trans Influence of Telluro- and Thio-ether Donor Sites: First Palladium(II) Complex,[PdCI 2 {4-MeOC 6 H 4 TeCH 2 CH 2 SEt}],showing their Relative Magnitude in the Same Molecule †
Free accessResearch articleFirst published online December, 1999
trans Influence of Telluro- and Thio-ether Donor Sites: First Palladium(II) Complex,[PdCI 2 {4-MeOC 6 H 4 TeCH 2 CH 2 SEt}],showing their Relative Magnitude in the Same Molecule †
The synthesis of a (Te,S) ligand 4-MeOC6H4TeCH2CH2SEt (L) and its complex [PdCI2L] is followed by single crystal structure determination of the complex, which indicates that the Pd-CI bond length trans to the ArTe group [2.344(3) Å] is longer than that trans to SEt [2.316(4) Å], suggesting a stronger trans influence for the former.
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