Electrochemical and spectroscopic investigation of synergestic effects in corrosion inhibition of aluminium bronze Part 1 – in pure HCl

Abstract

The synergistic inhibition of aluminium bronze corrosion by 4-phenyl semicarbazide hydrochloride (PSC) and the iodide ion in HCl of pH (1·8-2) at 60°C has been assessed by polarisation studies, Tafel plots, X-ray photoelectron spectroscopy and Auger electron spectroscopy. The addition of 0·01M KI to 0·01M PSC improved the inhibition efficiency from 86 to 94% owing to the formation of a CuI-PSC complex which is more compact, protective and hard than the film formed in the absence of iodide. The inner layer of this protective film contains a small amount of aluminium oxide, which increases the protective nature of the film and retards the dissolution of the underlying aluminium bronze.