An untreated wool fabric was bleached both with sodium borohydride (SBH) in the presence of sodium bisulphite (SBS) solution and with a commercial H2O2 bleaching method. The concentration effects of SBH and SBS, bleaching time, pH and temperature on SBH bleaching process were investigated. Whiteness, yellowness and alkali solubility results were assessed for both bleaching methods. The results showed that whiteness degrees obtained with SBH bleaching was comparable with that of H2O2 bleaching method; whereas the alkali solubility values of the SBH bleaching was superior to the H2O2 bleaching.
References
1.
LiuX., HurrenC.J., and WangX., “Comparative Analyses of Two Selective Bleaching Methods an Alpaca Fibers”, Fibers and Polymers, 4, 2003, 124–128.
2.
LewisD.M., Wool Dyeing, Ed. LewisD. M.Society of Dyers and Colourists, Leeds, 1992, 112–116.
3.
GacenJ., and CayuelaD., “Comparison of Wool Bleaching with Hydrogen Peroxide in Alkaline and Acidic Media”, J. S. D. C., 116, 2000, 13–15.
4.
SchottsH.P., and StevensF., US6663677B2, Rohm and Haas Company, 2003.
5.
HöhnW., “Neuartiges Reduktionsmittel für die Textileveredlung”, Melliand Textile Berichte, 4, 2005, 264–266.
6.
MohanazadehF., HosiniM., and TajbakhshM., “Sodium Borohydride-Ammonium Carbonate: An Effective Reducing System for Aldehydes and Ketones”, Monatshefte für Chemie, 136, 2005, 2041–2043.
SchlessingerH.I., BrownH.C., FinholtA.E., GilbreathJ.R., HoekstraH.R., and HydeE.K., “Sodium Borohydride, Its Hydrolyses and Its Use as a Reducing Agent and in the Generation of Hydrogen”, J. Am. Chem. Soc., 75, 1953, 215–219.
YakabeS., HiranoM., and MorimotoT., “Hydogenation of Alkenes with Sodium Borohydride and Moist Alumina Catalyzed by Nickel Chloride”, A Tetrahedron Letters, 41, 2000, 6795–6798.
11.
HuaD., HanxiY., XinpingA., and ChuansinC., “Hydrogen Production from Catalytic Hydrolysis of Sodium Borohydride Solution Using Nickel Boride Catayst”, Int. J. Hydrogen Energy, 28, 2003, 1095–1100.
SmithS.M., WestmorelandD.J., and SchootsH.P., “Colorclear Technology, a New Method of Whitening of Wool, Machine Washable Wool and Wool/Cotton Blends”, Proceedings of 11th International Wool Research Conference, 4th-9th Sept. 2005.
NairG.P., and ShahR.C., “Sodium Borohydride in Vat Dyeing”, Text. Res. J., 40, 1970, 303–312.
16.
MeksiN., KechidaM., and MhenniF., “Cotton Dyeing by Indigo with the Borohydride Process: Effect of Some Experimental Conditions on Indigo Reduction and Dyeing Quality”, Chem. Eng. J., 131, 2007, 187–193.
17.
MeksiN., KechidaM., and MhenniF., “New Process of Dyeing Cotton Textile by Indigo with Borohydride: Effect of the Concentration of the Reducing Agent”, Int. J. Appl. Chem., 14, 2008, 1–14.
18.
GhoreishiS.M., and HaghighiR., “Chemical Catalytic Reaction and Biological Oxidation for Treatment of Non-Biodegradable Textile Effluent”, Chem. Eng. J., 95, 2003, 163–169.
19.
OuchiA., ObataT., SakaiH., and SakuragiM., “Laser Bleaching of Cellulosic Fabrics by Sodium Borohydride Aqueous Solution; a Total Chlorine Free Process”, Green Chem., 3, 2001, 221–223.
20.
CookM.M., Environmental Chemistry of Dyes and Pigments, Ed. ReifeA., and FreemanH. S., J Wiley & Sons Inc., USA, 1996, 33–41.
21.
OnionsW.J., Wool: An Introduction to Its Properties, Varieties, Uses and Production, Ernest Benn, London, 1962, 34–43.
22.
SimpsonW.S., Wool: Science and Technology. Ed: SimpsonW. S., and CrawshawG. H., Woodhead Publishing Limited, Cambridge, 2002, 142–143.
23.
BoehmeTH, Innovative Reducing Agent For the Textile Industry, Technical Bulletin BTR-TC/BS, 2, 2004, 9.