Effect of TiAlN PVD coatings on corrosion performance of WC–6%Co

Abstract

The present study has been carried out to evaluate the corrosion performance of three different (Ti1–xAlx)N/TiN multilayers coatings commercially deposited on WC–Co inserts. Two of these coatings were nanostructured, and all of them presented different Ti/Al atomic ratios varying from 2 : 3 up to 7 : 3 and were deposited by employing a commercial physical vapour deposition cathodic arc process. X-ray diffraction analysis indicated that the grain size for both the TiAlN and TiN layers in the coatings architecture, varied between approximately 9 to 14 nm. The corrosion performance was evaluated in a 3 wt-%NaCl solution using both open circuit potential and potentiodynamic polarisation measurements. Scanning electron microscopy and energy dispersive spectroscopy surface characterisation before and after corrosion testing allowed the determination that all the coatings under study show a corrosion current density of approximately one order of magnitude smaller than the uncoated substrate, indicating thus their beneficial effect from the corrosion protection viewpoint.