The tribological characteristics of graphene oxide (GO) coatings deposited by the electrophoretic deposition method on a novel honeycomb laser-engraved pattern on AISI 52100 alloy steel surface are evaluated and compared with that of commonly engraved patterns like Sierpinski, Gosper, Hilbert, and Peano. The electrophoretic deposition parameters were optimised using the Taguchi method with ethanol as electrolyte. The most critical parameter was identified to be post-deposition heat treatment temperature and the impact of the same on crack density for GO coating is found to be proportional to the coefficient of friction (COF). Scanning electron microscope (SEM), X-ray photoelectron spectroscopy (XPS) and energy dispersive x-ray spectroscopy (EDX) were used to analyse the coated samples and tribological tests were carried out using pin-on-disc equipment. The results reveal that the GO-coated honeycomb structure achieved superior tribological performance compared to other engraved patterns, with the lowest mean COF (0.18) and wear loss (0.29 × 10−3g), indicating a 58.6% decrease in COF and a 90% reduction in wear loss relative to the pure substrate. The results show that GO-coated honeycomb-engraved surfaces exhibit enhanced tribological behaviour, making them suitable for low-friction components in automotive, aerospace, and bearing applications.
HolmbergKAnderssonPErdemirA. Global energy consumption due to friction in passenger cars. Tribol Int2012; 47: 221–234.
2.
MiaoXLiuSMaL, et al.Ti3C2-graphene oxide nanocomposite films for lubrication and wear resistance. Tribol Int2022; 167: 107361.
3.
MoskalewiczTZimowskiSZychA, et al.Electrophoretic deposition, microstructure and selected properties of composite alumina/polyetheretherketone coatings on the ti-13Nb-13Zr alloy. J Electrochem Soc2018; 165: D116.
4.
LiHWangJGaoS, et al.Superlubricity between MoS(2). Monolayers., Adv Mater2017; 29: 1701474.
5.
VilhenaJGPimentelCPedrazP, et al.Atomic-Scale sliding friction on graphene in water. ACS Nano2016; 10: 4288–4293.
6.
YeZEgbertsPHanGH, et al.Load-Dependent friction hysteresis on graphene. ACS Nano2016; 10: 5161–5168.
7.
ZhangFYangKLiuG, et al.Recent advances on graphene: synthesis, properties and applications. Compos Part A Appl Sci Manuf2022; 160: 107051.
8.
GodwinGJaisinghSJPriyanMS, et al.Wear and corrosion behaviour of ti-based coating on biomedical implants. Surf Eng2021; 37: 32–41.
9.
ZhangYSunWMaM, et al.Deposition characteristics, microstructure and wear behaviour of co–WC composite coatings. Surf Eng2021; 37: 702–711.
10.
DhiflaouiHKhlifiKBarhoumiN, et al.Effect of voltage on microstructure and its influence on corrosion and tribological properties of TiO2 coatings. J Mater Res Technol2020; 9: 5293–5303.
11.
GorjiMRSanjabiSEdtmaierC. Combination of electrophoretic and electroless depositions to fabricate Ni/TiC cladding. Surf Eng2020; 36: 929–935.
12.
RoseleyNRNHyieKMMasdekNRN, et al.Evaluation of corrosion and erosive wear behaviour of Co-Ni-Fe coating deposited by electrodeposition method. Jurnal Tribologi2022; 34: 56–68.
13.
RoustaADorranianDElahiM. Electrophoretic deposition of cobalt oxide nanoparticles on aluminium substrate. Surf Eng2020; 36: 919–928.
14.
AkramMArshadNBraemA. Nanoparticle-modified coatings by electrophoretic deposition for corrosion protection of magnesium. Surf Eng2022; 38: 430–439.
15.
BoshNDeggelmannLBlattertC, et al.Synthesis and characterization of halar® polymer coating deposited on titanium substrate by electrophoretic deposition process. Surf Coat Technol2018; 347: 369–378.
16.
HosseiniMRAhangariMJoharMH, et al.Optimization of nano HA-SiC coating on AISI 316L medical grade stainless steel via electrophoretic deposition. Mater Lett2021; 285: 129097.
17.
AravindAKamalVVRaniS, et al.Tribological investigation of composite coating on AISI 52100 alloy steel using electrophoretic deposition. In: Lecture notes in mechanical engineering. Singapore: Springer Science and Business Media Deutschland GmbH, Springer Nature Singapore, 2024, pp.263–276.
18.
KamalVVchettiar ArunkumarSSBindu KumarK, et al.Parameter optimization of electrophoretically deposited graphene oxide coating on the frictional characteristics of AISI 52100 alloy steel. Proceedings of the Institution of Mechanical Engineers, Part E: Journal of Process Mechanical Engineering2023: 09544089221150714.
19.
MaYHanJWangM, et al.Electrophoretic deposition of graphene-based materials: a review of materials and their applications. J Materiomics2018; 4: 108–120.
20.
HildyardRMohammadpourMSaremi-YarahmadiS, et al.Multiscale Numerical and Experimental Analysis of Tribological Performance of GO Coating on Steel SubstratesMaterials (Basel)2019; 13(1): 41.
21.
MuraAWangHAdamoF, et al.Graphene coatings to enhance tribological performance of steel. Mech Adv Mater Struct2021; 28: 657–664.
22.
SomasundaramSRamesh BapuBRRaj JawaharR. Tribological characteristics of n-(GO/WC-10Co-4Cr) HVOF coatings under biolubricant conditions. Surf Eng2021; 37: 91–100.
23.
SulaimanMHRaofNADahnelAN. The investigation of PVD coating, cryogenic lubrication and ultrasonic vibration on tool wear and surface integrity in manufacturing processes. Jurnal Tribologi2021; 28: 105–116.
ChenSShenBSunF. The influence of normal load on the tribological performance of electrophoretic deposition prepared graphene coating on micro-crystalline diamond surface. Diam Relat Mater2017; 76: 50–57.
26.
HoCYHuangSMLeeST, et al.Evaluation of synthesized graphene oxide as corrosion protection film coating on steel substrate by electrophoretic deposition. Appl Surf Sci2019; 477: 226–231.
XuHZangJYuanY, et al.Preparation of multilayer graphene coatings with interfacial bond to mild steel via covalent bonding for high performance anticorrosion and wear resistance. Carbon N Y2019; 154: 156–168.
29.
SchneiderMWeiserMKrasmannC, et al.Electrophoretic deposition of carbon nanotubes on aluminium for capacitor application. Surf Eng2022; 38: –7.
30.
RezaeiolumAAliofkhazraeiMKarimzadehA, et al.Electrodeposition of Ni–mo and Ni–mo-(nano Al2O3) multilayer coatings. Surf Eng2018; 34: 423–432.
31.
Hemmati SaznaghiMGhorbaniMRiahifarR, et al.Study of the coating effect of mildly oxidized graphene on aluminium current collectors by electrophoretic deposition and drop-casting methods for Li-ion battery application. Mater Lett2024; 356: 135571.
32.
BaioccoGMennaESalviD, et al.Investigating tribological properties of electrophoretically deposited graphene nanoplatelets coatings on mild steel. Thin Solid Films2024; 793, 140279.
33.
FuseiniMZaghloulMMYAbakarD, et al.Revolutionizing copper pipe durability: shielding against corrosion with graphene oxide through electrophoretic application. J Compos Mater2025; 59: 947–962.
34.
ShivakotiIKibriaGCepR, et al.Laser surface texturing for biomedical applications: a review. Coatings2021; 11: 1–15.
35.
KümmelDHamann-SchroerMHetznerH, et al.Tribological behavior of nanosecond-laser surface textured Ti6Al4V. Wear2019; 422–423: 261–268.
36.
DingQWangLHuL. Tribology optimization by laser surface texturing: from bulk materials to surface coatings. In: Laser surface engineering: processes and applications. Singapore: Springer Nature Singapore, 2015, pp. 405–422. 10.1016/B978-1-78242-074-3.00016-7.
37.
Pallarés-AldeiturriagaDClaudelPGranierJ, et al.Femtosecond laser engraving of deep patterns in steel and sapphire. Micromachines (Basel)2021; 12(7): 804.
38.
MutlakFA-HAhmedAFNayefUM, et al.Improvement of absorption light of laser texturing on silicon surface for optoelectronic application. Optik (Stuttg)2021; 237: 166755.
39.
UherVGajdošPSnášelV, et al.Hierarchical hexagonal clustering and indexing. Symmetry (Basel)2019; 11(6): 731.
40.
Soltani-KordshuliFHarrisNZouM. Tribological behavior of polydopamine/polytetrafluoroethylene coating on laser textured stainless steel with hilbert curves. Friction2023; 11: 1307–1319.
41.
LuLZhangZGuanY, et al.Comparison of the effect of typical patterns on friction and wear properties of chromium alloy prepared by laser surface texturing. Opt Laser Technol2018; 106: 272–279.
42.
NikamMDShimpiDBholeK, et al.Design and development of surface texture for tribological application. in: Key Eng Mater. Trans Tech Publications Ltd, 2019, pp.55–59. https://doi.org/10.4028/www.scientific.net/KEM.803.55.
43.
SeguDZLuCHwangP, et al.Optimization of tribological characteristics of a combined pattern textured surface using taguchi design. J Mater Eng Perform2021; 30: 3786–3794.
44.
WangHLiYZhuH. Experimental study on the tribological performance of fractal-like textured surface under mixed lubrication conditions. Surf Coat Technol2016; 307: 220–226.
45.
DamascenoJPVKubotaLT. The Electronic Origin of the Zeta Potential is Supported by the Redox Mechanism on an Aqueous Dispersion of Exfoliated Graphite, Angewandte Chemie. International Edition2022; 61(52):e202214995.
46.
Mancillas-SalasSReynosa-MartinezACBarroso-FloresJ, et al.Impact of secondary salts, temperature, and pH on the colloidal stability of graphene oxide in water. Nanoscale Adv2022; 4(11): 2435–2443.
47.
RenWMuraSIrudayarajJMK. Modified graphene oxide sensors for ultra-sensitive detection of nitrate ions in water. Talanta2015; 143: 234–239.
48.
Taha-TijerinaJVenkataramaniDAicheleCP, et al.Quantification of the particle size and stability of graphene oxide in a variety of solvents. Part Part Syst Char2015; 32(3): 334–339.
49.
MindivanF. The Synthesis and Charecterization of Graphene Oxide (GO) and Reduced Graphene Oxide (RGO). Int Sci J Mach Technol Mater2016; 10(6): 32–35.
50.
DibaMGarcía-GallasteguiAKlupp TaylorRN, et al.Quantitative evaluation of electrophoretic deposition kinetics of graphene oxide. Carbon N Y2014; 67: 656–661.
51.
ArunaSTRajamKS. A study on the electrophoretic deposition of 8YSZ coating using mixture of acetone and ethanol solvents. Mater Chem Phys2008; 111: 131–136.
52.
DibaMFamDWHBoccacciniAR, et al.Electrophoretic deposition of graphene-related materials: a review of the fundamentals. Prog Mater Sci2016; 82: 83–117.
53.
SuYZhitomirskyI. Electrophoretic deposition of graphene, carbon nanotubes and composite films using methyl violet dye as a dispersing agent. Colloids Surf A Physicochem Eng Asp2013; 436: 97–103.
54.
HajizadehAAliofkhazraeiMHasanpoorM, et al.Comparison of electrophoretic deposition kinetics of graphene oxide nanosheets in organic and aqueous solutions. Ceram Int2018; 44: 10951–10960.
55.
FinneranIACarrollPBAllodiMA, et al.Hydrogen bonding in the ethanol-water dimer. Phys Chem Chem Phys2015; 17: 24210–24214.
56.
AyarMK. A review of ethanol wet-bonding: Principles and techniques. Eur J Dent2016; 10(01): 155–159.
57.
MozafariMRamedaniAZhangYN, et al.Thin films for tissue engineering applications. Thin Film Coatings for Biomaterials and Biomedical Applications2016: 167–195. 10.1016/B978-1-78242-453-6.00008-0
58.
SauroSRenzoSDICastagnolaR, et al.Comparison between water and ethanol wet bonding of resin composite to root canal dentin. Am J Dent2011; 24(1): 25.
59.
BanoNHussainIEL-NaggarAM, et al.Reduced graphene oxide nanocomposites for optoelectronics applications. Appl Phys A2019; 125: 15.
60.
DhanyaARHaridossPRamaprabhuS. Pt-decorated oxygen-vacancy-tuned high temperature hydrogen-annealed WO3 as an efficient anode electrocatalyst for PEMFC. Int J Hydrogen Energy2024; 89: 1394–1404.
61.
AhmadiMSalgınBKooiBJ, et al.Cracking behavior and formability of Zn-Al-Mg coatings: Understanding the influence of steel substrates. Mater Des2021; 212: 110215.
62.
LanzónMGarcía-VeraVETenza-AbrilAJ, et al.Use of image analysis to evaluate surface dispersion and covering performance of nanolime coatings sprayed on heritage material substrates. Appl Surf Sci2019; 480: 962–968.
63.
ZhangNYangFJiangF, et al.Study of the effect of surface laser texture on tribological properties of cemented carbide materials. Proc Inst Mech Eng B J Eng Manuf2020; 234(6-7): 993–1006.
