Free accessResearch articleFirst published online 1999-4
Preparation of α-Heteroatom Substituted Allylic Alcohols by Reaction of ( E )-α-Selanylvinylzirconiums or ( E )-α-Trimethylsilylvinylzirconiums with Aldehydes †
Both (E)-α-selanylvinylzirconium and (E)-α-trimethylsilylvinylzirconium complexes undergo AgClO4-catalyzed reactions with aldehydes to give α-seleno- or α-trimethylsilyl-substituted allylic alcohols, respectively.
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