Method to improve corrosion resistance of AA 5083 by cerium based conversion coating and anodic polarisation in molybdate solution

Abstract

The corrosion resistance of aluminium alloys can be improved by the formation of chemical conversion coatings. Usually, chromate pretreatment processes are used. However, because of their high toxicity, alternative methods have been studied in the last years. In the present paper, a process to improve the corrosion resistance of AA 5083 was investigated. The main process consisted of serial immersion in two solutions containing two different cerium salts, followed by a further step involving anodisation in Na₂MoO₄. The corrosion resistance was investigated by potentiodynamic anodic polarisation tests and electrochemical impedance spectroscopy. The morphology and composition of the oxide layers were characterised by scanning electronic microscopy equipped with an energy dispersive X-ray detector. Serial treatment in the two solutions with different cerium salts and H₂O₂ produced a more uniform and thicker layer with a larger amount of deposits above the alloy cathodic areas than the single two treatments. In this way, the alloy corrosion resistance in chloride environments was improved and decreased the anodic reaction rate. When anodisation in molybdate salts was added, even better results were found. The corrosion resistance was higher due to a thicker and less conductive passive layer.