In this study, novel nanocomposite films of chitosan with fructose modified multi-walled carbon nanotube were prepared by solution casting technique. The fructose modified multi-walled carbon nanotube and the resulting bionanocomposite films were characterized using thermogravimetric analysis, Fourier transform infrared spectroscopy, field emission scanning electron microscopy, atomic force microscopy and transmission electron microscopy. The transmission electron microscopy showed that the presence of the functional moieties helped to improve the dispersion and compatibility of the multi-walled carbon nanotubes in the chitosan matrix. The tensile strength of bionanocomposite films was increased from 32 MPa for the pure chitosan film up to 62.96 MPa for the nanocomposite with 7 wt% addition of fructose modified multi-walled carbon nanotube.
SudhakarMTrishulADobleM. Biofouling and biodegradation of polyolefins in ocean waters. Polym Degrad Stabil2007; 92: 1743–1752.
2.
BonhommeSCuerADelortAM. Environmental biodegradation of polyethylene. Polym Degrad Stabil2003; 81: 441–452.
3.
MiyazakiKAraiTShibataK. Study on biodegradation mechanism of novel oxo-biodegradable polypropylenes in an aqueous medium. Polym Degrad Stabil2012; 97: 2177–2184.
4.
SinghJDuttaPKDuttaJ. Preparation and properties of highly soluble chitosan–l-glutamic acid aerogel derivative. Carbohydr Polym2009; 76: 188–195.
5.
RutnakornpitukMNgamdeePPhinyocheepP. Preparation and properties of polydimethylsiloxane-modified chitosan. Carbohydr Polym2006; 63: 229–237.
NajeebCKChangJLeeJ-H. Preparation of semiconductor-enriched single-walled carbon nanotube dispersion using a neutral pH water soluble chitosan derivative. J Colloid Interface Sci2011; 354: 461–466.
8.
Fernández-SaizPLagaronJM. Chitosan for film and coating applications. In: Plackett D (ed.) Biopolymers – new materials for sustainable films and coatings, Chichester, UK: John Wiley & Sons, Ltd, 2011, pp. 87–105.
9.
CarsonLHibbertKAkindojuF. Synthesis, characterization and stability of chitosan and poly(methyl methacrylate) grafted carbon nanotubes. Spectrochimica Acta A Molecul Biomolecul Spectrosc2012; 96: 380–386.
10.
Kim SK. Marine cosmeceuticals: trends and prospects. Taylor & Francis, CRC Press, 2011.
11.
SalmahHAzieyantiAN. Properties of recycled polyethylene/chitosan composites: the effect of polyethylene-graft-maleic anhydride. J Reinf Plast Compos2011; 30: 195–202.
12.
NavarroCHMorenoKJArizmendi-MorquechoA. Preparation and tribological properties of chitosan/hydroxyapatite composite coatings applied on ultra high molecular weight polyethylene substrate. J Plast Film Sheet2012; 28: 279–297.
13.
OngYTAhmadALZeinSHS. A review on carbon nanotubes in an environmental protection and green engineering perspective. Brazilian J Chem Eng2010; 27: 227–242.
14.
AbdolmohammadiSWan YunusWMZAB RahmanMZ. Effect of organoclay on mechanical and thermal properties of polycaprolactone/chitosan/montmorillonite nanocomposites. J Reinf Plast Compos2011; 30: 1045–1054.
PlaneixJMCoustelNCoqB. Application of Carbon Nanotubes as Supports in Heterogeneous Catalysis. J Am Chem Soc1994; 116: 7935–7936.
17.
HobbsJMPatelNNKimDW. Glucose determination in beverages using carbon nanotube modified biosensor: an experiment for the undergraduate laboratory. J Chem Edu2013; 90: 1222–1226.
18.
ArmentanoIDottoriMFortunatiE. Biodegradable polymer matrix nanocomposites for tissue engineering: a review. Polym Degrad Stabil2010; 95: 2126–2146.
19.
WangS-FShenLZhangW-D. Preparation and mechanical properties of chitosan/carbon nanotubes composites. Biomacromolecules2005; 6: 3067–3072.
20.
MoultonSEMinettAIMurphyR. Biomolecules as selective dispersants for carbon nanotubes. Carbon2005; 43: 1879–1884.
21.
ShiehY-TYangY-F. Significant improvements in mechanical property and water stability of chitosan by carbon nanotubes. Eur Polym J2006; 42: 3162–3170.
22.
SalamMAMakkiMSIAbdelaalMYA. Preparation and characterization of multi-walled carbon nanotubes/chitosan nanocomposite and its application for the removal of heavy metals from aqueous solution. J Alloys Compound2011; 509: 2582–2587.
23.
ChatterjeeSLeeMWWooSH. Adsorption of congo red by chitosan hydrogel beads impregnated with carbon nanotubes. Bioresource Technol2010; 101: 1800–1806.
24.
SolankiPRKaushikAAnsariAA. Multi-walled carbon nanotubes/sol–gel-derived silica/chitosan nanobiocomposite for total cholesterol sensor. Sensors Actuat B Chem2009; 137: 727–735.
25.
YangYYangGHuangY. A new hydrogen peroxide biosensor based on gold nanoelectrode ensembles/multiwalled carbon nanotubes/chitosan film-modified electrode. Colloid Surf A Physicochem Eng Aspects2009; 340: 50–55.
MallakpourSZadehnazariA. One-pot synthesis of glucose functionalized multi-walled carbon nanotubes: dispersion in hydroxylated poly(amide-imide) composites and their thermo-mechanical properties. Polymer2013; 54: 6329–6338.
28.
AbdolmalekiAMallakpourSBorandehS. Amino acid-functionalized multi-walled carbon nanotubes for improving compatibility with chiral poly(amide-ester-imide) containing l-phenylalanine and l-tyrosine linkages. Appl Surf Sci2013; 287: 117–123.
29.
MallakpourSSoltanianS. Chemical modification of MWCNTs with 5-aminoisophthalic acid and its effects on the thermal and morphological properties of chiral poly (ester-imide)/MWCNT nanocomposites having N-trimellitylimido-L-isoleucine moieties. J Polym Res2014; 21: 1–9.
30.
Mallakpour S, Abdolmaleki A and Rostami M. Morphology and thermal properties of environmental friendly nanocomposites using biodegradable poly(amide–imide) based on N-trimellitylimido-S-valine matrix reinforced by fructose-functionalized multi-walled carbon nanotubes. Colloid Polym Sci 2014; 293: 545--553.
31.
Pérez-CaberoMRodríguez-RamosIGuerrero-RuízA. Characterization of carbon nanotubes and carbon nanofibers prepared by catalytic decomposition of acetylene in a fluidized bed reactor. J Catalysis2003; 215: 305–316.
32.
YenM-TYangJ-HMauJ-L. Physicochemical characterization of chitin and chitosan from crab shells. Carbohydr Polym2009; 75: 15–21.
33.
LópezFAMercêALRAlguacilFJ. A kinetic study on the thermal behaviour of chitosan. J Therm Anal Calorim2008; 91: 633–639.
