elemental and Compound Semiconductors"
(edited by
Gatos
IL C.
), Metallurgical Society Conferences (Amer. Inst. Min. Met. Eng.) , Vol. 5 . 1960 : New York and London (Interscience Publishers).
2.
B. "Metallurgy of Elemental and Compound Semiconductors"
(edited by
Grubel
R. O.
), Metallurgical Society Conferences (Amer. Inst. Min. Met. Eng.) , Vol. 12 . 1981 : New York and London (Interticience Publishers).
3.
C. "Metallurgy of Semiconductor Materials"
(edited by
Schroeder
J. B.
), Metal-lurgical Society Conferences (Amer. Inst. MM. Met. Eng.) , Vol. 15 . 1962 : New York and London (John Wiley).
4.
D. "Metallurgy of Advanced Electronic Materials"
(edited by
Brock
G. E.
), Metal-lurgical Society Conferences (Amer. Inst. Min. Met. Eng.) , Vol. 19 . 1983 : New York and London (Interscience Publishers).
5.
E. "Ultmpurification of Semiconductor Materials"
(edited by
Brooks
M. S.
Kennedy
J. K.
). 1961 : New York (Macmillan Co.).
6.
Strunz
H.
Menge
G.
Geier
B. H.
, Neues Jahrb. Mineral. Manatee ., 1958 ,85 .
7.
Zemann
J.
, ibid ., 1959 , 67 .
8.
Strunz
H.
Giglio
M.
, Naturwiss ., 1959 , 46 , 489.
9.
Aubrey
K. V.
, Fuel , 1952 , 81 , 429.
10."Germanium from Coal" , [U.K.]
Dept. Ed. Indust. Research Rep ., 1957 .
11.
Stadnichenko
T.
Murata
K. J.
Zubovic
P.
Hufschmidt
E. L.
, U.S. Geol. Survey Circ . (272 ), 1953 .
12.
Corey
R. C.
Meyers
J. W.
Schwartz
C. M.
Gibson
F. H.
Colbassani
P. J.
, U.S. Bier. Mines Bull . (575 ), 1959 .
13.
Egerov
A. I.
Kalinen
S. K.
, Compt. rend. Acad. Sci. U. R.S.S ., 1940 , 26 , 925.
14.
Ralinsky
V. M.
, ibid ., 1943 , 40 , 198.
15.
Stadnichenko
T.
Murata
K. J.
Axelrod
J. M.
, Science , 1950 , 112 , 109.
16.
Headlee
A. J. W.
Hunter
R. G.
, West Virginia Geol. Econ. Survey Rep. Invest . (8 ), 1951 .
17.
Brit. Patent
No. 728 ,919 .
18.
Brit. Patent
No. 900 ,935 .
19.
Barnes
W. R.
Emblem
H. G.
, Indust. Chemist , 1961 , 37 , 385.
20.
Brit. Patent
No. 815 ,276 .
21.
Brit. Patent
No. 735 ,617 .
22.
Andrianov
K. A.
Golubtsov
S. A.
Trofimova
I. V.
, Zhur. Priklad. Khim . 1959 ,32 , 1620 .
23.
Theuerer
H. C.
, J. Ekarochem. Soc ., 1960 , 107, 29; U.S. Patent No. 3 ,071,444.
24.
Chirngaev
V. S.
, Zhur. Priklad. Khim ., 1962 , 35 , 1411 .
25.
Akerman
K.
Brafman
M.
Kruszewska
O.
Kruszewski
K.
, Nukleonika , 1962 ,7 , 635 .
26.
Brit. Patent
No. 893 ,495 .
27.
Brit. Patent
No. 906 ,617
28.
German Patent No
. 1,
028,543 .
29.
Brit. Patent
No. 867 ,871 .
30.
Misel&son
A.
, Tevelnaya Met ., 1963 , (6) , 133 .
31.
Brit. Patent
No. 745 ,698 .
32.
Brit. Patent
No. 894 ,456 .
33.
Buford
J. T.
, U.S. Dept. Commerce, Office Tech. Services , (AD
258 ,751 ), 1961 .
34.
Herrick
C. S.
Krieble
J. G.
, J . Elect rochem. Soc ., 1960 , 107 , 111.
35.
Baba
H.
Araki
H.
, Ref. E, p. 34. Si. Brit. Patents Nos. 856,137; 872,282 .
36.
Rubin
B.
Moates
O. H.
Weiner
J. R.
, J. Electrochem. Soc ., 1957 , 104 , 656.
37.
Buford
J. T.
Starks
R. J.
, Ref. E., p. 25 .
38.
Lyon
D. W.
Olson
C. M.
Lewis
E. D.
, J. Electrochem. Soc ., 1949 ,96 , 359.
39.
Patent
U.S.
No. 2,
773,745 .
40.
Patent
U.S.
No. 2,
883,269 .
41.
Brit. Patent
No. 871 ,831 .
42.
Wartenberg
H. V.
, Z. anorg. Chem ., 1951 , 265 , 186.
43.
Ono
K.
Matsushima
T.
, Sri. Rep. Research Inst. Tohoku Univ ., 1954 , [A], 6 , 477.
44.
Kamerar
B.
Grdenic
D.
, Z. anorg. Chem ., 1963 , 321 , 113.
45.
Theuerer
H. C.
, Bell Lab. Record , 1955 , 33 , 327.
46.
van der Linden
P. C.
, Rec. Tray. Chim. Pays-Bas , 1959 , 78 , 962.
47.
Brit. Patent
No. 831 ,359 .
48.
Pätz
K.
, Monatsber. deist. Alerted. Wise. Berlin , 1959 , 1 , 290 .
49.
Kurosawa
T.
Minamiya
J.
, Trans. Nat. Research Inst. Metals (Tokyo) , 1962 , 4,28 .
50.
Sheftal
N. N.
Kokorish
N. P.
Krasilov
A. V.
, hvest. Aka. Rank S.S.S.R., (Fiz .), 1957 , 21 , 140.
51.
Sangster
R. C.
Maverick
E. F.
Groutch
M. L.
, J. .Electrochem. Soc ., 1957 , 104 , 317.
52.
Siebertz
K.
Patent
U.S.
No. 3,
036,892 .
53.
Manning
B.
Patent
U.S.
No. 3,
043,667 .
54.
Szekely
G.
, J. Electrochem. Soc ., 1957 , 104 , 663 .
55.
Brit. Patent
No. 787 ,043 .
56.
Litton
F. B.
Andersen
H. C.
, J. Electrochem. Soc ., 1954 , 101 , 287.
57.
McCarty
L. V.
, ibid ., 1959 , 196 , 1036 .
58.
Ellis
R. C.
, ibid ., 1960 , 107 , 222.
59.
Baba
H.
Araki
H.
, Ref. E, p. 34 .
60.
Wajda
E. S.
Glang
R.
, Ref. B, p. 229 .
61.
Wajda
E. S.
Kippenham
B. W.
White
W. H.
, I.B.M. J. Research Develop ., 1960 , 4 , 288 .
62.
German Patent No
. 950,848 .
63.
French Patent No
. 1,
125,047 .
64.
Brit. Patent
No. 745 ,698 .
65.
Brit. Patent
No. 831 ,216 .
66.
Brit. Patent
No. 832 ,570 .
67.
Brit. Patent
No. 829 ,421 .
68.
Wilson
J. M.
, Research , 10, 166 ; 1959 , 12 , 91.
69.
Lewis
C. H.
Kelly
H. C.
Giusto
M. B.
Johnson
S.
, J. Electrochem, Soc ., 1961 , 108 , 1114 .
70.
Brit. Patents Nos. 832,333;
832,331 .
71.
Brit. Patents Nos. 871,614;
878,763 .
72.
Patent
U.S.
No. 3,
041,141 .
73.
de Pape
R.
, Ann. Clam ., 1963 , 8 , 185 .
74.
Brit. Patent
No. 831 ,289 .
75.
Jackson
H. L.
Marsh
F. D.
Muetterties
E. L.
, Inorganic Chem ., 1963 , 2 , 43.
76.
Kleshchevnikova
S. I.
, Ya. E. Pokrovsky, and E. I. Rumyantseva, Soviet Physics--Technical Physics , 1957 , 2 , 1529 .
77.
Lewis
C. H.
Giusto
M. B.
Kelly
H. C.
Johnson
S.
, Ref. E, P. 55 .
78.
O'Connor
J. A.
, Chem. Eng ., 1952 , 59, (4), 158; (5), 154, 370 .
79.
Thompson
A. P.
Musgrave
J. R.
, Trans. Amer. RA. Min. Met. Eng ., 1952 , 194 , 1132 .
80.Eng. Min. J., 1956, 157, 78 .
81.
Morrison
J.
, ibid , 1961 , 162 , 92 .
82.
Starliper
A. G.
Kenworthy
H.
Goin
P. T.
, U.S. Bur. Mines Rep. Invest . (5891 ), 1961 .
83.
Powell
A. R.
Lever
F. M.
Walpole
R. E.
, J. Appl. Chem ., 1951 , 1 , 541.
84.
Cuyper
J. A. de
, Caine Nouvelle , Numero Special , 1961 , p. 329 .
85.
Enke
M.
, Metall Reinigung u . Y orbehandlung , 1962 , 11 , 55 .
86.
Brit. Patent
No. 745 ,505 .
87.
Theuerer
H. C.
, Trans. Amer. Inst. Min. Met. Eng ., 1956 , 206 , 688.
88.
Brit. Patent
No. 734 ,144 .
89.
Morrison
G. H.
Dorfman
E. G.
Cosgrove
J. F.
, J. Amer. Chem, Soc ., 1959 , 78 ,4236 .
90.
Shashkov
Yu. M.
, "The Metallurgy of Semiconductors" . 1961 : London (Pitman) .
91.
German Patent No
. 855,702 .
92.
Grdenic
D.
Jagodie
V.
, J. Inorg. Nuclear Chem ., 1964 , 26 , 167.
93.
Sebba
F.
, J. Chem. Soc ., 1951 , 1975 .
94.
Green
M.
Kafales
J. A.
, ibid. , 1975.
95.
Reynolds
F. M.
, "Chemistry Research" (Dept. Sci. Indust. Research), p . 34 . 1951 : London (H.M. Stationery Office).
96.
German Patent No
. 1,
022,803 .
97.
Ono
K.
Matsushima,
T.
and Y. Linda, Bull. Research. Inst. Mineral Dressing and Metallurgy, Tohoku Univ ., 1955 , 1/ , 155.
98.
Yokokawa
T.
Koizurni
M.
Shimoji
M.
Miwa
K.
, J. Amer. Chem. Soc ., 1957 , 79 , 3365 .
99.
Becker
W. M.
and K. Lark-Horovitz, Proc. (U.S.) Nat. Electronics Con! ., 1952 , 8 , 506.
100.
Krause
A.
, Roczniki Chem , 1962 , 36 , 977 .
101.
German Patents Nos
. 964,351;
970,474 .
102.
Pfann
W. G.
, "Zone Melting" . 1958 : New York (John Wiley); London (Chapman and Hall).
103.
Pfann
W. G.
, Met. Rev ., 1957 , 2 , (5 ), 29 .
104.
Pfann
W. G.
, Trans. Amer. Inst. Min. Met. Eng ., 1953 , 197 , 1441 .
105.
Bradshaw
S. E.
, J. Electrochent. Soc ., 1954 , 101 , 293.
106.
Pfann
W. G.
Olsen
K. M.
, Phys . Rev ., 1953 , 89, 322 ; Bell Lab. Recant , 1955 , 33 , 201.
107.
Tanenbaum
M.
Goss
A. J.
Pfann
W. G.
, Trans. Amer. Inst. Min. Met. Eng ., 1954 , 200 , 762.
108.
Trumbore
F. A.
, Bell System Tech. J ., 1960 , 39 , 205.
109.
Taft
E. A.
Horn
F. H.
, J. Electrochem. Soc ., 1958 , 105 , 81.
110.
Lamb
D. M.
Porter
J. L.
, Ref. E, p. 469 .
111.
Keck
P. H.
Golay
M. J. E.
, Phys. Rev ., 1953 , 89 , 1297 .
112.
Keck
P. H.
Van Horn
W.
Soled
J.
Macdonald
A.
, Rev. Sci. Instruments , 1954 , 25 , 331.
113.
Buehler
E.
, ibid ., 1957 , 28 , 453 .
114.
Heywang
W.
, Z. Naturforsch ., 1956 , [A], 11 , 238.
115.
Wroughton
D. M.
Okress
E. C.
Brace
P. H.
Comenetz
G.
Kelly
J. C. R.
, J. Electrochent. Soc ., 1952 , 99 , 205.
116.
Benson
K. E.
, Ref. A, p. 17 .
117.
Silverman
S. J.
, J. Electrochem. Soc ., 1961 , 108 , 585.
118.
Davis
M.
Calverley
A.
Lever
R. F.
, J. Appl. Physics , 1956 , 27 , 195.
119.
Calverley
A.
Davis
M.
Lever
R. F.
, J. Sci. Instruments , 1957 , 34 , 142.
120.
Poplowsky
R. P.
Thomas
J. E.
, Rev. Sei. Instruments , 1960 , 31 , 1303 .
121.
Theuerer
H. C.
, Trans. Amer. Inst. Min. Met. Eng ., 1956 , 206 , 1316 .
122.
Kaiser
W.
Keck
P. H.
Lange
C. F.
, Phys. Rev ., 1956 , 101 , 1264 .
123.
Logan
R. A.
, ibid ., 1953 , 91 , 757.•
124.
Wang
P.
, J. Phys. Chem ., 1956 , 60 , 45 .
125.
Logan
R. A.
Schwartz
M.
, J. Appl. Physics , 1955 , 26, 1287. 122„ C. D. Thurmond and R. A. Logan , J. Phys. Chem ., 1956 , 60 , 591.
126.
Kikuchi
M.
Iijima
S.
, J. Phys. Soc. (Japan) , 1957 , 12 , 824.
127.
Blodgett
K. B.
, J. Appl. Physics , 1955 , 26 , 1520 .
128.
Finn
G.
, Phys. Rev ., 1953 , 91 , 754 .
129.
Ref.
A
, p. 327 (discussion) .
130.
Burton
J. A.
Prim
R. C.
Sehlichter
W. P.
, J. Chem. Physics , 1953 , 21 , 1987 .
131.
Bridgers
H. E.
, J. Appl. Physics , 1956 , 27 , 746.
132.
Korollov
V. I.
Romanenko
V. N.
, Soviet Physics—Solid State , 1963 -64, 5 , 2130 .
133.
Hall
R. N.
, J. Physics Chem. Solids , 8, 63 ; 1958 , 6 , 97.
134.
Thurmond
C. D.
, Ref. A, p. 121 .
135.
Trumbore
F. A.
Porbansky
E. M.
Tartaglia,
A. A.
J. Physics Chem. Solids , 1959 , 11 , 239 .
136.
Lehovec
K.
, ibid ., 1962 , 23 , 695 .
137.
Trumbore
F. A.
Freeland
P. E.
Logan
H. A.
, J. Electrochem. Soc ., 1961 , 108 , 458.
138.
Hall
R. N.
, Phys. Rev ., 1952 , 88, 139 ; J. Phys. Chem ., 1953 , 57 , 836.
139.
Hulme
K. F.
Mullin
J. B.
, Phil. Meg ., 1959 , 4 , 1286 .
140.
Dikhoff
J.A. M.
, Solid-State Electronics , 1900 , 1, 202 ; Philips Tech. Rev ., .2963 –64 , 25, 195.
141.
Mirvidsky
M. G.
Berkova
A. V.
, Soviet Physics—Solid State , 1963 –64, 5 , 517.
142.
Bridgers
E.
Kolb
E. D.
, J. Chem. Physics , 1956 , 25 , 648.
143.
Rutter
J. W.
Chalmers
B.
, Caned. J. Physics , 1953 , 31 , 15.
144.
Chalmers
B.
, Trans. Amer. Inst. Min. Met. Eng ., 1954 , 200 , 519 .
145.
Trumbore
F. A.
, Ref. B, p. 15 .
146.
Minden
H. T.
, Ref. B, p. 35 .
147.
Patel
J. R.
Tramposch
R. F.
Chaudhuri
A. H.
, Ref. B, p. 45 .
148.
Trumbore
F. A.
Porbansky
E. N.
, J. Appl. Physics , 1960 , 81 , 2068 .
149.
Reiss
H.
Fuller
C. S.
MorM
F. J.
, Bell System Tech. J ., 1956 , 85 , 535.
150.
Reiss
H.
Fuller
C. S.
, J. Physics Chem. Solids , 1958 , 4 , 58.
151.
Kh
N.
. Abrikosov, V. M. Glazov, and Liu Chen-Yuan, Russian .1. Inorg. Chem., 1962 , 7 , 429.
152.
McCaldin
J. O.
, J. Appl. Physics , 1960 , 31 , 89.
153.
Glazov
V. M.
Liu
Chen-Yuan
, Russian J. Inorg. Chem ., 1962 ,7 , 296.
154.
Glazov
V. M.
, Chien Ts'e-jen, and Liu Chen.Yuan, ibid ., p. 293 .
155.
McCaldin
J. O.
Wittry
D. B.
, J. Appl. Physics , 1961 , 82 , 65.
156.
Glazov
V. M.
Petrov
D. A.
Chizhevskaya
S. N.
, Izvest. Akad. Arauk S.S.S.R. (Wel. Tekhn.) Met. i Topl ., 1959 , (4) , 153 .
157.
Zhurkin
B. G.
, V.8. Zemskov, D. A. Petrov, and A. D. Suchkova, ibid ., p. 156 .
158.
Lehovec
K.
Slabodsky
A.
, J. Electrochem. Soc ., 1964 , 111 , 65.
159.
Zemskov
V. S.
Suchkova
A. D.
Zhurkin
B. G.
, Russian J. Phys. Chem ., 1962 ,36,
1033 .
160.
Zemskov
V. S.
Belaya
A. D.
Puns
T. E.
, Soviet Physics—Solid State , 1963 –64, 5 , 802.
161.
Bennett
D. C.
Sawyer
B.
, Bell System Tech. J ., 1956 , 35 , 637.
162.
Cressoll
I. G.
Powell
J. A.
, Progress in Semiconductors , 1957 , 2 , 139.
163.
Eisenhower
W. D.
, Western Elect. Eng ., 1961 , 5 , 18.
164.
Braun
J. H.
Pellin
R. A.
, J. Electrochem. Soc ., 1961 , 108 , 969.
165.
Goorissen
J.
and A. Van Run, Proc. Inst. Elect. Eng ., 1959 , [B], Suppl. No. 17, 858.
166.
Goss
A. J.
, Ref. E, p. 534 .
167.
Savery
J. W.
, Ref. D, p. 283 .
168.
Tanenbaum
M.
, "Semiconductors" (edited by
Hannay
N. B.
), p . 87 . 1959 : New York (Reinhold Publishing Corpn.).
169.
Parmee
J. L.
, Engineer , 1960 , 209 , 979.
170.
Schadler
H. W.
, "Art and Science of Growing Crystals" (edited by
Gilman
J. J.
), p . 347 . 1963 : New York and London (John Wiley).
171.
Teal
G. K.
Little
J. B.
, Phys. Rev ., 1950 , 78 , 647.
172.
Thurmond
C. D.
Guldner
W. G.
Beach
A. L.
, J. Electrochem. Soc ., 1956 , 103 , 603.
173.
Lehovee
K.
Soled
J.
Koch
R.
McDonald
A.
Stearne
C.
, Rev. Sci. Instruments , 1953 , 24 , 652 .
174.
Tanenbaum
M .
Valdes
L. B.
Buehler
E.
Hannay
N. B.
, J. Appl. Physics , 1955 , 26 , 686 .
175.
Priest
H. P.
, "Handbook of Semiconductor Electronics" (edited by
Hunter
L. P.
), Chapter 6 . 1956 : New York and London (McGraw-Hill).
176.
Valcie
A. V.
, Solid-State Electronics , 1962 , 5 , 131.
177.
Leverton
W. F.
, J. Appl. Physics , 1958 , 29, 1241; U.S. Patent No. 3, 025,191. .
178.
Goorissen
J.
Karstensen
F.
, Z. Metallkunde , 1959 , 50 , 46.
179.
Lambert
L. M.
, Solid-Stale Electronics , 1961 , 3 , 316.
180.
Bradley
W. G.
, "Transistor Technology" (edited by
Shiva
J.
), Vol. I , Chapter.
7 . 1957 : New York (Van Nostrand).
181.
Marshall
K. H. J. C.
Wickham
R.
, J. Sri. Instruments , 1958 , 35 , 121.
182.
Wilkes
J. G.
, Proc. Inst. Elect. Eng ., 1959 , [B], 106 , 866.
183.
Dash
W. C.
, J. Appl. Physics , 1958 , 29, 736; 1959 , 30, 459; 1960 ,81, 736.
184.
Okkerse
B.
, Philips Tech. Rev ., 1959 –60, 21 , 340.
185.
Brissot
J. J.
Raynaud
H.
, Bleetrochem. Technot ., 1963 ,1 , 304.
186.
Billig
E.
, Proc. Roy. Soc ., 1955 , (A],
229 , 346.
187.
Billig
E.
Holmes
P. J.
, Ada Cryd ., 1955 , 8 , 353.
188.
Billig
E.
Holmes
P. J.
, Ada Met ., 1957 , 5 , 53.
189.
Bennett
A. I.
Longini
R. L.
, Phys. Rev ., 1959 , 116 , 53.
190.
Longini
R. L.
Bennett
A. L
Smith
W. J.
, J. Appl. Physics , 1960 , 31 , 1204 .
191.
Hamilton
D. R.
Seidensticker
R. G.
, ibid ., 31, 1165 ; 1963 , 34 , 1450.
192.
Vasilevskaya
V. M.
Miselyuk
E. G.
Fortunatova
M. N.
, Fizika Tverdoga Tela , 1963 , 5 , 52.
193.
Smith
R. C.
, J. Electrochem. Soc ., 1961 , 108 , 238.
194.
Faust
J. W.
John
H. F.
, ibid ., 108, 855 , 860 , 864 .
195.
Booker
G. R.
, ibid ., 1961 , 108 , 564.
196.
Wagner
R. S.
, Ada Met ., 1960 , 8, 57; Ref. B, p. 177 .
197.
Bolling
G. F.
Tiller
W. A.
, Ref. B, p. 97 .
198.
Holmes
P. J.
, Ref. B, p. 161 .
199.
O'Hara
S.
Ref.
B
, p. 149 .
200.
Lever
R. F.
Powers
J. K.
Richards
J. L.
Sirgo
H. V.
, Rev. Sci. Instru-ments , 1960 , 31 , 1334 .
201.
Brit. Patents Nos. 899,058; 894,241; 911,349; 911,360;
913,676 .
202.
O'M.
J.
Diaz
Bockris, J.
Green
M.
, Electroc him . Ada , 1961 , 4 , 362 .
203.
Wernick
J. H.
, J. Chem. Physics , 1956 , 25 , 47.
204.
Keck
P. H.
Broder
J.
, Phys. Rev ., 1953 , 90 , 521.
205.
Trumbore
F. A.
Porbansky
E. M.
Tartaglia
A. A.
, J. Physics Chem. Solids , 1959 , 11, 239 ; Bell System Tech. J ., 1960 , 89 , 205.
206.
Pankove
J. I.
, RCA Rev ., 1954 , 15 , (1 ), 75 .
207.
Carman
J. N.
Stello
P. E.
Bittmann
C. A.
, J. Appl. Physics , 1954 , 25 , 543.
208.
Glang
R.
Wajda
E. S.
, "The Art and Science of Growing Crystals" (edited by
Gilman
J. J.
), p .80 . 1963 : New York and London (John Wiley).
209.
Glang
R.
Wajda
E. S.
, Ref. C, p. 27 .
210.
Dunoyer
J. M.
, J. Phys. Radium , 1951 , 12 , 602.
211.
Eckart
F.
Jungk
G.
, Ann.. Physik , 1961 , 7 , 210.
212.
Kurov
G. A.
Vasil'ev
V. D.
Kosaganova„
M. G.
Fizika Tverdogo Teta , 1061 ,8 , 3541 .
213.
Davey
J. E.
Tiernan
R. J.
Pankey
T.
Montgomery
M. D.
, Solid-State Electronics , 1963 , 6 , 205.
214.
Shalimova
K. V.
, V. 1..Vardanyan, and Yu. P. Ternovykb, Nauch. Doklady Vysahei Shkoly, Radiotekhn. i Elektron ., 1958 , (4) , 232 .
215.
Kataoka
Y.
, J. Phys. Soc. Japan , 1962 , 17 , 967 .
216.
Kurov
G. A.
Semiletov
S. A.
Pensker
Z. G.
, Soviet Physics—Doklady , 1956 , 1 , 604.
217.
Kurov
G. A.
Semiletov
S. A.
Pensker
Z. G.
, Nrisfallografiya , 1957 , 2 , 59.
218.
Davey
J. E.
, J. Appl. Physics , 1962 , 33 , 1015 .
219.
Patent
U.S.
No. 2,
898,248 .
220.
Reizman
F.
Bazseches
H.
, Ref. C, p. 169 .
221.
Unvala
B. A.
, Vide , 1963 , 18 , 109.
222.
Haase
O.
Ref.
C
, p. 159 .
223.(a).
Mayer
S. E.
Shea
D. E.
, J. Electrochem. Soc ., 1964 , 111 , 550. •
224.
Theuerer
H. C.
, ibid ., 1961 , 108, 649. 220(a). H. C. Theuerer , ibid ., 1962 , 109, 742. 220(b). R. Nutta.11 , ibid ., 1964 , 111 , 317.
225.
Tung
S. K.
, Ref. C, p. 87 .
226.
Basseches
H.
Tung
S. K.
Manz
R. C.
Thomas
C. O.
, Ref. C, p. 69 .
227.
Li
C. H.
, J. Electrochem. Soc ., 1962 , 109 , 952,
228.
Miller
K. J.
Manz
R. C.
Grieco
M. J.
, ibid., p. 643 .
229.
Bylander
E. G.
, ibid ., p . 1171 .
230.
Charig
J. M.
Joyce
B. A.
, ibid ., p. 957 .
231.
Joyce
B. A.
Bicknell
R. W.
Charig
J. M.
Stirland
D. J.
, Solid-Slate flommun ., 1963 , 1 , 107.
232.
Miller
K. J.
Grieco
M. J.
, J. Electrochem. Soc ., 1963 , 110 , 1252 .
233.
Schaefer
H.
Moreher
B.
, Z. anorg. Chem ., 1957 , 290 , 279.
234.
Wajda
E. S.
Glang
R.
, Ref. B, p. 229 .
235.
Clang
R.
Kippenham
B. W.
, IBM J. Research Develop ., 1960 , 4 , 299.
236.
Beatty
H. J.
Clang
R.
Kren
J. G.
Patrick
W. J.
Wajda
E. S.
White
W. N.
, U.S. Dept. of Commerce, Office Tech. Services , (AD
268 ,282 ), 1961 .
237.
Kokorish
N. P.
, Growth of Crystals , 1962 , 3 , 255.
238.
Nomura
M.
, Japan J. Appl. Physics , 1963 , 2 , 591 .
239.
Dunlap
W. C.
Marinace
J. C.
Ruth
R. P.
, Bull. Amer. Phys. Soc ., 1956 , 1 , 294.
240.
Ruth
R. P.
Marinace
J. C.
Dunlap
W. C.
, J. Appl. Physics , 1960 ,31,995 .
241.
Arizumi
T.
Akasaki
I.
Nishinaga
T.
, Japan. J. Appl. Physics , 1963 , 2 , 757 .
242.
Marinace
J. C.
Baker
W. E.
Compton
D. M. J.
, Ref. B, p. 271 .
243.
Lever
R. F.
, J. Electrochem. Soc ., 1963 , 110 , 775.
244.
Lever
R. F.
Jona
F.
, J. App!. Physics , 1963 , 84 , 3139 .
245.
Johnston
J. E.
, J. Brit. Inst. Radio Eng ., 1951 , 11 , 279.
246.
Smales
A. A.
Pate
B. D.
, ,Analyt. Chem ., 1952 , 24 , 717.
247.
Jaskolska
H.
and L. Wodkiewicz, Chemia analityczna , Warsaw , 1961 , 6 , 161 .
248.
Szekely
G.
, Analyt. Chem ., 1954 , 26 , 1500 .
249.
Gottfried
J.
Jakovlev
J. V.
, Chem. Prumysl ., 1959 , 9 , 179.
250.
Thompson
B. A.
Strauss
B. M.
Lehoeux
M. B.
, Analyt. Chem ., 1958 , 80 , 1023 .
251.
James
J. A.
Richards
D. H.
, J. Electronics Control , 1957 , 3 , 500.
252.
Morrison
G. H.
Cosgrove
J. F.
, Analyt. Chem ., 27, 810 ; 1956 , 28 , 320.
253.
Hannay
N. B.
, Rev. Sci. Instruments , 1954 , 25, 644 ; Science , 1961 , 134 , 1220.
254.
Hannay
N. B.
Ahearn
A. J.
, Analyt. Chem ., 1954 , 26 , 1056 .
255.
Owen
E. B.
, Lincoln Lab. Quarterly Progress Rep ., March , 1961 , p. 20 .
256.
Resnik
D. A.
Willardson
R. K.
, Ref. C, p. 209 .
257.
Craig
R. D.
Erroch
G. A.
Waldron
J. D.
, "Advances in Mass Spectro-metry" . 1959 : London (Pergamon Press).
258.
Zilbershtein
Rh. I.
Kaliteevsky
N. I.
Razumovsky
A. N.
Fedorov
Yu. F.
, Zavod. Lab ., 1962 , 28 , 43 .
259.
Martynov
Yu. M.
Komblit
I. I.
Smirnova
N. P.
Dzhagatspanyan
R. V.
, ibid ., 1961 , 27 , 839 .
260.
Borovsky
I. B.
Shteinberg
A. N.
Bugulova
V. V.
, Trudy Inst. Met. im. A. A. Baikova , 1958 , (3) , 283 .
261.
Karabash
A. G.
Peizulaev
Sh. I.
Morozova
G. G.
Smirenkina
I.I.
, Trudy Komissii Anal. Khim., Aka . Nauk S.S.S.R., Inst. Geokhim. i Anal. Khim ., 1960 , 12 , 25 .
262.
Morrison
G. H.
Rupp
R. L.
, Analyt. Chem ., 1957 , 29 , 892.
263.
Veleker
T. J.
Mehalchick
E. J.
, ibid ., 1961 , 33 , 767.
264.
Morrison
G. H.
, Ref. E, p. 267 .
265.
Fuller
C. S.
Ditzenberger
J. A.
Hannay
N. B.
Buehler
E.
, Phys. Rev ., 1954 , 96 , 833.
266.
Kaiser
W.
, ibid ., 1957 , 105 , 1751 .
267.
Kaiser
W.
Frisch,
M.
and H . Reiss, ibid ., 1958 , 112 , 1546 .
268.
Fuller
C. S.
Logan
R. A.
, J. Appl. Physics , 1957 , 28 , 1427 .
269.
Logan
R. A.
Peters
A. J.
, ibid ., p. 819 .
270.
Pearson
G. L.
Read
W. T.
Feldmann
W. L.
, Ada Met ., 1957 , 5 , 181.
271.
Green
G. W.
Hogarth
C. A.
Johnson
F. A.
, J. Electronics Control , 1967 , 8 , 171.
272.
Roberts
D. H.
Stephens
P. H.
Hunt
P. H.
, Nature , 1957 , 180 , 665.
273.
Matukum
Y.
, J. Phys. Soc . Japan,
1959 , 14 , 918.
274.
Fan
H. Y.
Becker
M.
, "Semi-Conducting Materials" (edited by
Henisch
H. K.
) (Proceedings of Reading Conference 1950 ), p. 132 . 1951 : London (Butterworths).
275.
Collins
R. J.
and H. Y . Fan. Phys. Rev ., 1954 , 93 , 674 .
276.
Lax
M.
Burstein
E.
, ibid ., 1955 , 97 , 39 .
277.
Hrostowski
H. J.
Kaiser
R. H.
, ibid ., 1957 , 107 , 966.
278.
Hrostowski
H. J.
Alder
B. J.
, J. Chem. Physics , 1960 , 33 , 980.
279.
Kaiser
W.
Keck
P. H.
, J. Appl. Physics , 1957 , 28 , 882.
280.
Beach
A. L.
Goldner
W. G.
, 'Gases in Metals" (Special Tech. Publ.
No. 222 ), p. 15 . 1958 : Philadelphia , Pa. (Amer. Soc. Test. Mat .).
281.
Kaiser
W.
Thurmond
C. D.
, J. Appl. Physics , 1961 , 32 , 115.
282.
Elliott
G.
, Nature , 1957 , 180 , 1350 .
283.
Knight
G.
, "Handbook of Semiconductor Electronics" (edited by
Hunter
L. P.
), Section 20 . 1956 : New York and London (McGraw.Flill).
284.
Valdes
L. B.
Smith
K. D.
, "Transistor Technology" , Vol. 1 , Chapter
12 . 1958 : New York (D. Van Nostrand).
285.
Keller
W.
, Z. angew. Physik , 1959 , 11 , 346 .
286.
Allen
C. C.
Bylander
E. G.
, Ref. C, p. 113 .
287.
Schumann
P. A.
Hallenback
J. F.
, J. Electrochem. Soc ., 1963 , 110 , 538.
288.
Brownson
J.
, ibid ., 1964 , 111 , 919 .
289.
Biard
J. R.
Watelski
S. B.
, ibid ., 1962 , 109 , 705.
290.
Putley
E. H.
, "The Hall Effect and Related Phenomena" . 1960 : London (Butterworths).
291.
Bate
R. T.
Weingarten
L. R.
Shombert
D. J.
, J. Electrochem. Soc ., 1980 , 107 , 908.
292.
Berthel
K. H.
Doege
H. G.
Ehrlich
G.
Koethe
A.
Schmidt
A.
, Mikro-chim. Ada , 1963 –64, 702 .
293.
James
H. M.
and K. Lark-Horovitz, Z. physikal. Chem ., 1951 , 198 , 107.
294.
Cleland
J. W.
Crawford
J. H.
Pigg
J. C.
, Phys. Rev ., 98, 1742 ; 99 , 1170 .
295.
Curtis
O. L.
Cleland
J. W.
Crawford
J. H.
Pigg
J. C.
, J. Appl. Physics , 1957 , 28 , 1161 .
296.
Hobstetter
J. N.
Breidt
P.
, ibid., p . 1214 .
297.
Pearson
G. L.
Read
W. T.
Morin
F. J.
, Phys. Rev ., 1954 , 93 , 666.
298.
Read
W. T.
, Phil. Meg ., 1955 , 46 , 111.
299.
Wertheim
G. K.
Pearson
G. L.
, Phys. Rev ., 1957 , 107 , 694.
300.
Vogel
F. L.
Pfann
W. G.
Corey
H. E.
Thomas
E. E.
, ibid ., 1953 , 90 , 489.
301.
Vogel
F. L.
, Ada Met ., 1955 , 3 , 245 .
302.
Vogel
F. L.
, Trans. Amer. Inst. Min. Met. Eng ., 1956 , 206 , 946.
303.
Pfann
W. G.
Vogel
F. L.
, Ada Met ., 1957 , 5 , 377.
304.
Bardsley
W.
Bell
R. L.
Straughan
B. W.
, J. Electronics Control , 1958 ,5 , 19.
305.
Dragoun
Z.
, Ceechoslov. J. Physics , 1958 , 8 , 600 .
306.
Vasilevskaya
V. N.
Miselyuk
E. G.
, Soviet Physics—Solid State , 1961 , 8 , 313.
307.
Billig
E.
, Brit. J. Appl. Physics , 1956 , 7 , 375 .
308.
Yu
E.
. Kokorish and E. Y. Myakeninkova, Growth of Crystals , 1962 , 8 , 264.
309.
Dash
W. C.
, J. Appl. Physics , 1956 , 27 , 1193 .
310.
Greger
G.
, Z. physikal. Chem ., 1959 , 22 , 313 .
311.
Holmes
P. J.
, Ada Met ., 1959 , 7, 283 ; Proc. Inst. Elect. Eng ., 1959 , (B], 106 , 861.
312.
Furuoya
T.
, Japan J. Appl. Physics , 1962 , 1 , 135.
313.(a).
Sehwuttke
G. H.
, J. Electrochem. Soc ., 1961 , 108, 166, Figs. 11 and 12 .
314.
Kurtz
A, D.
Kuhn
S. A.
Averbach
B. L.
, Phys. Rev ., 1956 , 101 , 1285 .
315.
Hirsch
P. B.
, "Progress in Metal Physics" , Vol. VI , p. 230 . 1956 : London (Pergamon Press).
316.
Lang
A. R.
, J. Appl. Physics , 29, 597 ; 1959 , 30 , 1748.
317.
Schwuttke
G. H.
, ibid ., 1962 , 83 , 1538 .
318.
Schwuttke
G. H.
IL
J
. Queisser, ibid.. p. 1540 .
319.(a).
Jenkinson
A. E.
Lang
A. R.
, "Direct Observation of Imperfections in Crystals" , p. 478, Fig. 5.
1962 : New York and London (Interscience publishers).
320.
von Lane
M.
, Acta Cryst ., 2, 106 ; 1952 , 5 , 619.
321.
Borrman
G.
., "Beitmge zur Physik und Chemie des 20. Jahrhunderts" (edited by
Frisch
O. R.
Paneth
F. A.
Laves
F.
Rosbaud
P.
), p. 262 . 1959 : Braunschweig (Frieclr. Vieweg u. Sohn).
322.
Schwuttke
G. H.
, J. Appl. Physics , 1962 , 33 , 2760 .
323.
Elistratov
A. M.
Efimov
O. F.
, Soviet Physics—Solid State , 1962 , 4 , 1757 .
324.
Datsenko
L. I.
, ibid ., p. 381 .
325.
Straumanis
M. E.
Aka
E. Z.
, J. Appi. Physim , 1952 , 23 , 330.
326.
Hall
R. O. A.
, Ada Cryst ., 1961 , 14 , 1004 .
327.
Wentorf
R. H.
Kaapar
J. S.
, Science , 1963 , 139 , 338.
328.
Bundy
F. P.
Kaspar
J. S.
, ibid., g . 340 .
329.
Smakula
A.
Sils
V.
, Phys. Rev ., 1955 , 99 , 1744 .
330.
McSkimin
H. J.
, J. Appl. Physics , 1953 , 24 , 988.
331.
McSkimin
H. J.
Andreatch
P.
, ibid ., 1963 , 34 , 651.
332.
Fine
M. E.
, ibid ., 1955 , 26 , 862.
333.
Keck
P. H.
and W. Van Horn, Phys. Rev ., 1953 , 91 , 512.
334.
Sangster
R. C.
Carman
J. N.
, J. Chem. Physics , 1955 , 28 , 1142 .
335.
Lucas
L. D.
Urbain
G.
, Compt. rend ., 1962 , 255 , 2414 .
336.
Olette
M.
, ibid ., 1957 , 244 , 1033 .
337.
Greiner
E. S.
and P. Breidt, . Trans Amer. Inst. Min. Met. Eng ., 1955 , 203 , 187 .
338.
Keesom
P. H.
Seidel
G.
, Phys. Rev ., 1959 , 113 , 33.
339.
Bryant
C. A.
Keesom
P. H.
, ibid ., 1961 , 124 , 698.
340.
Conwell
E. M.
, Proc. Inst. Radio Eng ., 1952 , 40 , 1327 .
341.
Greiner
E. S.
, Trans. Amer. Inst. Min. Met. Eng ., 1952 , 194 , 1044 .
342.
Kantor
P. B.
Kisel
A. M.
Fomcchev
E. N.
, Ukrain. Fiz. Zhur ., 1960 , 5 , 358.
343.
Davis
S. G.
Anthrop
D. F.
Searcy
A. W.
, J. Chem. Physics , 1961 , 34 , 659.
344.
Honig
R. E.
, ibid ., 1954 , 22 , 1610 .
345.
Morris
R. G.
Hust
J. G.
, Phys. Rev ., 1961 , 124 , 1426 .
346.
Salzburg
C. D.
Villa
J. J.
, J. Opt. Soc. Amer ., 1957 , 47 , 244.
347.
Salzburg
C. D.
Villa
J. J.
, ibid ., 1958 , 48 , 579.
348.
Allen
F. G.
, J. Appl. Physics , 1957 , 28 , 1510 .