Microscopic morphological features of the cubic chromium and nodular titanium powders prepared by electroreduction of the respective oxides in molten salts (the FFC Cambridge process) are compared with the preferential crystal growth mechanism. The analysis leads to an understanding of determining forces for the formation of cubic particles in the chromium powders owing to preferential growth, but nodular particles in the titanium powder owing to interruption of the preferential growth by particularly oxygen atoms.
ChenG. Z., FrayD. J. and FarthingT. W.: Nature, 2000, 407, 361–364.
8.
ChenG. Z. and FrayD. J.: ‘Light metals’, 1147-1151; 2001, Warrendale, PA, TMS.
9.
ChenG. Z. and FrayD. J.: Proc. 6th Int. Symp. on ‘Molten salt chemistry and technology’, (ed. ChenN. Y. and QiaoZ. Y.), 79–85; 2001, Shanghai, China, Shanghai University Press.
10.
WoodA. J. M., CopcuttR. C., ChenG. Z. and FrayD. J.: Adv. Eng. Mater., 2003, 5, 650–653.
11.
ChenG. Z. and FrayD. J.: ‘Light metals’, 881–886; 2004, Warrendale, PA, TMS.
12.
ChenG. Z., GordoE. and FrayD. J.: Metall. Mater. Trans. B, 2004, B35, 223–233.
13.
FrayD. J. and ChenG. Z.: J. Mater. Sci Technol, 2004, 20, 295–300.
14.
FrayD. J., FarthingT. W. and ChenZ.: PCT patent W09964638, 1998.
15.
DringK., DashwoodR. and InmanD.: J. Electrochem. Soc., 2005, 152, E104—E113.
16.
NohiraT., YasudaK. and ItoY.: Nat. Mater., 2003, 2, 397–401.
17.
JinX. B., GaoP., WangD. H., HuX. H. and ChenG. Z.: Angew. Chem. Int. Ed., 2004, 43, 733–736.
18.
ChenG. Z. and FrayD. J.: J. Electrochem. Soc., 2002, 149, E455—E467.
19.
ChenG. Z. and FrayD. J.: J. Appl. Electrochem., 2001, 31, 155–164.
20.
MohamediM., BorresenB., HaarbergG. M. and TunoldR.: J. Electrochem. Soc., 1999, 146, 1472–1477.
21.
DengY., WangD. H., XiaoW., JinX. B., HuX. H. and ChenG. Z.: J. Phys. Chem. B, 2005, B109, 14043–14051.
22.
OkabeT. H., NakamuraM., OishiT. and OnoK.: Metall Mater. Trans. B, 1993, B24, 449–455.
23.
OnoK. and SuzukiR. O.: JOM J. Min. Met. Mater. Soc., 2002, 54, 59–61.
24.
SuzukiR. B.: J. Phys. Chem. Solids, 2005, 66, 461–465.
25.
QiuG. H., MaM., WangD. H., JinX. B., HuX. H. and ChenG. Z.: J. Electrochem. Soc., 2005, 152, E328—E336.
26.
MaM., WangD. H., WangW. G., HuX. H., JinX. B. and ChenG. Z.: J. Alloy. Comp., published online —doi:10.1016/j.jallcom. 2005.10.048.