Ruthenium oxide for effective activation of aluminium sacrificial anodes: A new approach

Abstract

Ruthenium oxide, one of the excellent electrocatalysts having high conductivity and high chemical and thermodynamic stability, has been coated onto the surface of an electrode made from a Al–5 wt-%Zn alloy. The activated aluminium ion was able to diffuse through the porous catalytic hydrophilic layer. Ruthenium oxide coated Al–Zn alloy anodes displayed high open circuit potential and high closed circuit potential during galvanic exposure with mild steel cathodes. A galvanic efficiency as high as 86% with an actual current capacity of 2573 A h kg^-1 was achieved. The RuO₂ film underwent very little deterioration and a considerable mass of the ruthenium oxide film persisted on the anode surface, even after the electrode size had been reduced to one third of its original size owing to galvanic dissolution. These electrodes are economically efficient, as convenient to prepare, install and use as other conventional electrodes, are tolerable of very aggressive media and highly efficient, even under high galvanic current loads.