Abstract
An account is given of recent developments in the preparation of dihydroxy terminated poly(hexafluoropropylene oxide) and its conversion into elastomeric networks with either triazine or urethane crosslinks. Mechanical, dynamic mechanical and thermal properties of the networks are described. Reference is made to the wider field of perfluorinated elastomers, concentrating on those in which main-chain oxygen atoms contribute to chain flexibility.
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References
1.
Smith
S.
in “Preparation, Properties and Industrial Applications of Organofluorine Compounds ”,
Banks
R.E.
, Ed., Ellis Horwood UK , 1982 , Ch.3
2.
Uschold
R.
, Polym . J. , 17 , 1985 , 253
3.
Eleuterio
H.S.
, J. Macromol. Sci. - Chem., A28 , 1991 , 897
4.
Kalb
G.H.
,
Khan
A.A.
,
Quarles
R.W.
and
Barney
A.L.
, ACS Advances in Chemistry Series, No . 129 , 1973 ,13
5.
Eleuterio
H.S.
and
Meschke
R.W.
, US Patent 3358003 (1967 ) . Chem. Abstr. , 68 , 1968, 29573d
6.
Eleuterio
H.S.
, J. Macromol. Sci. - Chem., A6 , 1972 ,1027
7.
Millauer
H.
,
Schwertfeger
W.
and
Siegemund
G.
, Angew . Chem. Int. Ed. Engl. , 24 , 1985 ,161
8.
Fritz
C.G.
,
Moore
E.P.
and
Selman
S.
,
Patent
U.S.
3114778 (1963 ) . Chem. Abstr. , 60 , 1963, 67506
9.
Moore
E.P.
, French. Patent 1362548 (1964 ) . Chem. Abstr. , 62 , 1965, 78976
10.
Fritz
C.G.
and
Moore
E.P.
,
Patent
U.S.
3250807 (1966 ) . Chem. Abstr. , 65 , 1966,13553h
11.
Fritz
G.C.
and
Warnell
J.L.
, US Patent 3317484 (1967 ). Chem. Abstr. , 67 , 1967, 22455n
12.
Sianesi
D.
,
Pasetti
A
,
Fontanelli
R.
,
Bernardi
G.C.
and
Caporiccio
G.
, Chim . Ind. , 55 , 1973 , 208
13.
Faucitano
A.
,
Buttafava
A.
,
Martinetti
F.
,
Marchionni
G.
and
De Pasquale
R.J.
, J. Phys. Org. Chem. , 4 , 1991 , 293
14.
Marchionni
G.
,
Staccione
A.
and
Gregorio
G.
, J. Fluor. Chem. , 47 , 1990 , 515
15.
Marchionni
G.
,
Ajroldi
G.
and
Pezzin
G.
, Eur . Polym. J. , 24 , 1988 , 1211
16.
Hill
J.T.
and
Garabedian
M.E.
,
Patent
U.S.
3660315(1970 ) . Chem. Abstr. , 77 , 1972, 35266h
17.
Hill
J.T.
, J. Macromol. Sci. - Chem., A8, 1974 , 499
18.
Hill
J.T.
and
Erdman
J.P.
, ACS Symposium Series , 59 , 1977 , 269
19.
Darling
T.R.
, Eur. Patent 0062325 A2 (1982 ) . Chem. Abstr. , 98 , 1983, 107982x
20.
Gubanov
V.A.
,
Tyul'ga
G.M.
,
Sherman
M.A.
,
Troichanskaya
P.E.
,
Erenburg
E.G.
,
Shpakov
P.P.
and
Zak
A.V.
, Vysokomol . Soedin. Ser. B. , 26 , 1984 , 406. Chem Abstr., 101, 1984, 172062s
21.
Shpakov
P.P.
,
Gubanov
V.A.
, Tyul'ga G. M.,
Zak
A.V.
,
Troichanskaya
P.E.
and
Kazakova
L.M.
, Zh . Prikl. Khim.. 54 , 1981 , 2726. Chem Abstr., 96, 1982, 143376v
22.
Ikeda
M.
and
Aoshima
A
, Japanese Patent 02097526 A2 (1990 ) . Chem. Abstr. , 113 , 1990, 172989x
23.
Ding
J.-F.
,
Proudmore
M.
,
Mobbs
R.H.
,
Khan
AR.
,
Price
C.
and
Booth
C.
, Makromol . Chem. , 193 , 1992 , 2211
24.
Ding
J.-F.
,
Khan
AR.
,
Proudmore
M.
,
Mobbs
R.H.
,
Heatley
F.
,
Price
C.
and
Booth
C.
, Macromol . Chem. Phys , 195 , 1994 , 3137
25.
Hollander
J.
, Narmco Research and Development Division of Whittaker
Corporation
NASA
Report 1967 NASA-CR-61743. Chem . Abstr. , 71 , 1969, 92165z
26.
Hollander
J.
,
Trischler
F.D.
and
Harrison
E.S.
, ACS Div . Polym. Chem. Prepr. , 8 , 1967 , 1149
27.
Proudmore
M.
, Ding J . -F. ,
Mobbs
R.H.
,
Yeates
S.G.
,
Price
C.
and
Booth
C.
, J. Polym. Sci., Part A, Polym. Chem., submitted
28.
Anderson
R.
,
Baum
K.B.
and
Psarras
T.
, J. Fluorine Chem. 7 , 1976 ,581
29.
Alper
T.
,
Barlow
AJ.
,
Gray
R.W.
,
Kim
M.G.
,
Mclachan
R.J.
and
Lamb
J.
, J. Chem. Soc., Faraday 2 , 76, 1980 , 205
30.
Ouano
AC.
, Appelt Band
Watson
T.
, Org . Coat. Appl. Polym. Sci. Proc. , 46 , 1981 , 230
31.
Marchionni
G.
,
Ajroldi
G.
Cinquina
P.
,
Tampellini
E.
and
Pezzin
G.
, Polym . Eng. Sci. , 30 , 1990 , 829
32.
Ajroldi
G.
,
Marchionni
G.
,
Fumagalli
M.
and
Pezzin
G.
, Plast . Rubber. Compos. Proc. Appl. , 17 , 1992 , 307. Chem. Abstr., 118, 1993, 81732y
33.
Heatley
F.
,
Yu
G.-E.
,
Lawrence
J.
and
Booth
C.
, Eur . Polym. J. , 30 , 1994 ,1249
34.
Mandelkern
L.
in “Comprehensive Polymer Science ”, Vol. 2, Eds.
Booth
C.
and
Price
C.
, Pergamon, Oxford, 1989 , p. 387
35.
Rosser
R.W.
and
Korus
R.A
, J. Polym. Sci., Polym. Lett. Edn. , 18 , 1980 , 135
36.
Rosser
R.W.
,
Chen
T.S.
and
Cheng
C.H.
, J. Polym. Sci., Polym. Lett. Edn. , 20 , 1982 , 467
37.Du Pont Product Information Bulletin, Krytox Fluorinated
Greases
E.I.
Du Pont de Nemours & Co. Inc., Wilmington, Delaware, USA
38.
Queslel
J.P.
and
Mark
J.E.
in “Comprehensive Polymer Science ”, Vol. 2, Eds.
Booth
C.
and
Price
C.
, Pergamon, Oxford, 1989 , p. 289
39.
Mooney
M.
, J. Appl. Phys. , 19 , 1948 , 434
40.
Rivlin
R.S.
, Phil . Trans. R. Soc. London, Ser. A , 241 , 1948 , 379
41.
Polymer Laboratories
MKII
DMTA specification: Polymer laboratories Ltd., Thermal Sciences Division, Loughborough,
LEll
OQE
, UK
42.
McKenna
G.B.
in “Comprehensive Polymer Science ”, Vol. 2 , Eds.
Booth
C.
and
Price
C.
, Pergamon, Oxford, 1989 , p. 326
43.
Hale
A.
,
Macosko
C.W.
and
Blair
H.E.
, Macromolecules , 24 , 1991 ,2610
44.
Reference 38, p. 300
45.
British Patent 797,795 (1958 ) to Dow Corning Corp . Chem. Abstr. , 53 , 1959, 1830c
46.
Bonanni
A.P.
, US Naval Air Engineering Center, Report No. NAEC AML 1636 , 1963
47.
Hollander
J.
,
Trischler
F.D.
,
Harrison
E.S.
,
Rafter
R.T.
, and
Ade
L.
, Narmco Research and Development Division of Whittaker Corporation, Contract No. NAS 8-11068, Annual Summary
Report
II
, 1965
48.
Bruson
H.A.
and
Rose
J.S.
, French Patent, 1371674 (1964), Chem. Abstr. 62, 1965, 9321c. US Patent 3269961(1966), Chem. Abstr . 66 , 1967 , 3406v
49.
Hollander
J.
in “High Polymers, Vol . 25, Fluoropolymers”, Ed .
Wall
L.A.
, Wiley-lnterscience, New York, 1972 , Ch. 6
50.
Trombetta
T.
,
Tonelli
C.
,
Castiglioni
G.
and
Ajroldi
G.
, J. Fluor. Chem. , 58 , 1992 , 210
51.
Miyabayashi
T.
and
Kennedy
J.P.
, J. Appl. Polym. Sci. , 31 , 1986 , 2523 .