Lithium hydride is efficiently used as a reducing agent in the ligated Ni0 catalysed homocoupling of aryl bromides and chlorides.
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Ligated Ni0 reagents were found to be very efficient in desulfurization of various sulfur containing compounds: (a) BeckerS., FortY., VanderesseR., and CaubereP., J. Org. Chem., 1989, 54, 4848; (b) S. Becker, Y. Fort and P. Caubere, J. Org. Chem., 1990, 55, 6194; (c) C. Kuehm-Caubere, A. Guilmart, S. Adach-Becker, Y. Fort and P. Caubere, Tetrahedron Lett., 1998, 39, 8987.
12.
In the presence of LiCl, the catalyst is difficult to prepare. Moreover, generation of our catalyst from NiCl2 is more difficult than from Ni(OAc)2: IllyS., TillementO., MachizaudF., DuboisJ. M., MassicotF., FortY., and GhanbajaJ., Philas. Mag. A, 1999, 79, 1021.
