Homogeneous precipitation synthesis and thermoelectric properties of Ca 2 Co 2 O 5 ceramics

Abstract

Homogeneous precipitation method was applied to synthesise Ca₂Co₂O₅ powders using calcium nitrate, cobalt nitrate and urea as raw materials. Uniform plate-like Ca₂Co₂O₅ powders with an average grain size of 1 μm can be obtained by calcining the precursor for 8 h at 1073 K in the air. The Ca₂Co₂O₅ ceramics were gained after sintering for 4 h at 1083 K using uniaxial pressure moulding and then sintering technique. The thermoelectric properties of ceramic samples were measured from 303 to 973 K, and the result shows that the electrical conductivity, Seebeck coefficient, thermal conductivity and figure of merit of the sample are 2236·85 S m⁻¹, 175·95 μV K⁻¹, 1·01 W m⁻¹ K⁻¹ and 0·69 at 973 K respectively.