[Rf2PPd(PhCHO)(Ph2PCH2CH2PPh2)] + SbF6-[Rf =o-C6H4C(CF3)20] 5 is prepared by the reaction of Rf2PPdCI(Ph2PCH2CH2PPh2) 1 with AgSbF6 in the presence of benzaldehyde in 92% yield, and the structure determined by X-ray diffraction analysis.
References
1.
SodeokaM., OhraiK., and ShibasakiM., J. Org. Chem., 1995 60 2648; SodeokaM., TokunohR., MiyazakiF., HagiwaraE. and ShibasakiM., Synlett, 1997, 463.
2.
JohnsonL. K., KillianC. M., and BrookhartM., J. Am. Chem. Soc., 1995, 117, 6414; FeldmanJ., McLainS. J., ParthasarathyA., MarshallW. J., CalabreseJ. C. and ArthurS. D., Organometallics, 1997, 16, 1514.
3.
BrumbaughJ. S., WhittleR. R., ParvezM., and SenA., Organometallics, 1990, 9, 1735; DghaymR. D., YaccatoK. J. and ArndtsenB. A., Organometallics, 1998, 17, 4.
4.
JohnsonL. K., MeckingS., and BrookhartM., J. Am. Chem. Soc., 1996, 118, 267; HagiwaraE., FujiiA. and SodeokaM., J. Am. Chem. Soc., 1998, 120, 2474.
5.
YamamotoY., OkazakiM., WakisakaY., and AkibaK.-y., Organometallics, 1995, 14, 3364.
ParksD. J. and PiersW. E., J. Am. Chem. Soc., 1996, 118, 9440; CiceroR. L. and ProtasiewiczJ. D., Organometallics, 1995, 14, 4792; GauH.-M., LeeC.-S., LinC.-C., JiangM.-K., HoY.-C. and KuoC.-N., J. Am. Chem. Soc., 1996, 118, 2936.
8.
KimY.-J., OsakadaK., TakenakaA. and YamamotoA., J. Am. Chem. Soc., 1990, 112, 1096; SeligsonA. L., CowanR. L. and TroglerW. C., Inorg. Chem., 1991, 30, 3371.
9.
OtwinowskiZ., University of Texas, Southwestern Medical Center. The program is available from Mac Science Co.
