The effect of polypyrrole (PPy) and ionic liquid (IL) nanocoatings on the electrical properties of cellulose film has been investigated. Cellulose–PPy film was prepared by employ-ing the polymerization-induced adsorption process with controlled polymerization time. Nanocoating of IL was carried out by immersing cellulose–PPy film into an aqueous solution of 1-butyl-3-methylimidazolium tetrafluoroborate. Fourier-transform infrared spectroscopy, transmission electron microscopy, and secondary-ion mass spectrometry analysis showed the successful build-up of PPy and IL nanolayers over the cellulose film. The electrical properties of regenerated cellulose were enhanced several times by PPy and IL nanocoatings. The preparation, characterization, and electrical properties of cellulose–PPy–IL nanocomposite films are explained.
KimJ.YunS. R.OunaiesZ.Discovery of cellulose as smart material. Macromolecules, 2006, 39, 4202–4206.
2.
PushparajV. L.ShaijumonM. M.KumarA.MurugesanS.LijieC.VajtaiR.LinhardtR. J.NalamasuO.AjayanP. M.Flexible energy storage devices based on nanocomposite paper. Proc. Natl Acad. Sci USA, 2007, 104, 13574–13577.
3.
AgarwalM.LvovY.KodyV.Conductive wood microfibres for smart paper through layer-by-layer nanocoating. Nanotechnology, 2006, 17, 5319–5325.
4.
PengC. Q.ThioY. S.GerhardtR. A.Conductive paper fabricated by layer-by-layer assembly of polyelectrolytes and ITO nanoparticles. Nanotechnology, 2008, 19, 505603.
5.
TampieriA.SprioS.RuffiniA.CelottiG.LesciI. G.RoveriN.From wood to bone: multi-step process to convert wood hierarchical structures into biomimetic hydroxyapatite scaffolds for bone tissue engineering. J. Mater. Chem., 2009, 19, 4973–4980.
6.
YunS. R.JangS. D.YunG. Y.KimJ. H.KimJ.Paper transistor made with covalently bonded multiwalled carbon nanotube and cellulose. Appl. Phys. Lett., 2009, 95, 104102.
ZhangH.WangZ.ZhangZ.WuJ.ZhangJ.JiasongH.Regenerated cellulose/multiwalled-carbon-nanotube composite fibers with enhanced mechanical properties prepared with the ionic liquid 1-allyl-3-methylimidazolium chloride. Adv. Mater., 2007, 19, 698–704.
11.
Dall’AcquaaL.ToninaC.PeilaaR.FerrerobF.CatellanicM.Performances and properties of intrinsic conductive cellulose–polypyrrole textilesSynth. Met., 2004, 146, 213–221.
12.
EbrahimS. M.KashyoutA. B.SolimanM. M.Electrical and structural properties of polyaniline/cellulose triacetate blend films. J. Polym. Res., 2007, 14, 423–429.
13.
HydeK.RusaM.JuanH.Layer-by-layer deposition of polyelectrolyte nanolayers on natural fibers: cotton. Nanotechnology, 2005, 16, 422–428.
14.
JangS. D.KimJ. H.CaiZ.KimJ.The effect of chitosan concentration on the electrical property of chitosan-blended cellulose electroactive paper. Smart Mater. Struct., 2009, 8, 015003.
15.
LiY.JiangJ. H.MaX. D.DongG. X.WangJ.Paul SungK. L.Polypyrrole/oligonucleotide nanocomposite: its initial growth. Proc. IMechE, Part N: J. Nanoengineering and Nanosystems, 2008, 222(2), 57–63. DOI: 10.1243/17403499JNN14310.1243/17403499JNN143
16.
ZangL.YenM.BalakrishnanK.YangX.MooreJ. S.Expedient fabrication of well-defined nanofibres from a macrocycle molecule: solution-controlled self-assembly. Proc. IMechE, Part N: J. Nanoengineering and Nanosystems, 2010, 223(3–4), 139–147. DOI: 10.1243/17403499JNN19010.1243/17403499JNN190
17.
MahadevaS. K.KimJ.Nanocoating of ionic liquid and polypyrrole for durable electro-active paper actuators working under ambient conditions. J. Phys. D Appl. Phys., 2010, 43, 205502.
18.
McCormickC. L.CallaisP. A.HutchinsonB. H.Jr.Solution studies of cellulose in lithium chloride and N, N-dimethylacetamide. Macromolecules, 1985, 18, 2394–2401.
19.
YunS.KimJ.LeeK. S.Evaluation of cellulose electro-active paper made by tape casting and zone stretching methods. Int. J. Precision Engng Mf., 2010, 11, 987–990.
20.
HuangJ.IchinoseI.KunitakeT.Nanocoating of natural cellulose fibers with conjugated polymer: hierarchical polypyrrole composite materials. Chem. Commun., 2005, 1717–1719.
21.
SureshaK. M.LeeS. W.KimJ.Effect of heat treatment on the structure, piezoelectricity and actuation behavior of a cellulose electro active-paper actuator. Acta Mater., 2008, 56, 1868–1875.
22.
SureshaK. M.YiC.KimJ.Effect of room temperature ionic liquids adsorption on electromechanical behavior of cellulose electro-active paper. Macromol. Res., 2009, 17, 116–120.
23.
JiangJ.GaoD.LiZ.SuG.Gel polymer electrolytes prepared by in situ polymerization of vinyl monomers in room-temperature ionic liquids. React. Funct. Polym., 2006, 66, 1141–1148.
24.
MatsudaA.HonjoH.HirataK.TatsumisagoM.MinamiT.Electric double-layer capacitor using composites composed of phosphoric acid-doped silica gel and styrene–ethylene–butylene–styrene elastomer as a solid electrolyte. J. Power Sources, 1999, 77, 12–16.
25.
MihranyanA.NyholmL.BennettG. A. E.StrømmeM.A novel high specific surface area conducting paper material composed of polypyrrole and cladophora cellulose. J. Phys. Chem. B, 2008, 112, 12249–12255.
26.
RazaqA.MihranyanA.WelchK.NyholmL.StrømmeM.Influence of the type of oxidant on anion exchange properties of fibrous cladophora cellulose/polypyrrole composites. J. Phys. Chem. B, 2009, 113, 426–433.
