Sage Journals: Discover world-class research

Abstract

To develop a more effective primer, we must understand how 2-hydroxyethylmethacrylate, the HEMA primer, enhances bonding at the resin-dentin interface. In this study, to obtain an insight into the adhesion mechanisms of adhesive resin to etched dentin through HEMA, we examined the adsorption characteristics of HEMA to dentinal collagen by using the ¹³C NMR technique. The addition of dentinal collagen to the HEMA solution resulted in a decrease in T ₁ values of carbons attributed to the HEMA, thus reflecting an interaction between HEMA and collagen. Specifically, a reduction in the T ₁ value in the ester carbonyl carbon attributed to HEMA greater than that in the other carbons suggested the formation of a hydrogen bond between the ester carbonyl group in HEMA and the dentinal collagen.

Get full access to this article

View all access options for this article.

References

Muramatsu Y, Nishiyama N -1999-. Analysis of interaction mechanisms of dentin adhesive primer. Jpn J Dent Mater 19:1–10.

Nakabayashi N, Pashley DH -1998-. Hybridization of dental hard tissues. 1st rev. ed. Osaka, Japan: Quintessence Publishing Co, Ltd.

Nakabayashi N, Takarada K -1992-. Effect of HEMA on bonding to dentin. Dent Mater 8:125–130.

Nakabayashi N, Kojima K, Masuhara E -1982-. The promotion of adhesion by the infiltration of monomers into tooth substrates. J Biomed Mater Res 16:265–273.

Nishiyama N, Asakura T, Suzuki K, Sato T, Nemoto K -1998-. Adhesion mechanisms of resin to etched dentin primed with N-methacryloyl glycine studied by ¹³C NMR. J Biomed Mater Res 40:458–463.

Nishiyama N, Asakura T, Suzuki K, Komatsu K, Nemoto K -2000-. Bond strength of resin to acid-etched dentin studied by ¹³C NMR. J Dent Res 79:806–811.

Nishiyama N, Suzuki K, Asakura T, Komatsu K, Nemoto K -2001-. Adhesion studies of N-methacryloyl-ω-amino acid primers to collagen analyzed by ¹³C NMR. J Dent Res 80:855–859.

Pashley DH -1990-. Interactions of dentinal materials with dentin. Trans Acad Dent Mater 3:55–73.

Stryer L -1975-. Biochemistry. 1st rev. ed. San Francisco: W.H. Freeman and Company.

10.

Sugizaki J -1991-. The effect of the various primers on the dentin adhesion of resin composite. Jpn J Conserv Dent 34:228–265.

11.

Suzuki K, Nakai H -1994-. Adhesion of restorative resin to tooth substance. Treatment of acid-etched dentin by aqueous solution of HEMA. Jpn J Dent Mater 12:34–44.

12.

Van Meerbeek B, Inokoshi S, Braem M, Lambrechts P, Vanherle G -1992-. Morphological aspects of the resin-dentin interdiffusion zone with different dentin adhesive systems. J Dent Res 71:1530–1540.

13.

Xu J, Stangel I, Butler IS, Gilson DF -1997-. An FT-Raman spectroscopic investigation of dentin and collagen surfaces modified by 2-hydroxyethylmethacrylate. J Dent Res 76:596–601.

A 13 C NMR Study on the Adsorption Characteristics of HEMA to Dentinal Collagen

Abstract

Get full access to this article

References