Liquid-liquid equilibria (LLE) data were measured for ternary system epoxidized soybean oil (ESO) + acetic acid + water at 313.15, 323.15 and 333.15 K, respectively. The consistency of the measured LLE data was tested, using Othmer-Tobias correlation and root-mean-square deviation (δ) in mass fraction of water in the lower phase and average value of the absolute difference (AAD) between experimental mass fraction of epoxidized soybean oil in the upper phase and that calculated using Othmer-Tobias correlation.
GoudVV, PatwardhanAV, PradhanNC. (2007) Kinetics of in situ epoxidation of natural unsaturated triglycerides catalyzed by acidic ion exchange resin. Industrial and Engineering Chemistry Research, 46, 3078–3085.
2.
WarwelS, Rüsch gen KlaasM, WarwelS. (1999) Complete and partial epoxidation of plant oils by lipase catalyzed perhydrolysis 1. Industrial Crops and Products, 9, 125–132.
3.
Sinadinović-FišerS, JankovićM, PetrovićZS. (2001) Kinetics of in situ epoxidation of soybean oil in bulk catalyzed by ion exchange resin. Journal of the American Oil Chemists’ Society, 78, 725–731.
4.
RangarajanB, HaveyA, GrulkeEA, CulnanPD. (1995) Kinetic parameters of a two-phase model for in situ epoxidation of soybean oil. Journal of the American Oil Chemists’ Society, 72, 1161–1169.
5.
WangLS, ChuJZ. (1996) Measurement of liquid-liquid equilibrium data in a ternary system cotton seed oil / acetic acid / water. Beijing Institute of Technology, 16, 215–219.
6.
JankovićM, Sinadinović-FišerS, LamshoeftM. (2010) Liquid-liquid equilibrium constant for acetic acid in an epoxidized soybean oil-acetic acid-water system. Journal of the American Oil Chemists’ Society, 87, 591–600.
7.
RaoDS, RaoKV, PrasadAR, ChiranjiviC. (1979) Extraction of acetonitrile from aqueous mixtures. 2. Ternary liquid equilibria. Journal of Chemical & Engineering Data, 24, 241–244.
8.
GB/T 1676-2008. (2008) Determination of the iodine value of plasticizers. Standards Press of China. Beijing, China.
9.
GB 1677-2008. (2008) Determination of the epoxy value of plasticizers. Standards Press of China. Beijing, China.
10.
GB/T 1668-2008. (2008) Plasticizers-Determination of acid value and acidity. Standards Press of China. Beijing, China.
11.
LiGH. (2006) Inspection and analysis of oils & oil seeds. Chemical Industry Press. Beijing, China. 97–98.
12.
SwernD. (1979). Bailey's Industrial Oils and Fat Products, 4th Ed. Wiley, New York.
