Coarsening process of coherent β ′ precipitates in Fe–10 wt-Ni–15 wt-Al and Fe–10 wt-Ni–15 wt-Al–1 wt-Cu alloys

Abstract

The coarsening process of the NiAl ordered β′ precipitates was studied in the isothermally aged Fe–10 wt-Ni–15 wt-Al and Fe–10 wt-Ni–15 wt-Al–1 wt-Cu alloys. The aging treatments at 750, 850 and 950°C caused the precipitation of the β′phase in a ferritic matrix. In general, the coarsening process of Cu containing alloy was slower with an activation energy of 248 kJ mol⁻¹ compared to 194 kJ mol⁻¹ for the other alloy. However, the coarsening kinetics for the former alloy was faster at 950°C. The precipitation hardening response was also better in the Cu containing alloy, with a slower overaging stage. The coarsening kinetics followed the behaviour predicted by the modified Lifshitz–Slyozov–Wagner theories for coarsening controlled by volume diffusion.