Preparation of silver/silver bromide/titanium dioxide/graphene oxide nanocomposite for photocatalytic degradation of 4-chlorophenol

Abstract

A ultaviolet–visible light responded photocatalytic nanocomposite, silver/silver bromide/titanium dioxide, supported on graphene oxide (GO; silver/silver bromide/titanium dioxide/GO) was fabricated via a layer intercalation method using n-butylamine, cetyltrimethyl ammonium bromide, titanium dioxide and silver/silver bromide-intercalated GO successively. The resultant silver/silver bromide/titanium dioxide/GO exhibited much stronger visible light absorption and enhanced photocatalytic efficiency than titanium dioxide/GO and titanium dioxide. Furthermore, the degradation efficiency of silver/silver bromide/titanium dioxide/GO was improved when irradiated under light without the ultaviolet cut filter. The apparent degradation rate constants, k, for silver/silver bromide/titanium dioxide/GO, titanium dioxide/GO and titanium dioxide are 0.5192, 0.2273 and 0.0627 h⁻¹. A possible photocatalytic degradation mechanism for degradation of 4-chlorophenol by silver/silver bromide/titanium dioxide/GO under irradiation with/without the ultaviolet cut filter was proposed. The factors including the visible light response from silver bromide, surface plasmon ‘hot’ electron effect from silver nanoparticles and efficient electron transfer among silver, silver bromide, titanium dioxide and GO are contributed to enhance the photocatalytic activity under visible light irradiation, while the additional factor of ultaviolet light response from titanium dioxide plays an important role under light irradiation without the ultaviolet cut filter. The resultant silver/silver bromide/titanium dioxide/GO possessed a good photochemical stability and reusability.

Keywords

Nanocomposite graphene oxide photocatalytic degradation plasmon hot electron 4-chlorophenol

Introduction

Chlorophenol is an important organochloride intermediate that has been widely used as antiseptics, herbicides and pesticides.^1
–3 Although most chlorophenols are moderate toxicity, they are easy to accumulate in the environment and human body, hard to degradate and have a strong medicinal taste and smell, leading serious risks to the environment and human health, and be classified as persistent organic pollutants (POPs). Therefore, the treatment of chlorophenols has become a challenging task. Photocatalytic degradation technology is an alternative solution to solve this problem, especially in wastewater treatment, due to its advantages of strong oxidation ability, simple operation and low energy consumption.

As a typical semiconductor photocatalyst, titanium dioxide (TiO₂) has been widely studied for air and water purification applications, due to its unique properties such as high photocatalytic activity, low cost and non-toxicity.^4
–6 However, the wide band gap (approximately 3.2 eV) of TiO₂ limits its application to ultaviolet (UV) environments, which means it utilizes no more than 5% of the total solar energy. Efforts on improving the photocatalytic efficiency of TiO₂ have been extensively investigated in recent studies,^4

–7 mainly focus on lowering the band gap by doping or coupling TiO₂ with noble metals, semiconductors, transition and non-metal anions, and thereby increasing its photocatalytic activity to visible light range.

Recently, silver/silver halide (Ag/AgX) plasmon resonance photocatalysts have triggered considerable attentions due to their excellent photocatalytic activity in the visible light range.^8
–10 Generally, TiO₂ exhibits high photocatalytic efficiency by short-time UV light irradiation, whereas most visible light photocatalysts require much longer visible light irradiation time to achieve the same photocatalytic efficiency. Therefore, in order to obtain high photocatalytic efficiency in the broad UV–visible (UV-Vis) spectral range, TiO₂ and Ag/silver bromide(AgBr) were composited on graphene oxide (GO) sheets to get Ag/AgBr/TiO₂/GO photocatalytic nanocomposite in this work. As we know, GO is an outstanding photocatalyst carrier, due to its large surface area, high adsorption ability and good solubility and intercalation properties in aqueous solution.^11
–13 Besides, GO can increase the charge separation and decrease the recombination of photogenerated electron–hole pairs (e⁻–h⁺) and surface-adsorbed amount of organic molecules through π–π interactions. In this work, the Ag/AgBr/TiO₂/GO nanophotocatalyst was synthesized using n-butylamine (n-BA), cetyltrimethyl ammonium bromide (CTAB), TiO₂ and Ag/AgBr-intercalated GO successively. The resultant Ag/AgBr/TiO₂/GO exhibited high UV-Vis light photocatalytic activity for the degradation of 4-chlorophenol (4-CP) solution and kept stable even after five consecutive photodegradation cycles. The photocatalytic mechanism of Ag/AgBr/TiO₂/GO under light irradiation with/without UV cut filter was discussed respectively.

Experimental

Materials

Silver nitrate (AgNO₃), TiO₂ powder, CTAB, n-BA and 4-CP were all analytical grade and purchased from Sinopharm Chemical Reagent Co., Ltd. Natural graphite powder (44 μm) was provided by Qingdao Zhongtian Company. The chemicals were used without further purification.

Preparation of Ag/AgBr/TiO₂/GO photocatalyst

As descripted by Figure 1, Ag/AgBr/TiO₂/GO nanocomposite was fabricated by intercalation of GO as followed with n-BA, CTAB, TiO₂ and Ag/AgBr. GO was prepared from purified natural graphite using a modified Hummers’ method¹⁴; 50 mg of the obtained GO powder and 2.5 mL of n-BA were dispersed in 50 mL of water by sonication, forming a stable GO–n-BA colloid. After 30 min, 12 mL of CTAB (0.05 mol·L^–1) aqueous solution was added and then sonicated for 30 min to form a GO–CTAB colloid; 0.5 g of TiO₂ powder that pre-sonicated in 35 mL of water was added slowly into the above GO–CTAB colloid under sonication. After the suspension was stirred for additional 2 h, TiO₂/GO was obtained. At last, the solution mixed with 0.21 g of AgNO₃, 2.3 mL of NH₃·H₂O and 5 mL of water was quickly added into the suspension of TiO₂/GO and then kept stirring for 12 h. The Ag/AgBr/TiO₂/GO sample can be obtained by centrifugation (4400 r min⁻¹, 8 min) of the mixture and washed with isopropyl alcohol, alcohol and water, respectively, and then dried at 60°C under vacuum for 12 h.

Figure 1.

Schematic illustration of the preparation of Ag/AgBr/TiO₂/GO. AgBr: silver bromide; Ag: silver; TiO₂: titanium dioxide; GO: graphene oxide.

Characterization

X-ray diffraction (XRD) patterns of samples were scanned on a D8 Advanced X-ray diffractometer (Bruker, Karlsruhe, Germany) using Cu K_α radiation (λ = 0.1542 nm). The diffraction data were recorded for 2θ angles between 2° and 80°. Morphology analyses of the samples were carried out on JEOL JEM-2100 transmission electron microscope (TEM, Japan) and JEOL JSM-6010 scanning electron microscope (SEM, Japan). UV-Vis diffuse reflectance spectroscopy (UV-Vis DRS) was carried out on an UV-3010 UV-Vis spectrophotometer (Hitachi, Japan).

Evaluation of photocatalytic performance

The photocatalytic activity of Ag/AgBr/TiO₂/GO composite was examined through photodegradation of 4-CP. Typically, 100 mg of Ag/AgBr/TiO₂/GO was dispersed into a 100 mL aqueous solution of 4-CP (20 mg·L⁻¹). The pH value of 4-CP solution was adjusted to 4. Prior to irradiation, the dispersion was kept in the dark under magnetic stirring for 1 h to establish an adsorption–desorption equilibrium state. The irradiation light was provided by a Xenon arc lamp (500 W), operated on a GHX-2 photochemical reactor. The temperature of the reaction was kept at about 25°C by recycled water. Air was bubbled through the reaction solution from the bottom with an air flow of 250 mL·min⁻¹ to ensure effective dispersion. To monitor the photodegradation, 3 mL of dispersion was taken out from the reaction system at certain time intervals and separated through centrifugation and then monitored by UV-Vis spectroscopy (Shimadzu UV-2450) through recording the absorbance changes. For comparison, the photocatalytic performances of TiO₂ and TiO₂/GO were investigated under the same condition.

Results and discussion

Characterization of the as-synthesized nanocomposite

The powder XRD peak of GO was observed at around 2θ = 12° corresponding to the interlayer d-spacing of GO (approximately 0.74 nm), which could be attributed to the intercalation of hydrophilic polar oxygen functional groups on the surface of graphite during its oxidation (Figure 2). After GO intercalated with n-BA, the interlayer d-spacing enlarged to approximately 0.94 nm (2θ = 9.4°), which is slightly larger than the chain length of n-BA (0.73 nm). The intercalation with n-BA broadened the interlayer space of GO, which facilitated the following intercalation with large molecules. Subsequently, the diffraction peak of GO intercalated with CTAB was observed at a lower angle of 4.4° corresponding to the interlayer d-spacing of approximately 2 nm. It should be noted that the intensity of interlayer peak became weaker and weaker after the intercalation, which means the regular stacks of GO were destroyed in some degree during the intercalation.^15,16 Finally, the interlayer peak was disappeared in the sample of GO intercalated with TiO₂. As shown in Figure 2(d), the diffraction peaks observed in as-synthesized TiO₂/GO samples are all ascribed to the characteristic Bragg reflections of anatase TiO₂ (JCPDS file 21-1272). No diffraction peak for GO component was observed. For Ag/AgBr/TiO₂/GO, the diffraction peaks at approximately 26.7° (111), 31.0° (200), 44.4° (220), 55.0° (222) and 73.21° (420) could be assigned to AgBr (JCPDS file 6-438), while the peak at approximately 44.4° (200) and 64.5° (220) could be indexed to metallic Ag⁰ (JCPDS file 65-2871). It indicated the AgBrs were essentially in a form of Ag/AgBr structure in Ag/AgBr/TiO₂/GO. To further investigate the structures of Ag/AgBr/TiO₂/GO, morphologic analyses were carried out.

Figure 2.

XRD patterns of the resultant. (a) GO, (b) GO–n-BA, (c) GO–CTAB, (d) TiO₂/GO, and (e) Ag/AgBr/TiO₂/GO. AgBr: silver bromide; XRD: X-ray diffraction; GO: graphene oxide; n-BA: n-butylamine; CTAB: cetyltrimethyl ammonium bromide; Ag: silver; TiO₂: titanium dioxide.

The microscopic morphologies and structures of Ag/AgBr/TiO₂/GO were observed via TEM and SEM. Figure 3 shows that the almost transparent and crumpled silk-like GO sheets were decorated by two kinds of nanoparticles: TiO₂ nanoparticles with an average diameter of approximately 40 nm and the large AgBr nanoparticles with an average diameter of approximately 350 nm. It is known from recent works^8
–10 and our previous work¹⁷ that the small nanoparticles (approximately 30 nm) adhered onto the surface of AgBr were Ag⁰ decomposed from AgBr. The calculated mole ratio of Ag–Br–Ti of Ag/AgBr/TiO₂/GO composite from Energy-dispersive X-ray spectroscopy (EDS) image was 10:9:81 (Online Supplementary Figure S1), indicating that a small proportion (10%) of AgBr is decomposed into metallic Ag⁰, which agrees well with the XRD spectrum.

Figure 3.

(a) TEM image of the resultant Ag/AgBr/TiO₂/GO. (b) SEM image of the resultant Ag/AgBr/TiO₂/GO. AgBr: silver bromide; TEM: transmission electron microscope; Ag: silver; TiO₂: titanium dioxide; GO: graphene oxide; SEM: scanning electron microscope.

UV–Vis DRS spectra of TiO₂, TiO₂/GO and Ag/AgBr/TiO₂/GO photocatalysts are compared in Figure 4. TiO₂/GO exhibited stronger visible light absorption and a red shift to longer wavelength range compared to TiO₂ due to the incorporation of GO. For Ag/AgBr/TiO₂/GO, the surface plasmon resonance (SPR) of Ag nanoparticles¹⁸ and visible light responded AgBr nanoparticles¹⁹ can strongly absorb visible light. Therefore, Ag/AgBr/TiO₂/GO showed significant enhancement of absorption in the visible light range compared to TiO₂ and TiO₂/GO. The band gap energy (E_g ) of TiO₂ species can be calculated by Tauc plot of DRS spectra. The E_g of Ag/AgBr/TiO₂/GO (approximately 2.4 eV) was lower than that of TiO₂/GO (approximately 2.7 eV) and TiO₂ (approximately 3.0 eV), which indicated that the visible light absorption ability of TiO₂ was enhanced after it composited with Ag/AgBr and GO.

Figure 4.

(a) UV-Vis DRS spectra of TiO₂, TiO₂/GO and Ag/AgBr/TiO₂/GO and (b) Tauc plots of these nanocomposites. AgBr: silver bromide; UV-Vis: ultaviolet–visible. UV-Vis DRS: UV-Vis diffuse reflectance spectroscopy; TiO₂: titanium dioxide; GO: graphene oxide; Ag: silver.

Photocatalytic performance for degradation of 4-CP

To evaluate the photocatalytic activity of the resultant Ag/AgBr/TiO₂/GO, firstly, the photodegradations of 4-CP were carried out under visible light irradiation provided by a Xenon arc lamp with a UV cut filter (λ ≥ 400 nm). For comparison, the photodegradations of 4-CP in the presence of TiO₂ and TiO₂/GO were carried out under the same condition. Figure 5 shows that the presence of Ag/AgBr and GO enhanced the 4-CP degradation under visible light irradiation. About 86.8% of 4-CP were removed after irradiated for 5 h in the presence of Ag/AgBr/TiO₂/GO, while 44.7% and 8.0% removal for TiO₂/GO and TiO₂, respectively. Generally, TiO₂ can only be activated under UV light irradiation but has almost no response under visible light irradiation, due to its wide band gap (approximately 3.2 eV). The TiO₂ sample showed only little removal of 4-CP, which could be originated from the photolysis of 4-CP and the adsorption of 4-CP on TiO₂. It should be mentioned that with the addition of GO, TiO₂/GO showed some extent of visible light activity, which was also presented in Figure 4. Recent researches^20
–22 have claimed that a C–Ti or C–O–Ti bond could be formed in the TiO₂/GO nanocomposites, which acted as doping in TiO₂, leading TiO₂/GO to be a visible light driven photocatalyst. Furthermore, GO could enhance the electron–holes separation through its π–π graphitic carbon network,^{13

–23} thus improve the degradation efficiency. For Ag/AgBr/TiO₂/GO nanocomposite, four factors could contribute to its high visible light photocatalytic activity, including the SPR effect of Ag nanoparticles¹⁸; AgBr possesses a band gap of approximately 2.6 eV which could be excited by visible light¹⁹; the efficient charge transfer among Ag, AgBr, TiO₂ and GO²⁴; and the large surface area and π–π conjugated carbon network could increase surface-adsorbed amount of chemical molecules and facilitate the fast and long-range interfacial charge transfer.²³

Figure 5.

Photocatalytic activities of the resultant TiO₂, TiO₂/GO and Ag/AgBr/TiO₂/GO for photodegradation of 4-CP molecules under light irradiation (a) with and (b) without the UV cut filter λ ≥ 400 nm. (c) Effect of the UV cut on the photodegradation of 4-CP; (d) pseudo-first-order reaction kinetics fitting. AgBr: silver bromide; UV: ultaviolet; TiO₂: titanium dioxide; GO: graphene oxide; Ag: silver; 4-CP: 4-chlorophenol.

Secondly, the photodegradations of 4-CP were also carried out with the same Xenon lamp but without the UV cut filter. All of the three samples showed enhanced photocatalytic activities in this case (Figure 5(b) and (c)). As we know, the light provided by a Xenon arc lamp is very similar to natural sunlight in the UV and visible light ranges. The output percentages of UV, visible and infrared light are 10.9, 33.9 and 55.1%, respectively. TiO₂ could be excited by UV light and generate electron–hole pairs to exhibit efficient photocatalytic activity for degrading 4-CP. Due to TiO₂ was excited, the time for degradation of 4-CP was reduced, and the degradation efficiencies of these TiO₂ nanospecies were improved. After irradiated for 5 h, the removal of 4-CP reached to 91.5% in the presence of Ag/AgBr/TiO₂/GO, while 65.5 and 26.5% removal for TiO₂/GO and TiO₂, respectively.

At low concentration of 4-CP, the pseudo-first-order kinetics model, a simplified form of Langmuir–Hinshelwood model,²⁵ was roughly applied for analysis of the photocatalytic degradation kinetics of 4-CP in our system

r_{0} = - \frac{d C}{d t} = - k \times C

In (\frac{C_{0}}{C}) = k \times t

where r₀ is the initial reaction rate, C is the concentration of 4-CP, C₀ is the initial concentration of 4-CP, k is the apparent rate constant and t is the reaction time.

As shown in Figure 5(d), the calculated values of apparent rate constants k for Ag/AgBr/TiO₂/GO, TiO₂/GO and TiO₂ are 0.5192, 0.2273 and 0.0627 h⁻¹, respectively. The k value of Ag/AgBr/TiO₂/GO is 2.28 and 8.28 times than those of TiO₂/GO and TiO₂. The enhancement could be contributed to the composition of Ag/AgBr and GO with TiO₂. Its interesting that the value of the second point refers to k₁ h for Ag/AgBr/TiO₂/GO and TiO₂/GO is smaller than the fitted line in Figure 5(d). Recent researches^{1

–26} have noted that 4-CP would first be converted to p-benzoquinone/phenol in its early stage of reaction and then followed by the degradation process. Therefore, the rate of absorbance reducement looks a bit slower than it should be in the first 1-h irradiation for Ag/AgBr/TiO₂/GO and TiO₂/GO.

The stability of Ag/AgBr/TiO₂/GO was further investigated by recycling it for 4-CP degradation as shown in Figure 6. In the photodegradations cycles, Ag/AgBr/TiO₂/GO was easily recycled by simple centrifugation without any other treatment. As shown in Figure 6, the high photocatalytic activity was still achieved without significant decrease after five consecutive cycles. The previous research of our group¹⁷ has shown that Ag/AgBr could keep stable in GO-based nanocomposites under light irradiation. It is found that the Ag/AgX photocatalysts, especially Ag/AgX deposited on a conducting support, are quite stable and high efficient. The stability of the Ag/AgX photocatalysts under light irradiation arises from the clusters of Ag atoms around AgX surface which restrict the decomposition of AgX, in fact most likely from that a photon is absorbed by the Ag nanoparticles, and an electron separated from an absorbed photon remains in the nanoparticles rather than being transferred to the Ag⁺ ions of the AgX lattice. In this article, the morphology of Ag/AgBr/TiO₂/GO did not display significant changes after five cycling photodegradations in Online Supplementary Figure S2. Based on the above results and discussion, Ag/AgBr/TiO₂/GO could keep structure stable and exhibit good reusability and photochemical stability during the photocatalytic process.

Figure 6.

Five consecutive cycling photodegradation curves of 4-CP over Ag/AgBr/TiO₂/GO under light irradiation without the UV cut filter. AgBr: silver bromide; UV: ultaviolet; 4-CP: 4-chlorophenol; Ag: silver; TiO₂: titanium dioxide; GO: graphene oxide.

Proposed photocatalytic mechanism

Armed with the above results, a possible photocatalytic mechanism for degradation of 4-CP by Ag/AgBr/TiO₂/GO under visible light irradiation with/without the UV cut filter was proposed in Figure 7. When irradiated with light of λ ≥ 400 nm, TiO₂ could not be activated and the photoelectrons could only be generated from the photoexcited AgBr and plasmonexcited Ag (Figure 7(a)). Due to the polarization field provided by AgBr core,²⁷ the plasmonexcited ‘hot’ electrons on the surface of Ag transferred quickly to GO or the conduction band (CB) of TiO₂ and then trapped by O₂ in the solution to form superoxide ions (O₂ ^–) and other reactive oxygen species. The photoexcited electrons generated from AgBr could be captured by Ag and then transfer to GO or CB of TiO₂, and then trapped by O₂ to form O₂ ^–, while the photoholes could combine with H₂O to produce active ^·OH for oxidation of 4-CP.

Figure 7.

Proposed photocatalytic mechanism of Ag/AgBr/TiO₂/GO for photodegradation of 4-CP under irradiation (a) with and (b) without the UV cut filter. AgBr: silver bromide; Ag: silver; TiO₂: titanium dioxide; GO: graphene oxide; 4-CP: 4-chlorophenol; UV: ultaviolet.

When irradiated under light without the UV cut filter, all of the three components (TiO₂, Ag and AgBr) could generate photoelectrons. Besides the photoexcited AgBr and plasmonexcited Ag, TiO₂ could be excited by the 10.9% output UV light from a Xenon arc lamp. Although the proportion of UV light is small, the superior UV photocatalytic efficiency of TiO₂ made a valuable contribution to the total degradation as illustrated in Figure 5(b) and (c).

Conclusion

In order to obtain high photocatalytic efficiency in the broad UV-Vis spectral range, Ag/AgBr/TiO₂/GO photocatalytic nanocomposite was synthesized using n-BA, CTAB, TiO₂ and Ag/AgBr-intercalated GO successively. The resultant Ag/AgBr/TiO₂/GO nanocomposite exhibited enhanced photocatalytic efficiency for the degradation of the POPs molecules 4-CP under light irradiation without the UV cut filter. The apparent degradation rate constants k for Ag/AgBr/TiO₂/GO, TiO₂/GO and TiO₂ are 0.5192, 0.2273 and 0.0627 h⁻¹, respectively. The higher photocatalytic activity could be attributed to visible light response from AgBr, UV light response from TiO₂, surface plasmon ‘hot’ electron effect from Ag nanoparticles and efficient electron transfer among Ag, AgBr, TiO₂ and GO. In addition, Ag/AgBr/TiO₂/GO nanocomposite possessed good photochemical stability and reusability after five degradation cycles. This work shows that the as-synthesized Ag/AgBr/TiO₂/GO has a potential for application in treating wastewater containing POPs using sunlight or indoor light.

Footnotes

Declaration of conflicting interests

The author(s) declared no potential conflicts of interest with respect to the research, authorship and/or publication of this article.

Funding

The author(s) disclosed receipt of the following financial support for the research, authorship, and/or publication of this article: This work was supported by the National Natural Science Foundation of China (51302113) and Natural Science Foundation of Jiangsu Province (BK20130512). We are also indebted to Jiangsu Training Programs for Innovation and Entrepreneurship for Undergraduate (201613986010Y).

Supplemental material

Supplementary material for this article is available online.

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Supplementary Material

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Preparation of silver/silver bromide/titanium dioxide/graphene oxide nanocomposite for photocatalytic degradation of 4-chlorophenol

Abstract

Keywords

Introduction

Experimental

Materials

Preparation of Ag/AgBr/TiO2/GO photocatalyst

Characterization

Evaluation of photocatalytic performance

Results and discussion

Characterization of the as-synthesized nanocomposite

Photocatalytic performance for degradation of 4-CP

Proposed photocatalytic mechanism

Conclusion

Footnotes

Declaration of conflicting interests

Funding

Supplemental material

References

Supplementary Material

Preparation of Ag/AgBr/TiO₂/GO photocatalyst