Micro- and nano-scale deformation processes during scratch damage in high density polyethylene

Abstract

Atomic force microscopy and scanning electron microscopy techniques have been used to examine the surface deformation experienced by high density polyethylene during the scratch test. The scratch deformation process involves stretching of fibrils and microfibrils resulting in the formation of surface openings. At the molecular level the chains of molecules unfold and align in the direction of the moving indenter. In the scratch test, the scratch velocity may suggest that low strain rates are valid, but the local strain rates can be many orders of magnitiude higher as exemplified by atomic force microscopy. A number of modes of deformation are encountered during scratching. They include deformation bands, crazing, tearing, microcracking, regular cracking, and grooving. Crazing-tearing is the predominant mode of scratch deformation. It is envisaged that the sequence of tearing along the craze involves formation of deformation bands, development of craze, followed by tearing. Atomic force and scanning electron microscopy of scratch surface damage indicated that the nature and modes of scratch deformation are qualitatively similar to the case of uniaxial tensile deformation, implying similarities in the deformation behaviour between scratch and tensile deformation.