Modelling the evolution of particle size distribution during nucleation,growth and coarsening

Abstract

A model, based on the numerical framework of Kampmann and Wagner, has been developed to predict the evolution of particle size distribution (PSD) during the decomposition of supersaturated solid solutions by nucleation, growth, and coarsening. During the early stages of transformation, where nucleation and growth are dominant, the PSD shape is predicted to be constantly evolving. Only during the latter stages of transformation, when coarsening becomes dominant, does the PSD tend towards a steady state shape, which closely matches that expected from classical coarsening theory. It is also predicted that as the PSD evolves, a transient double peak forms and then decays. The physical basis of this double peak has been investigated and the effect of supersaturation on its formation has been predicted.